Вид документа : Шифр издания : 54/P 17 Автор(ы) : Varaksin M. V., Utepova I. A., Chupakhin O. N., Charushin V. N. Заглавие : Palladium(II)-Catalyzed Oxidative C–H/C–H Coupling and Eliminative SNH Reactions in Direct Functionalization of Imidazole Oxides with Indoles Место публикации : Journal of Organic Chemistry. - 2012. - Vol.77, №20. - С. 9087-9093 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): imidazole oxides --indoles Аннотация: Two novel synthetic approaches to realize the direct C(sp2)–H bond functionalization in cyclic nitrones are reported. Palladium(II)-catalyzed oxidative C–C coupling of 2,2-dialkyl-4-phenyl-2H-imidazole 1-oxides with indoles was shown to result in the formation of 5-indolyl-3-yl derivatives, while nucleophilic substitution of hydrogen (SNH) at C(5) of the same imidazole system was found to afford the corresponding deoxygenated compounds Доп.точки доступа: Varaksin, M. V.; Utepova, I. A.; Chupakhin, O. N.; Charushin, V. N.