I-85 Isomerization of monohydroperfluoroalkenes [Electronic resource] / T. I. Filyakova, A. Ya. Zapevalov, M. I. Kodess, M. A. Kurykin, L. S. German // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1994. - Vol. 43, № 9. - P1526-1531 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Isomerization of monohydroperfluoro-1-alkenes HC(CF2)nCF=CF2 (n = 2 to 8) catalyzed by Lewis bases or acids (CsF, KHF2, and SbF5) under conditions of thermodynamic control affords equilibrium mixtures of all of the possible isomers resulting from migration of the double bond along the carbon chain. Under conditions of kinetic control, isomerization through the action of SbF5 gives -H-perfluoro-2-alkenes. The substantially higher proportion ofcis-isomers in the resulting monohydroperfluoroalkenes than in their perfluorinated analogs has been attributed to the effect of an intramolecular hydrogen bond \\\\Expert2\\nbo\\Russian Chemical Bulletin\\1994, 43 (9), 1526.pdf |