A 10 A Study of the Cerium Valence in Multinary Garnet Compounds / N. N. Efremova, N. I. Lobachevskaya, V. I. Nefedov, L. D. Finkel’shtein, V. G. Bamburov // Russian Journal of Inorganic Chemistry. - 2006. - Vol. 51, № 2. - P277-280 : il. - Bibliogr. : p. 280 (6 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ЦЕРИЙ -- ГРАНАТЫ МНОГОКОМПОНЕНТНЫЕ Аннотация: The valence state of cerium ions in the ferrite garnets {Gd1.96BiCe0.04}Ga1.2Fe3.8O12,{GdBiCe 0.5Ca0.5}Ga1.2Fe3.8O12, and {GdBiCe0.25Ca0.25}Ga1.2Fe.8O12 was studied by L3 X-ray absorption spectroscopy. Information on the change in the chemical bonding in ferrite garnets upon the violation of lattice completeness was obtained from the shifts of absorption maxima Полный текст |