Вид документа : Статья из журнала Шифр издания : 54/N 57 Автор(ы) : Makarycheva-Mikhailova A. V., Gushchin P. V., Kopylovich M. N., Ganebnuikh I. N., Charushin V. N., Haukka M. P., Armando J. L., Kukushkin V. Yu. Заглавие : Ni(II)-Mediated nitrosation of oximes bearing an alfa-CH2 group Место публикации : Inorganic Chemistry Communications. - 2006. - Vol. 9, № 8. - С. 869-871 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: Heating of NiCl2 · 6H2O with 10-fold excess of an oxime having an CH2 group (1–4) at 100 °C for 1 day in air leads to the formation of the dioxime/ato complexes [Ni(dioxime/ato)2] (5–8) formed due to a novel type of metal-mediated nitrosation. Compounds 5–8 were characterized by elemental analyses, FAB (5–7) or APCI (8) mass-spectrometry, IR, 1H and 13C{1H} spectroscopies (for 8), and X-ray structural study has been performed for 5 and 8; the corresponding ketones (9–12) were identified by LC–MS. Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Makarycheva-Mikhailova, A. V.; Gushchin, P. V.; Kopylovich, M. N.; Ganebnuikh, I. N.; Ганебных Илья Николаевич; Charushin, V. N.; Haukka, M. P.; Armando , J. L.; Kukushkin, V. Yu.