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Труды сотрудников Института горного дела УрО РАН
Труды сотрудников Института органического синтеза УрО РАН
Труды сотрудников Института теплофизики УрО РАН
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Труды сотрудников ЦНБ УрО РАН
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Каталог библиотеки ИЭРиЖ УрО РАН
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1.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis of fluorine-containing quinoline-2,3-dicarboxylates from products of vicarious nucleophilic substitution of hydrogen in 3-fluoronitroarenes [Electronic resource] / S. K. Kotovskaya, G. A. Zhumabaeva, V. N. Charushin, O. N. Chupakhin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2009. - Vol. 58, № 1. - P170-175
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of 3-fluoro-4-R-6-phenylsulfonylmethylnitrobenzenes with dimethyl fumarate or diethyl maleate in acetonitrile in the presence of an excess of K2CO3 and a catalytic amount of 18-crown-6 afforded mixtures of dialkyl 6-R-7-fluoro- and dialkyl 6-R-7-phenylsulfonylquinoline-2,3-carboxylate N-oxides, as well as dialkyl 6-R-7-fiuoro- quinoline-2,3-carboxylates (alkyl is methyl or ethyl), which were resolved by column chromatography and identified by 1H NMR spectroscopy and X-ray diffraction

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2009, 58 (1), 170-175.pdf
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2.
Инвентарный номер: нет.
   
   F 70

   
    Fluorine-containing quinazolines annulated at the pyrimidine ring [Electronic resource] / E. V. Nosova, A. A. Laeva, T. V. Trashakhova, G. N. Lipunova, P. A. Slepukhin, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2009. - Vol. 58, № 6. - P1303-1308
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Fluorine-containing quinazolines annulated at the sides [a] and [c] were synthesized by the reaction of 2- and 4-hydrazino-substituted quinazolines with aldehydes and subsequent oxidative cyclization. Annulation at the side [b] was performed by alkylation of 2-alkylthio-4(3H)-quinazolinones with bromoethanol and ipso-substitution of the alkylthio group

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2009, 58 (6), 1303-1308.pdf
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3.
Инвентарный номер: нет.
   
   F 98

   
    Fused polycyclic nitrogen-containing heterocycles. 21. Condensation of 4-hydroxy-3,5-diphenyl-2-phenyliminothiazolidine with 5-fluoro-4-morpholino- and 4-(4-methylpiperazino)-1,2-phenylenediamines [Electronic resource] / V. A. Mamedov, N. A. Zhukova, T. N. Beschastnova, A. A. Balandina, A. T. Gubaidullin, S. K. Kotovskaya, Sh. K. Latypov, Ya. A. Levin, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2009. - Vol. 58, № 1. - P203-211
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The condensation of 4-hydroxy-3,5-diphenyl-2-phenyliminothiazolidine with 5-fluoro-4-morpholino- and 5-fluoro-4-(4-methylpiperazino)-1,2-phenylenediamines leads to region-isomeric thiazolo[3,4-a]quinoxalines differing in substituents in positions 7 and 8 of the benzene ring. From the ratio of isomers formed it follows that the mesomeric effect of a fluorine atom in 1,2-phenylenediamines is comparable with the influence of an aminosubstituent

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2009, 58 (1), 203-211.pdf
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4.
Инвентарный номер: нет.
   
   E 27

   
    Effective fluoroalkylation of aldehydes by delta-perfluoroalkyl-iron compounds [Text] / V. G. Ratner, V. B. Korolev, D. L. Chizhov, K. I. Pashkevich // Journal of Fluorine Chemistry. - 1992. - Vol. 58, № 2-3. - P355
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Organoiron compounds with ?-perfluoroalkyl-iron bonds are well-known and common compounds convenient to prepare and handle. However, their application in organic synthesis was restricted to the introduction of fluoroalkyl group only into electron rich organic molecules such as arenes and thiols

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5.
Инвентарный номер: нет.
   
   F 70

   
    Fluorine-containing heterocycles. XVIII. Monofluoro derivatives of quinazolines and 1,3-benzothiazin-4-ones [Electronic resource] / E. V. Nosova, A. A. Laeva, T. V. Trashakhova, A. V. Golovchenko, G. N. Lipunova, P. A. Slepukhin, V. N. Charushin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2009. - Vol. 45, № 6. - P904-912
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 5- and 7-Fluoro-substituted quinazolines and 1,3-benzothiazin-4-ones were synthesized starting from 2-amino-6-fluorobenzonitrile and mono- and difluoro-substituted benzoic acid derivatives. The reactivities of di- and tetrafluoro-substituted benzoyl chlorides and benzoyl isothiocyanates in cyclocondensations leading to fluorinated quinazolines and 1,3-benzothiazines were compared

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2009, 45 (6), 904.pdf
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6.
Инвентарный номер: нет.
   
