S 98 Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones / V. I. Saloutin, Y. V. Burgart, Y. O. Edilova [et al.] // Russian chemical bulletin. - 2021. - Vol. 70, № 5. - P839-846 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): FLUORINATED 1,3-DIKETONATES -- CLAISEN CONDENSATION -- ACETALS -- TRANSITION METAL DIKETONATES Аннотация: Mononuclear copper(II) complexes were synthesized based on fluorinated diketonates decorated with a carbonyl or acetal group. The X-ray diffraction data demonstrate the effect of the nature of the fluorinated substituent on the crystal structure of homoleptic copper(II) complexes. As opposed to 1,2,4-triketonate, the acetal moiety of 1,3-diketonate enables intermolecular coordination to the metal centers, thereby making it possible to use 1,3-diketonate in further synthesis of heterometallic structures. |