Unusual synthesis of triosmium carbene clusters by tandem activation of chlorohydrocarbons and heterocyclic amines / B. Y. Savkov, V. A. Maksakov, A. V. Virovets [et al.] // European journal of inorganic chemistry. - 2021. - № 10. - P989–996 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The carbene ligand is assembled on a cluster core of two dichloromethane and one morpholine at room temperature, which is the first example of carbene ligands formed in this way. Clusters with a carbene ligand exist as two stable isomers, as confirmed by NMR studies and conformational analysis. Possible mechanistic pathways for the formation of clusters with carbene and enamine ligands are proposed. |