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Каталог книг и продолжающихся изданий
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Каталог диссертаций и авторефератов диссертаций УрО РАН
Каталог препринтов УрО РАН (1975 г. - )
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Изобретения уральских ученых
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Нанотехнологии
Демидовские премии
Гибель династии Романовых
История Урала
Личная библиотека С. В. Вонсовского
Книжная коллекция Шубиных
Труды Института высокотемпературной электрохимии УрО РАН
Труды Института истории и археологии УрО РАН
Труды сотрудников Института горного дела УрО РАН
Труды сотрудников Института органического синтеза УрО РАН
Труды сотрудников Института теплофизики УрО РАН
Труды сотрудников Института химии твердого тела УрО РАН
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Труды сотрудников ЦНБ УрО РАН
Публикации Черешнева В.А.
Публикации Чарушина В.Н.
Каталог библиотеки ИЭРиЖ УрО РАН
Электронная энциклопедия «Дискурсология»
Библиометрия
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 Найдено в других БД:Каталог книг и продолжающихся изданий (36)Каталог препринтов УрО РАН (1975 г. - ) (1)Нанотехнологии (1)Труды Института высокотемпературной электрохимии УрО РАН (2)Труды сотрудников Института теплофизики УрО РАН (84)Труды сотрудников Института химии твердого тела УрО РАН (21)Расплавы (4)Публикации Черешнева В.А. (1)Публикации Чарушина В.Н. (18)Каталог библиотеки ИЭРиЖ УрО РАН (2)
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Общее количество найденных документов : 42
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1.

Вид документа : Статья из журнала
Шифр издания : 54/A 10
Автор(ы) : Bazhin D. N., Kudyakova Yu.S., Roeschenthaler G.-V., Burgart Ya. V., Slepukhin P. A., Isenov M. L., Saloutin V. I., Charushin V. N.
Заглавие : A Convenient Approach to CF3-Containing N-Heterocycles Based on 2-Methoxy-2-methyl-5-(trifluoromethyl)furan-3(2H)-one [Электронный ресурс]
Место публикации : European Journal of Organic Chemistry. - 2015. - № 23. - С. 5236-5245
Систем. требования: http://apps.webofknowledge.com/
Примечания : Bibliogr. : p. 5245 (23 ref.). - 18.01.16
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): nitrogen heterocycles --fluorine--oxygen heterocycles
Аннотация: New synthetic routes to trifluoromethylated N-heterocycles based on condensations of 2-methoxy-2-methyl-5-(trifluoromethyl)furan-3(2H)-one with bifunctional N-nucleophiles are described. For the first time, trifluoromethyl-containing pyrazoles, pyrazolines and isoxazolines bearing hydrazone or oxime groups could be obtained by a one-pot strategy based on reactions of 5-(trifluoromethyl)furan-3(2H)-one with two equivalents of the corresponding hydrazines or hydroxylamine in the presence of an acid. The interaction of furan-3(2H)-one with ureas proceeded under mild conditions to furnish 1H-furo[2,3-d]imidazol-2(3H)-one derivatives in good yield. Further, a trifluoromethyl-containing quinoxaline derivative was obtained by condensation of furan-3(2H)-one with ortho-phenylenediamine.
\\\\expert2\\nbo\\European Journal of Organic Chemistry\\2015, №23. p.5236-5245.pdf
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2.

Вид документа : Статья из журнала
Шифр издания : Г/A 22
Автор(ы) : Puzyrev I. S., Andreikov E. I., Osipova V. A., Zakharova G. S., Podval'naya N. V.
Заглавие : Adsorption properties of mesoporous carbon synthesized by pyrolysis of zinc glycerolate
Место публикации : Russian chemical bulletin. - 2021. - Vol. 70, № 5. - С. 805-810
ББК : Г
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Mesoporous carbon of lamellar morphology was synthesized by the thermal decomposition of zinc glycerolate in an inert atmosphere followed by the removal of zinc oxide from the ZnO/C composite. The obtained material was characterized by scanning electron microscopy, Raman spectroscopy, and low-temperature adsorption of nitrogen. Mesoporous carbon is remarkable for a high adsorption rate of methylene blue dye from aqueous solutions with the maximum adsorption capacity toward the dye equal to 1680 mg g−1.
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3.

