Вид документа : Шифр издания : 54/C 31 Автор(ы) : Bazhin D. N., Kudyakova Yu.S., Burgart Ya. V., Saloutin V. I. Заглавие : Catalyst-free transformations of diethyl 2-ethoxymethylenemalonate and diethyl polyfluorobenzoylmalonates in water Место публикации : Tetrahedron Letters. - 2012. - Vol. 53, №15. - С. 1961-1963 ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): 1,3,5-benzenetricarboxylate --water--polyfluorobenzoylmalonates Аннотация: The unusual transformation of diethyl 2-ethoxymethylenemalonate into triethyl 1,3,5-benzenetricarboxylate is described. This one-pot reaction proceeds in water without any catalyst in a good yield. One of the proposed intermediates of this process is also used under similar conditions to give the desired trisubstituted benzene. A catalyst-free, efficient, practical, and convenient process in water based on deethoxycarbonylation has been developed to form ethyl polyfluorobenzoylacetates in a high yield from diethyl polyfluorobenzoylmalonates Доп.точки доступа: Bazhin, D. N.; Kudyakova, Yu.S.; Burgart, Ya. V.; Бургарт Янина Валерьевна; Saloutin, V. I.