Вид документа : Статья из журнала Шифр издания : Г/S 98 Автор(ы) : Saloutin V. I., Burgart Y. V., Edilova Y. O., Slepukhin P. A., Kudyakova Y. S., Bazhin D. N. Заглавие : Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones Место публикации : Russian chemical bulletin. - 2021. - Vol. 70, № 5. - С. 839-846 ББК : Г Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): fluorinated 1,3-diketonates--claisen condensation--acetals--transition metal diketonates Аннотация: Mononuclear copper(II) complexes were synthesized based on fluorinated diketonates decorated with a carbonyl or acetal group. The X-ray diffraction data demonstrate the effect of the nature of the fluorinated substituent on the crystal structure of homoleptic copper(II) complexes. As opposed to 1,2,4-triketonate, the acetal moiety of 1,3-diketonate enables intermolecular coordination to the metal centers, thereby making it possible to use 1,3-diketonate in further synthesis of heterometallic structures. Доп.точки доступа: Saloutin, V. I.; Burgart, Y. V.; Бургарт Янина Валерьевна; Edilova, Y. O.; Slepukhin, P. A.; Kudyakova, Y. S.; Bazhin, D. N.