Вид документа : Статья из журнала Шифр издания : 54/T 44 Автор(ы) : Kulikova T. V., Maiorova A. V., Shunyaev K.Yu., Gorbunova T. I., Saloutin V. I., Chupakhin O. N. Заглавие : Thermodynamic modeling of the reaction of polychlorinated biphenyls with sodium methoxide Место публикации : Russian Journal of General Chemistry. - 2013. - Vol.83, №5. - С. 893-900 Примечания : Библиогр.: с. 900 (17 ref.) ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): thermodynamic modeling --sodium methoxide--polychlorinated biphenyls Аннотация: Thermochemical parameters, like standard enthalpy of formation (ΔH 298 0), enthalpy increment from 0 to 298 K (H 298 0 - H 0 0), standard heat capacity (C p298 0) and its temperature dependence [Cp(T)], and entropy (S 298 0), were calculated for the gaseous methoxy derivatives formed from polychlotinated biphenyl (PCB) congeners. Thermodynamic modeling and the HSC software were used to evaluate the reactivity of PCB congeners toward sodium methoxide in DMSO, and the calculation results were compared with experimental data Доп.точки доступа: Kulikova, T. V.; Maiorova, A. V.; Shunyaev, K.Yu.; Gorbunova, T. I.; Горбунова Татьяна Ивановна; Saloutin, V. I.; Chupakhin, O. N.