R 30 Reactions of Terpene Alcohols and Diols with Chlorine Dioxide in Dimethylformamide [Electronic resource] / L. L. Frolova, A. V. Popov, L. V. Bezuglaya, I. N. Alekseev, P. A. Slepukhin, A. V. Kutchin // Russian Journal of General Chemistry. - 2016. - Vol. 86, № 3. - С. 613-621 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ONE-POT SYNTHESIS -- OXIDATION -- KETONES Аннотация: The system chlorine dioxide-dimethylformamide in combination with or without a catalytic amount of MoCl5, CeCl3, ZrOCl2, or VO(acac)(2) induces oxidative chlorination of a number of bicyclic terpene alcohols and vicinal diols. 2 alpha-Chloropinan-3-one, 3 alpha-chloro-10 beta-pinan-4-one, 5 alpha-chloro-3 alpha-hydroxycaran-4-one, 5 beta-chloro-3 beta-hydroxycaran-4-one, and 4 alpha-chloro-2 alpha-hydroxypinan-3-one were thus synthesized in good preparative yields. \\\\expert2\\NBO\\Russian Journal of General Chemistry\\2016, V. 86, N 3, p. 613-621.pdf |