Вид документа : Статья из журнала Шифр издания : 54/B 62 Автор(ы) : Fokin S.V., Ovcharenko V., Romanenko G. V., Tretyakov E. V., Bogomyakov A. S., Saloutin V. I., Filyakova T. I., Saloutina L. V., Charushin V. N., Chupakhin O. N. Заглавие : Bis(1,1,1,3,5,5,5-heptafluoro-4-iminopent-2-ene-2-aminato)copper(ii) — a new metal-containing matrix in the design of heterospin systems Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2011. - Vol.60, №5. - С. 816-823 Примечания : Bibliogr. : p. 823 (11 ref.) ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): copper(ii)--bischelates--nitroxides Аннотация: The first heterospin compounds based on bis(1,1,1,3,5,5,5 heptafluoro 4 iminopent 2 ene 2 aminato)copper(II) (CuL2) and nitronyl nitroxide radicals, 2 R 4,4,5,5 tetramethyl 4,5 dihydro 1H imidazole 3 oxide 1 oxyls (NIT R, where R = H, Me, Ph, and 1 methyl pyrazol 4 yl), were synthesized and structurally characterized. An important peculiarity of the structure of synthesized solid phases is the formation of a supramolecular structure due to hydrogen bonds between the oxygen atoms of the nitronyl nitroxide fragments of NIT R and the hydrogen atoms of the NH groups of CuL2 Доп.точки доступа: Fokin, S.V.; Ovcharenko, V.; Romanenko, G. V.; Tretyakov, E. V.; Bogomyakov, A. S.; Saloutin, V. I.; Filyakova, T. I.; Филякова Татьяна Ивановна; Saloutina, L. V.; Салоутина Людмила Васильевна; Charushin, V. N.; Chupakhin, O. N. |