V 92 Vorokh, A. S. Atomic structure of cadmium sulfide nanoparticles [Текст] / A. S. Vorokh, A. A. Rempel // Physics of the Solid State. - 2007. - Vol. 49, № 1. - С. 148-153. - Библиогр. : с. 153 (20 назв.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): АТОМНАЯ СТРУКТУРА -- СУЛЬФИД КАДМИЯ -- НАНОЧАСТИЦЫ Аннотация: A method for calculating the x-ray diffraction patterns of cadmium sulfide nanoparticles with a disordered internal structure, a real surface, shape, and size is proposed within the kinematic theory of scattering. A computer analysis has revealed that the characteristic shape of the experimental x-ray diffraction patterns of cadmium sulfide films and powders is determined by a specific disordered anoparticle structure differing from the crystal structures of wurtzite and sphalerite. According to the computer simulation, cadmium sulfide nanoparticles synthesized through chemical deposition have a shape similar to a hexagonal prism with a characteristic size of approximately 5 nm. Полный текст |