Вид документа : Статья из журнала Шифр издания : 54/S 89 Автор(ы) : Kovaleva E. G., Molochnikov L. S., Kharchuk V. G., Kuznetsova O. V., Shishmakov A. B., Yanchenko M. Yu., Buldakova L. Yu., Zhdanov I. N., Mikushina Yu. V., Petrov L. A. Заглавие : Structure and Catalytic Properties of a Cu2+-Containing Hydrogel of Zirconium Dioxide Место публикации : Kinetics and Catalysis (Translation of Kinetika i Kataliz). - 2004. - Vol. 45, № 5. - С. 752-758 Примечания : Библиогр. : с. 758 (17 назв.) ББК : 54 Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ Ключевые слова (''Своб.индексиров.''): каталитические свойства--медь двухвалентная--диоксид циркония Аннотация: The distribution of Cu2+ ions in ZrO2 and sulfated ZrO2 hydrogel phases was studied by EPR spectroscopy and voltammetry. The formation of the following three types of copper structures was observed mononuclear Cu2+ complexes (A), magnetic associates (B), and Cu2+ compounds (C) that gave no EPR signals under the conditions used in the spectroscopic measurements. The specific catalytic activity of various Cu2+ compounds in the liquid-phase reaction of 2,3,5-trimethyl-1,4-hydroquinone oxidation was determined. The copper complexes C were found to exhibit the highest catalytic activity Держатели документа: Центральная научная библиотека УрО РАН Доп.точки доступа: Kovaleva, E. G.; Molochnikov, L. S.; Kharchuk, V. G.; Kuznetsova, O. V.; Shishmakov, A. B.; Yanchenko, M. Yu.; Buldakova, L. Yu.; Zhdanov, I. N.; Mikushina, Yu. V.; Petrov, L. A.