Вид документа : Шифр издания : 54/S 98 Автор(ы) : Demakova M. Ya., Sudarikov D. V., Rubtsova S.A., Frolova L. L., Popov A. V., Slepukhin P. A., Kuchin A. V. Заглавие : Synthesis and Asymmetric Oxidation of (Caranylsulfanyl)-1H-imidazoles Место публикации : Helvetica Chimica Acta. - 2012. - Vol.95, №6. - С. 940-950 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): 1h-imidazoles--asymmetric oxidation--x-ray crystallography Аннотация: For the first time 2-(cis-caran-4-ylsulfanyl)-1H-imidazole, 1-methyl-2-(cis-caran-4-ylsulfanyl)-1H-imidazole, and 2-(cis-caran-4-ylsulfanyl)-1H-benzimidazole (carane=3,7,7-trimethylbicyclo[4.1.0]heptane) were synthesized, and the asymmetric oxidation of these compounds was also carried out. It was shown that oxidation by the Bolm system and the modified system of Sharpless lead to corresponding sulfoxides with de values of 91–100% Доп.точки доступа: Demakova, M. Ya.; Sudarikov, D. V.; Rubtsova, S.A.; Frolova, L. L.; Popov, A. V.; Slepukhin, P. A.; Kuchin, A. V.