Вид документа : Статья из журнала Шифр издания : 54/F 94 Автор(ы) : Saloutina L. V., Zapevalov A. Ya., Kodess M. I., Lyssenko K.A., Antipin M. Yu., Saloutin V. I., Chupakhin O. N. Заглавие : From oxides of internal perfluoroolefins to fluorocontaining camphor thiazolinylhydrazones Место публикации : Journal of Fluorine Chemistry. - 2003. - Vol. 120, № 1. - С. 41-47 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The reaction of oxides of internal trans- and cis-perfluoroolefins with (1S, 4S)- or racemic camphor thiosemicarbazone leads to the formation of trans- and cis-isomers of (1S, 4S)- or racemic camphor 5?-fluoro-4?-hydroxy-4?,5?-di(perfluoroalkyl)-1?,3?-thiazolinyl-2?-hydrazones, respectively. Unsymmetrical dodecafluoro-2,3-epoxyhexane yields a mixture of regioisomeric hydrazones. The molecular structure of the trans-isomer of (1S, 4S)-camphor 5?-fluoro-4?-hydroxy-4?,5?-bis(trifluoromethyl)-1?,3?-thiazolinyl-2?-hydrazone has been established by X-ray crystallography. The quite rare example of cocrystallization of two diastereomers of the latter in homochiral crystal (sp. group P21) has been revealed???? Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Saloutina, L. V.; Салоутина Людмила Васильевна; Zapevalov, A. Ya.; Запевалов Александр Яковлевич; Kodess, M. I.; Кодесс Михаил Исаакович; Lyssenko, K.A.; Antipin, M. Yu.; Saloutin, V. I.; Chupakhin, O. N.