Вид документа : Статья из журнала
Шифр издания : 54/A 53
Автор(ы) : Bakharev V. V., Parfenov V. E., Ul’yankina I. V., Zavodskskaya A. V., Gidaspov A. A., Slepukhin P. A.
Заглавие : An unexpected direction of the reaction of hydrazino-1,3,5-triazines with formic acid. Synthesis of (4H-1,2,4-triazol-3-yl)guanidines [Электронный ресурс]
Место публикации : Chemistry of Heterocyclic Compounds. - 2015. - Vol. 51, № 11/12
Систем. требования: http://link.springer.com/article/10.1007/s10593-016-1805-y
Примечания : Bibliogr. : p. 1018 (10 ref.). - 03.02.2016
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): nitrogen heterocycles --1,2,4-triazolylguanidines--dimroth rearrangement
Аннотация: A new direction of the reaction of 6-amino-substituted 4-hydrazino-1,3,5-triazin-2(1H)-ones with formic acid was found leading to the formation of N-substituted (4H-1,2,4-triazol-3-yl)guanidines together with the expected 5-amino-substituted 1,2,4-triazolo[1,5-a][1,3,5]-triazin-7-ones as a result of opening of the triazine ring and subsequent decarboxylation of an intermediate of the Dimroth rearrangement. The discovered reaction is of interest as a novel method for the synthesis of N-substituted (4H-1,2,4-triazol-3-yl)guanidines.
\\\\expert2\\nbo\\Chemistry of Heterocyclic Compounds\\2015, v.51, N 11-12, p. 1014-1018.pdf
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4.

Вид документа : Статья из журнала
Шифр издания : Г/A 99
Автор(ы) : Taniya O. S., Khasanov A. F., Varaksin M. V., Starnovskaya E. S., Krinochkin A. P., Savchuk M. I., Kopchuk D. S., Kovalev I. S., Nosova E. V., Zyryanov G. V., Chupakhin O. N., Kim G. A.
Заглавие : Azapyrene-based fluorophores: synthesis and photophysical properties
Место публикации : New Journal of Chemistry. - 2021. - Vol. 45, № 45. - С. 20955-20971
ББК : Г
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Azapyrenes are the nitrogen isosteres of pyrene. Based on theoretical and experimental studies, electron–acceptor azapyrene domains may be considered as convenient scaffolds for constructing a large variety of “push–pull” π-conjugated chromophores with pronounced ICT properties. Over the past decade, due to the unrelenting interest in functional materials and modern methodologies such as cross-coupling, peri-annulation, direct C–H-functionalization, etc., methods for the synthesis of aryl(alkyl) K-functionalized azapyrenes and other derivatives have been developed, and their photophysical and electrochemical properties have been studied. This short review aims at critical analysis of the best known/modern methods for the preparation of functionalized azapyrene derivatives, as well as an assessment of their photophysical/electrochemical properties in comparison with the structural and electronic properties of the parent pyrene.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Charushin V. N., Titova Y. A., Milaeva E. R.
Заглавие : Chemical elements in medicine
Место публикации : Herald of the Russian academy of sciences. - 2020. - Vol. 90, № 2. - С. 229-238
Ключевые слова (''Своб.индексиров.''): beta-lactam antibiotics--boron neutron capture therapy--fluoroquinolones--heterocycles
Аннотация: A brief review of chemical elements, compounds from which find application in medicine, ranging from the commonly occurring organogenic elements (carbon, hydrogen, nitrogen, oxygen, sulfur, and phosphorus), composing the structure of proteins and nucleic acids of the cells of living organisms and determining the genetic transmission, to native rarely encountered organic fluorine compounds, synthetic derivatives of which have become firmly ingrained in the arsenal of modern pharmaceutical drugs, is given. Strong emphasis is put on metalloproteins, which play a significant role in the biochemistry of vitally essential processes, as well as metal compounds that are widely used in medicine. Of particular importance are the chemical elements and the isotopes, compounds of which are employed in nuclear medicine for diagnostics and treatment of a wide range of diseases, oncological and cardiovascular in particular.
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6.

