Вид документа : Статья из журнала Шифр издания : Автор(ы) : Ilchenko N. O., Sudarikov D. V., Slepukhin P. A., Rubtsova S. A., Kutchin A. V. Заглавие : Synthesis of chiral CF3-contaning pinane-type hydroxythiols Место публикации : ChemistrySelect. - 2021. - Vol. 6, № 7. - С. 1710-1714 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: For the first time, the isomeric trifluoromethylated thioacetates have been synthesized in 37–52 % yields by nucleophilic addition of the Ruppert-Prakash reagent (TMSCF3) to the corresponding thioacetates based on (1R)-(−)-myrtenal and (1S)-(−)-verbenone. Thioacetates have been transformed into the corresponding pinane thiols in 73–90 % yields. The structure and configuration of the resulting compounds have been determined. Доп.точки доступа: Ilchenko, N. O.; Sudarikov, D. V.; Slepukhin, P. A.; Rubtsova, S. A.; Kutchin, A. V.