R 30 Reactions of [2-iodo-3-(perfluoroalkyl)propyl]glycidyl ethers with alcohols under basic conditions [Electronic resource] / D. N. Bazhin, T. I. Gorbunova, A. Ya. Zapevalov, V. I. Saloutin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2008. - Vol. 57, № 11. - P2324-2327. - Bibliogr. : p. 2327 ( ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): GLYCIDYL ETHERS -- ORGANOFLUORINE COMPOUNDS -- OXIRANES -- PHASE TRANSFER CATALYSIS Аннотация: On treatment with sodium alkoxides in the corresponding alcohols, [2-iodo-3-(perfluoroalkyl)propyl]glycidyl ethers are converted into 3-alkoxy-1-[3-(perfluoroalkyl)prop-2-enyloxy]-propan-2-ols in 56-78% yields, while its reaction with 2,2,2-trifluoroethanol and phenol under phase transfer conditions (NaOH, CH2Cl2-H2O, Bu 4N+I-, 35-40 °C) gives 3-alkoxy1-[2-iodo-3- (perfluoroalkyl)propoxy]propan-2-ols (yields 45-72%). \\\\Expert2\\nbo\\Russian Chemical Bulletin\\2008, 57 (11), 2324.pdf |