P 17 Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one: Synthesis, structure, and catalytic activity / A. Mechaev, A. V. Pestov, P. A. Slepukhin, Yu. G. Yatluk, M. G. Pervova, M. A. Samorukova, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2011. - Vol.47, №9. - С. 1366-1369 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): HECK REACTION -- ARYL Аннотация: Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (S (N) (H) reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction \\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2011, 47 (9), 1366.pdf |