I-76 Ionic Equilibria in Alkaline Aqueous Solutions of Metal Complex Salts / N. S. Kozhevnikova, A. A. Uritskaya, A. S. Vorokh, A. A. Rempel // Russian Journal of General Chemistry. - 2008. - Vol. 78, № 4. - P551-556 : il. - Bibliogr. : p. 556 (10 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ИОННОЕ РАВНОВЕСИЕ -- ЩЕЛОЧНЫЕ ВОДНЫЕ РАСТВОРЫ -- СОЛИ МЕТАЛЛОВ Аннотация: A thermodynamic analysis of the formation conditions of metal hydroxides was performed. The areas of stable formation of metal hydroxide precipitates in the coordinates pH–metal concentration, including also solutions containing various kinds of complexing agents, were evaluated. With the precipitation of cadmium hydroxide as example, X-ray phase analysis confirmed the formation of metal hydroxide in the chemical composition areas where its formation is predicted by a thermodynamic analysis Полный текст |