   A 53

   
    An efficient synthesis of alkylfluoroalkylketones [Text] / O. G. Khomutov, V. I. Filyakova, A. V. Kutchin, K. I. Pashkevich // Journal of Fluorine Chemistry. - 1992. - Vol. 58, № 2-3. - P161
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Interaction of fluoroacyl chlorides with lithium tetraalkylaluminates II prepared by the hydroalumination of alkenes I results in fluorinated ketones III with yields of 65–70%.??RF = CF3, H(CF2)2, C4F9, C6F13 R1 = C3H7, C4H9, C6H13, C7H15??The reaction is simple and does not require an argon atmosphere, as is needed for most reactions of organoaluminum compounds????

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7.
Инвентарный номер: нет.
   
   R 30

   
    Reactions of 2-ethoxycarbonyl(carboxy)-5,6,7,8-tetrafluorochromones with N-nucleophiles [Electronic resource] / V. I. Saloutin, I. T. Bazyl, Z. E. Skryabina, O. N. Chupakhin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1994. - Vol. 43, № 5. - P849-853
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
2-ETHOXYCARBONYL(CARBOXY)-5,6,7,8-TETRAFLUOROCHROMONES -- N-NUCLEOPHILES -- ETHYLENEDIAMINE -- AMINES -- NUCLEOPHILIC REPLACEMENT
Аннотация: The direction of reactions of 2-ethoxycarbonyl-5,6,7,8-tetrafluoro- and 2-carboxy-5,6,7,8-tetrafluorochromones with ammonia, methylamine, hexylamine, and aniline depends on the inductive effect of the substituent at position C-2 of the chromone and on the basicity of the amine. Nucleophilic aromatic substitution of a fluorine atom takes place in the interaction of 2-ethoxycarbonyl-5,6,7,8-tetrafluorochromone with secondary amines (morpholine, N-methylpiperazine) and ethylenediamine.

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\1994, 43 (5), 849.pdf
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8.
Инвентарный номер: нет.
   
   K 42

    Khomutov, O. G.
    Selective reduction of derivatives of fluorinated beta-diketones [Text] / O. G. Khomutov, V. I. Filyakova, K. I. Pashkevich // Journal of Fluorine Chemistry. - 1992. - Vol. 58, № 2-3. - P351
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reduction of fluorinated ?-diketones (DK) is known to give ?-diols [G. Swalens, M. Anteunis and D. Tavernier, Bull. Soc. Chim. Belg., 79 (1970) 441–450] and ?-hydroxyketones (HK) II [A.L. Henne and P.E. Hinkamp, J. Am. Chem. Soc., 76 (1954) 5147]. We have established that the lithium salts (Ia) as well as chelate compounds of DK with zinc (Ib) and aluminium (Ic) undergo selective reduction with LiAlh4 to HK III. Salts (Id) and chelate compounds (If) are not reduced under the same conditions

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9.
Инвентарный номер: нет.
   
   S 89

   
    Structures of Ni(II), Pd(II) and Cu(II) complexes with 1,2-bis(5,5,5-trifluoro-4-oxopent-2-en-2-amino)benzene [Electronic resource] / D. L. Chizhov, E. F. Khmara, P. A. Slepukhin, V. I. Filyakova, V. N. Charushin // Journal of Structural Chemistry. - 2010. - Vol. 51, № 2. - P288-295
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
Cu(II) COMPLEXES -- SYNTHESIS -- X-RAY CRYSTALLOGRAPHY ????
Аннотация: A new fluorine-containing tetradentate ligand 1,2-bis(5,5,5-trifluoro-4-oxopent-2-en-2-amino)benzene and its complexes with Ni(II), Pd(II) and Cu(II) are characterized by single crystal X-ray diffraction. It is found that the enaminoketone fragments of the ligand are identical in bond lengths and angles; they are almost planar, and make the angles of 51.3° to the plane of the benzene ring. The structures of Ni(II), Pd(II), and Cu(II) complexes are similar and have a saddle-shape configuration. The metal ions have square planar coordination and are located almost in the center of the N2O2 square. The average M-N bond lengths are longer than M-O ones by 0.014 A and 0.034 A for the Ni(II) and Cu(II) complexes respectively, while in the Pd(II) complex, M-O is longer than M-N by 0.029 A. The average chelate angles N-M-O in the complexes are: N-Ni-O 95.12°; N-Pd-O 95.68°; N-Cu-O 93.88

\\\\Expert2\\nbo\\Journal of Structural Chemistry\\2010, V. 51, N 2, p.288-295.pdf
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10.
Инвентарный номер: нет.
   
