B 33 Bazuev, G. V. Synthesis and Magnetic Properties of Quasi-Unidimensional Oxide Sr6.3Rh2.35Mn2.35O15 / G. V. Bazuev, T. I. Chupakhina, M. A. Melkozerova // Russian Journal of General Chemistry. - 2008. - Vol. 78, № 10. - P1843-1848 : il. - Bibliogr. : p. 1847-1848 (33 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): КВАЗИОДНОМЕРНЫЕ ОКСИДЫ -- МАГНИТНЫЕ СВОЙСТВА Аннотация: Attempts of the synthesis in air of complex oxides Sr3RhMnOx and Sr4Rh1.5Mn1.5Ox resulted in revealing formation of a new oxide phase Sr6.3Rh2.35Mn2.35O9 related to quasi-unidimensional family A3n+3mA'nВ3m+nO9m+6n at n = 1 and m = 1. Its structural characteristics and magnetic properties are studied. X-ray data of the obtained phase is indicated on the basis of trigonal cell (spatial group P321) with the parameters: a 9.6239(4) Å; с1 4.1130(4) Å, с2 2.4946(2) Å. Manganese and rhodium exist in the compound as the cations Mn4+, Rh3+ and Rh4+, as follows from the data of measuring of magnetic susceptibility in the range 2–300 K Полный текст |