G 65 Gorbunova, T. I. Synthesis of oxyranes based on 1,1,2,3,3-pentafluoro-1,5-hexadiene [Electronic resource] / T. I. Gorbunova, A. Ya. Zapevalov, V. I. Saloutin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1995. - Vol. 44, № 8. - P1470-1473 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Interaction of 1,1,2,3,3-pentafluoro-1,5-hexadiene with Br2 in a MeCOOH medium results in the product of selective bromination of the hydrocarbon double bond,i.e., 5,6-dibromo-1,1,2,3,3-pentafluoro-1-hexene. Epoxidation of the latter with H2O2 in an alkaline medium followed by debromination afforded 5,6-epoxy-4,4,5,6,6-pentafluoro-1-hexene for the first time \\\\Expert2\\nbo\\Russian Chemical Bulletin\\1995, 44 (8), 1470.pdf |