I-85 Isaev, V. A. Galvanostatic nucleation and growth under diffusion control / V. A. Isaev, O. V. Grishenkova // Journal of Solid State Electrochemistry . - 2013. - Vol. 17, № 6. - С. 1505-1508. - Bibliogr. : p. 1508 (18 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ДИФФУЗИЯ -- ОСАЖДЕНИЕ -- ЭЛЕКТРОЛИТ -- ЭЛЕКТРООСАЖДЕНИЕ -- ЗАРОЖДЕНИЕ Аннотация: A theory is proposed for galvanostatic three-dimensional nucleation and growth of new phase clusters controlled by diffusion of depositing ions in the bulk of the electrolyte to the clusters surface. The mathematical model is used to calculate the time dependences of the overpotential, number, and size of clusters formed on the electrode |