T 44 Thermodynamics of separation of uranium from neodymium between the gallium-indium liquid alloy and the LiCl-KCl molten salt phases / A. Smolenski, A. Novoselova, A. Osipenko, M. Kormilitsyn, Ya. Luk’yanova // Electrochimica Acta. - 2014. - Vol. 133. - P .354-358. Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): УРАН -- НЕОДИМ -- РАЗДЕЛЕНИЕ -- ТЕРМОДИНАМИКА Аннотация: This work presents the electrochemical study of neodymium and uranium compounds in fused LiCl-KCl eutectic vs. Cl-/Cl2 reference electrode in the temperature range 723-823 K on liquid gallium-indium eutectic alloy. The activity, solubility and the activity coefficients of neodymium were calculated. The separation factor of uranium from neodymium on gallium-indium eutectic alloy was determined. The obtained data show the perspective of used this system in future innovation method for recovery of nuclear waste. |