Synthesis of chiral CF3-contaning pinane-type hydroxythiols / N. O. Ilchenko, D. V. Sudarikov, P. A. Slepukhin [et al.] // ChemistrySelect. - 2021. - Vol. 6, № 7. - P1710-1714 Рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: For the first time, the isomeric trifluoromethylated thioacetates have been synthesized in 37–52 % yields by nucleophilic addition of the Ruppert-Prakash reagent (TMSCF3) to the corresponding thioacetates based on (1R)-(−)-myrtenal and (1S)-(−)-verbenone. Thioacetates have been transformed into the corresponding pinane thiols in 73–90 % yields. The structure and configuration of the resulting compounds have been determined. |