F 17 Faizullin, M. Z. Properties of gas hydrates formed by nonequilibrium condensation of molecular beams [Electronic resource] / M. Z. Faizullin, A. V. Vinogradov, V. P. Koverda // High Temperature. - 2014. - Vol. 52, № 6. - С. 830-839. - Bibliogr. : p. 838-839 (36 ref.) Рубрики: ФИЗИКА Кл.слова (ненормированные): GLASS-TRANSITION -- AMORPHOUS SOLIDS -- AQUEOUS-SOLUTIONS Аннотация: Low-temperature crystallization of amorphous materials has been analyzed theoretically taking into account nonstationary nucleation. The kinetics of crystallization of amorphous water layers, formed by depositing molecular beams on a substrate cooled by liquid nitrogen, has been investigated by differential thermal analysis. The conditions of gas hydrate formation in low-temperature amorphous-ice layers saturated with carbon dioxide have been studied. The glass-transition and crystallization temperatures of the gas hydrates have been determined from the change in dielectric properties upon heating. Under the deep-metastability conditions, crystallization of water-gas layers leads to the formation of crystallohydrates. Gas molecules are captured by the avalanche-like nucleation of crystallization centers and, therefore, are not displaced by the moving crystal-melt interface. Gas-hydrate samples formed in nonequilibrium water-gas layers are convenient for studying their thermophysical properties \\\\expert2\\nbo\\High Temperature\\2014, v. 52, N 6, p.830-839.pdf |