Вид документа : Статья из журнала Шифр издания : 54/N 89 Автор(ы) : Novoselova A., Smolenski V. Заглавие : Thermodynamic properties of thulium and ytterbium in molten caesium chloride Место публикации : The Journal of Chemical Thermodynamics . - 2010. - Vol. 42, № 8. - С. 973-977. - ISSN 0021-9614. - ISSN 0021-9614 Примечания : Bibliogr. : p. 977 (47 ref.) ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Аннотация: This work presents the results of a study of the Tm3+/Tm2+ and Yb3+/Yb2+ couple redox potentials vs. Cl?/Cl2 reference electrode at the temperature range (973 to 1123) K in molten CsCl by direct potentiometric method. Initial concentrations of TmCl3 and YbCl3 in solvents did not exceed 5.0 mol%. Basic thermodynamic properties of the reactions TmCl2(l) + 1/2 Cl2(g) TmCl3(l) and YbCl2(l) + 1/2 Cl2(g) YbCl3(l) were calculated using the temperature dependencies of apparent standard potentials of the couples and .?? Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Smolenski, V.