Вид документа : Шифр издания : 54/A 10 Автор(ы) : Bazhin D. N., Gorbunova T. I., Zapevalov A. Ya., Beketov I. V., Saloutin V. I. Заглавие : A study of the physico-chemical features of the [(perfluoroalkyl)methyl]oxirane amino derivatives based on the hexafluoropropylene oxide trimer Место публикации : Russian Journal of General Chemistry. - 2011. - Vol.81, №9. - С. 1829-1833 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): physico-chemical features --hexafluoropropylene--oxide trimer Аннотация: The 1,2-epoxy-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecane was synthesized for the first time on the basis of the hexafluoropropylene oxide trimer. We showed that it reacted with diethylamine, morpholine, or N-methylpiperazine to afford the product of regioselective cleavage of the oxirane ring. The processing of nano-sized copper powder with a solution of the obtained hydroxyamine solution in acetone allowed the formation of the hydrophobic metal coating Доп.точки доступа: Bazhin, D. N.; Gorbunova, T. I.; Горбунова Татьяна Ивановна; Zapevalov, A. Ya.; Запевалов Александр Яковлевич; Beketov, I. V.; Saloutin, V. I. |