Вид документа : Статья из журнала Шифр издания : Автор(ы) : Savkov B. Y., Maksakov V. A., Virovets A. V., Peresypkina E. V., Potemkin V. A., Palko N. N. Заглавие : Unusual synthesis of triosmium carbene clusters by tandem activation of chlorohydrocarbons and heterocyclic amines Место публикации : European journal of inorganic chemistry. - 2021. - № 10. - С. 989–996 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: The carbene ligand is assembled on a cluster core of two dichloromethane and one morpholine at room temperature, which is the first example of carbene ligands formed in this way. Clusters with a carbene ligand exist as two stable isomers, as confirmed by NMR studies and conformational analysis. Possible mechanistic pathways for the formation of clusters with carbene and enamine ligands are proposed. Доп.точки доступа: Savkov, B. Y.; Maksakov, V. A.; Virovets, A. V.; Peresypkina, E. V.; Potemkin, V. A.; Palko, N. N.