E 43 Electrochemical and thermodynamic properties of ytterbium trichloride in molten caesium chloride [Текст] / V. Smolenski, A. Novoselova, A. Bovet, A. Osipenko, M. Kormilitsyn // Journal of Nuclear Materials . - 2009. - Vol. 385, № 1. - С. 184-185. - Библиогр.: с. 185 (5 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ИТТЕРБИЙ Аннотация: This work presents the electrochemical study of YbCl3 in molten CsCl in the temperature range 973–1073 K. Transient electrochemical techniques have been used in order to investigate the reduction mechanism, transport parameters and thermodynamics properties of the reaction YbCl2+1/2Cl2=YbCl3. The results obtained show that the reduction reaction is reversible being controlled by the rate of the mass transfer. The diffusion coefficient of [YbCl6]3- complex ions was determined. The apparent standard electrode potential of the soluble–soluble redox system Yb3+/Yb2+ was obtained by cyclic voltammetry. \\\\Cserver\\dist\\НБО\\Cтатьи БД ИВТЭ\\Journal of Nuclear Materials\\2009, V. 385, № 1, С. 184-185.pdf |