S 98 Synthesis and Structure of Bilayered Manganites Based on Ca3Mn2O7 with the Simultaneous Substitution of Calcium by Lanthanum and Strontium / S. L. Petukhov, E. V. Vladimirova, B. V. Slobodin, L. L. Surat // Russian Journal of Inorganic Chemistry. - 2006. - vol. 51, № 1. - P23-26 : il. - Bibliogr. : p. 26 (9 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): МАНГАНИТЫ ДВУХСЛОЙНЫЕ -- ЛАНТАН -- СТРОНЦИЙ -- КАЛЬЦИЙ Аннотация: A tetragonal (space group I4/mmm) solid solution La2 − 2x(Ca1 − ySry)1 + 2xMn2O7 based on the Raddlesden–Popper phase (n = 2), which is formed by the simultaneous substitution of calcium in Ca3Mn2O7 by strontium and lanthanum, is synthesized by high-temperature annealing of La2O3, Mn2O3, CaCO3, and SrCO3 mixtures (1500°C, air). The concentration area of the solid solution in the scheme is a pentagon, whose corners correspond to the manganites Ca3Mn2O7, Ca0.75Sr2.25Mn2O7, La0.2Sr2.8Mn2O7, La1.6Sr1.4Mn2O7, and LaCa2Mn2O7 Полный текст |