Вид документа : Статья из журнала Шифр издания : 54/R 30 Автор(ы) : Saloutin V. I., Skryabina Z. E., Burgart Ya. V., Chupakhin O. N. Заглавие : Reaction of 2-amino-4-imino-2-perfluoropentene with ethylenediamine and diethylenetriamine [Electronic resource] Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1993. - Vol. 42, № 10. - С. 1697-1700 Систем. требования: http://www.springerlink.com/content/675411v130641297/fulltext.pdf Примечания : 24.10.2011 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The transamination of 2-amino-4-imino-2-perfluoropentene with ethylenediamine gives the corresponding 6-fluoro-5,7-bis(trifluoromethyl)-2,3-dihydro-1H-1,4-diazepine. The transamination of 2-amino-4-imino-2-perfluoropentene by diethylenetriamine is accompanied by intramolecular nucleophilic substitution of the ?-fluorine atom to form 1,9-bis(trifluoromethyl)-3,4,6,7-tetrahydro-2H-pyrazino[1,2-a]pyrazine whose structure was established by an X-ray structural investigation. Several salts of this bicyclic compound and its complex with BF3 have been described Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Saloutin, V. I.; Skryabina, Z. E.; Скрябина Зинаида Эдуардовна; Burgart, Ya. V.; Бургарт Янина Валерьевна; Chupakhin, O. N.