   F 70

   
    Fluorinated azines and benzazines containing oxygen or sulfur atoms [Text] / E. V. Nosova, G. N. Lipunova, V. N. Charushin, O. N. Chupakhin // Journal of Fluorine Chemistry. - 2010. - Vol. 131, № 12. - P1267-1288
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: In the frames of this review article the recently obtained data on synthetic approaches to fluorinated oxa(thia)azines and benzazines, their chemical properties, structure, and biological activity have been analyzed

\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2010, v. 131, p.1267.pdf
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11.
Инвентарный номер: нет.
   
   T 86

   
    Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N?-1,2-phenylen-bis(beta-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes [Text] / D. L. Chizhov, M. G. Pervova, M. A. Samorukova, E. F. Khmara, V. I. Filyakova, V. I. Saloutin, V. N. Charushin // Journal of Fluorine Chemistry. - 2011. - Vol. 132, № 6. - P394-401. - Bibliogr. : p. 401 (19 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: An effecient synthetic method for fluorinated tridentate ?-aminoenones and tetradentate bis(?-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(?-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described

\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2011, v. 132, p.394.pdf
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12.
Инвентарный номер: нет.
   
   S 17

    Saloutin, V. I.
    Fluorinated 2-methylidene-1,3-dicarbonyl compounds in organic synthesis [Text] / V. I. Saloutin, Ya. V. Burgart, O. N. Chupakhin // VIII Regular German-Russian-Ukrainian Symposium On Fluorine Chemistry, Zvenigorod, October 11-15, 2010 : abstr. - Zvenigorod, Russia, 2010. - PL-04
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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13.
Инвентарный номер: нет.
   
   B 62

   
    Bis(acetylaryl) podands in the synthesis of fluorine-containing bis(beta-diketones) joined by a polyether spacer [Electronic resource] / D. L. Chizhov, P. A. Slepukhin, I. G. Ovchinnikova, O. V. Fedorova, G. L. Rusinov, V. I. Filyakova, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2010. - Vol. 59, № 11. - P2122-2125 : рис., табл. - Bibliogr. : p. 2125 (14 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: O-Alkylation of 2-acetylphenols with ?,?-dichloro derivatives of oligoethylene glycols in the presence of KOH and Al2O3 in DMF gave the corresponding podands. Their condensation with ethyl trifluoroacetate afforded fluorine-containing bis(?-diketones) with the aryl fragments linked by conformationally flexible polyether spacers

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2010, 59 (11), 2122-2125.pdf
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14.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis and antitumor activity of fluorinated derivatives of [i,j]-annelated quinolones [Electronic resource] / G. N. Lipunova, E. V. Nosova, L. P. Sidorova, V. N. Charushin // Pharmaceutical Chemistry Journal. - 2011. - Vol. 45, № 4. - P208-210 : ил. - Bibliogr. : p. 210 (7 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Tri- and pentacyclic fluoroquinolones were synthesized by intramolecular cyclization of the corresponding 3-hydrazinopolyfluorobenzoylacrylates followed by substitution of fluorine atoms by amine residues. The antitumor activity of the resulting compounds was studied at the National Cancer Institute using cultures of 60 cell lines of nine groups, including leukemia, lung tumor, large intestine tumor, CNS tumor, melanoma, ovary tumor, renal tumor, prostate tumor, and breast tumor. Relationships between structure and antitumor activity were analyzed. In vivo experimental data from hollow fiber tests are presented for two derivatives

\\\\Expert2\\nbo\\Pharmaceutical Chemistry Journal\\2011, 45 (4), 208.pdf
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15.
Инвентарный номер: нет.
   

