R 30 Reactions of 1,1,1trihalo-3-nitrobut-2-enes with enamines derived [Electronic resource] / V. Yu. Korotaev, A. Yu. Barkov, P. A. Slepukhin, V. Ya. Sosnovskikh // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2012. - Vol.61, №9. - С. 1750-1760. - Bibliogr. : p. 1760 (30 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): 1,1,1TRIHALO-3NITROBUT-2ENES -- ENAMINES -- X-RAY DIFFRACTION Аннотация: 1,2 Oxazine Noxides derived from (E)1,1,1trifluoro3nitrobut2ene and cyclohexanone enamines underwent spontaneous rearrangement with ring contraction to give 1pyrroline N oxides. Reactions of (E) 1,1,1 trifluoro(trichloro) 3 nitrobut 2 enes with N cyclopent enylmorpholine resulted in a series of novel CX3 containing nitroalkyl enamines and g nitro ketones; the stereochemistry of the synthesized compounds were studied by NMR spectroscopy and X ray diffraction \\\\expert2\\NBO\\Russian Chemical Bulletin\\2012, 61 (9), 1750-1760.pdf |