I-76 Ion and electron conduction in SrFe1-xScxO3-delta [Text] / M. V. Patrakeev, A. A. Markov, I. A. Leonidov, V. L. Kozhevnikov, V. V. Kharton // Solid State Ionics. - 2006. - Vol. 177, № 19-25. - P.1757-1760. - Bibliogr. : p. 1760 (12 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ИОННАЯ ПРОВОДИМОСТЬ, ЭЛЕКТРОННАЯ ПРОВОДИМОСТЬ -- СТРОНЦИЙ -- ЖЕЛЕЗО -- СКАНДИЙ -- НЕСТЕХИОМЕТРИЯ Аннотация: The oxygen ion and electron transport in SrFe1-xScxO3-delta (x =0.1–0.3) system at 700–950 -C were studied analyzing the total conductivity dependencies on the oxygen partial pressure, pO2. The conductivity measurements were performed both under reducing conditions (10(-19)<=pO2<=10(-8) atm) comprising the electron-hole equilibrium point, and in oxidizing atmospheres (10(-5)<=pO2<=0.5 atm) which are??characterized by extensive variations of the oxygen content studied by coulometric titration technique. The incorporation of 10% Sc3+ cations into the iron sublattice suppresses transition of the cubic perovskite phase into vacancy-ordered brownmillerite, thus improving ion conduction at temperatures below 850 -C. When scandium content increases, the ion conductivity becomes considerably lower. The hole mobility is thermallyactivated and varies in the range of 0.001 to 0.05 cm(2) V(-1) s(-1), increasing with oxygen concentration and decreasing on Sc doping |