   
    2,3-Epoxyperfluoro-2-methylpentane in reactions with urea and thiourea [Electronic resource] / T. I. Filyakova, V. I. Saloutin, A. Ya. Zapevalov, P. A. Slepukhin, M. I. Kodess, V. I. Saloutin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2011. - Vol. 47, № 5. - P650-658 : рис., табл. - Bibliogr. : p. 658 (24 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 2,3-Epoxyperfluoro-2-methylpentane reacts with thiourea in protic (methanol, 2-propanol) and aprotic (dioxane) solvents, and also with urea in acetonitrile affording unexpected products: 1-(2,2,3,3,3-pentafluoropropionyl)-2-(2,2,2-trifluoro-1-trifluoro-methylethyl)isothiourea, and 1-(2,2,3,3,3-pentafluoropropionyl)-3-(2,2,2-trifluoro-1-trifluoro-methylethyl)urea respectively that result from the rearrangement of the intermediately formed ketone in the process of the intramolecular “haloform” cleavage. At the same time in dioxane the 2,3-epoxyperfluoro-2-methylpentane reacts with urea with the formation of a heterocyclic compound, 2-amino-4-pentafluoroethyl-5,5-bis(trifluoromethyl)-4,5-dihydrooxazol-4-ol. From 1-(2,2,3,3,3-pentafluoropropionyl)-2-(2,2,2-trifluoro-1-trifluoromethylethyl)isothiourea and Cu(OAc)2 a stable fluorine-containing chelate complex was obtained

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2011, 47 (5), 650-658.pdf
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16.
Инвентарный номер: нет.
   
   S 53

    Shcherbakov, K. V.
    Interaction of fluorinated 4-hydrohycoumarins and 2-ethoxycarbonylchromone with aniline [Text] : доклад, тезисы доклада / K. V. Shcherbakov, Ya. V. Burgart, V. I. Saloutin // 17th International Symposium on Fluorine Chemistry, Shanghai, China, July 24-29 2005 : abstract book. - Shanghai, 2005. - P42 (A-O-09) : рис.
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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17.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis of 2,6-bis(fluoroalkyl)-2,6-dihydroxytetrahydro-2H-pyran-3,5-dicarboxylates from aldehydes and fluorinated beta-oxo esters in the presence of ionic liquid-K2CO3 as catalytic system [Electronic resource] / S. G. Zlotin, G. V. Kryshtal’, G. M. Zhdankina, A. V. Ignatenko, Ya. V. Burgart, V. I. Saloutin, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2010. - Vol. 46, № 4. - P468-473 : рис., табл. - Bibliogr. : p. 472-473 (35 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
DICARBOXYLATES -- ALDEHYDES -- ESTERS -- CATALYTIC SYSTEM
Аннотация: An efficient procedure has been developed for the synthesis of 4-substituted 2,6-bis(fluoroalkyl)-2,6-dihydroxytetrahydro-2H-pyran-3,5-dicarboxylates by reactions of aldehydes with fluorine-containing ?-oxo esters in heterogeneous catalytic system 1-butyl-3-methylimidazolium tetrafluoroborate [bmim][BF4]-K2CO3 activated by ultrasound. The system retains its catalytic activity for three reaction cycles.

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2010, 46 (4), 468-473.pdf
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18.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis of nickel(II) chelates of fluoroalkyl-containing 2,2-(4,4-diphenyldihydraono)-bis(1,2,3-triketones) [Text] : доклад, тезисы доклада / V. I. Saloutin, I. V. Shchur, O. G. Khudina, Ya. V. Burgart // 17th International Symposium on Fluorine Chemistry, Shanghai, China, July 24-29 2005 : abstract book. - Shanghai, 2005. - 244 (P-II-11) : рис.
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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19.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis and transformations of 3-fluoroalkyl-2-(het)arylhydrazon-1,3-dicarbonyl compounds [Text] / E. V. Shchegol'kov, Ya. V. Burgart, O. G. Khudina, V. I. Saloutin // VIII Regular German-Russian-Ukrainian Symposium On Fluorine Chemistry, Zvenigorod, October 11-15, 2010 : abstr. - Zvenigorod, Russia, 2010. - PL-30
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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20.
Инвентарный номер: нет.
   
   S 98

   
    Synthesis of heteroannelated pyrimidines on the base of 2-aryliden-2-polyfluoroacyl esters [Text] : доклад, тезисы доклада / V. I. Saloutin, M. V. Pryadeina, Ya. V. Burgart, E. V. Sadtchikova, E. N. Ulomskii // 17th International Symposium on Fluorine Chemistry, Shanghai, China, July 24-29 2005 : abstract book. - Shanghai, 2005. - 245 (P-II-12) : рис.
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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