Вид документа :
Шифр издания : 54/C 75
Автор(ы) : Verbitskiy E. V., Rusinov G. L., Charushin V. N., Chupakhin O. N., Cheprakova E. M., Slepukhin P. A., Pervova M. G., Kodess M. I.
Заглавие : Consecutive S-N(H) and Suzuki–Miyaura Cross-Coupling Reactions – an Efficient Synthetic Strategy to Pyrimidines Bearing Pyrrole and Indole Fragments
Место публикации : European Journal of Organic Chemistry. - 2012. - Vol. 2012, №33. - С. 6612-6621
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): synthetic methods--cross-cou­pling--nitrogen heterocycles
Аннотация: The combination of the Suzuki–Miyaura cross-coupling and nucleophilic aromatic substitution of hydrogen reactions is a versatile tool for the syntheses of 4-(1R-pyrrol-2-yl)- and 4-(1R-indol-3-yl)-5-(hetero)aryl-substituted pyrimidines from commercially available 5-bromopyrimidine. The SNH [AE, (addition–elimination)] and SNH [AO, (addition–oxidation)] reactions of 5-bromopyrimidine with pyrroles and indoles were studied by gas chromatography–mass spectrometry. The structures of the intermediate σH adducts as well as the pyrrole-(hetero)arylpyrimidine and indole-(hetero)arylpyrimidine dyads were established for the first time by X-ray crystal structure analysis
\\\\Expert2\\nbo\\European Journal of Organic Chemistry\\2012, p.6612.pdf
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7.

Вид документа : Статья из журнала
Шифр издания : 54/R 30
Автор(ы) : Kozhevnikov D. N., Rusinov V. L., Chupakhin O. N., Makosza M., Rykowski A., Wolinska E.
Заглавие : Deoxygenative vs. vicarious nucleophilic substitution of hydrogen in reactions of 1,2,4-triazine 4-oxides with - alpha-halocarbanions
Место публикации : European Journal of Organic Chemistry. - 2002. - № 8. - С. 1412-1416
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The 3,6-diaryl-1,2,4-triazine 4-oxides 1a-e undergo a nucleophilic substitution of hydrogen with the -halomethyl aryl sulfones 2, 3 and 7 by two alternative pathways: vicarious nucleophilic substitution (VNS) and/or an intramolecular deoxygenative process. The former pathway is found to dominate in the reaction of 1 with bromomethyl tolyl sulfone (7) yielding the 5-tosylmethyl-1,2,4-triazine 4-oxides 6, while the reaction with the chloromethyl aryl sulfones 2 and 3 leads to the 5-arylsulfonylchloromethyl-1,2,4-triazines 4 and 5, respectively, as the products of deoxygenative substitution. The reaction of 6-phenyl-1,2,4-triazine 4-oxide (1f) with the chloromethyl aryl sulfones 2 and 3 proceeds differently. At low temperature (-75 C) the products of the VNS reaction at position 5 (6f and 12f) are formed. At room temperature the 7-chloro-1-hydroxy-3-phenyl-7-(arylsulfonyl)-1,4,5-triazahepta-1,3,6-trienes 10f and 11f are obtained by addition of the carbanions 2 and 3 in the 3-position, followed by the ring opening of the resulting adduct. © Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)????????
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Verbitskiy E. V., Rusinov G. L., Chupakhin O. N., Charushin V. N.
Заглавие : Design of fluorescent sensors based on azaheterocyclic push-pull systems towards nitroaromatic explosives and related compounds: a review
Место публикации : Dyes and pigments. - 2020. - Vol. 180. - С. 108414
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): nitroaromatic explosives--fluorescence quenching--pyridines--pyrazine--pyrimidines--triazines
Аннотация: Highly sensitive and selective detection of nitro containing high energy organic compounds such as picric acid (PA), 2,4,6-trinitrotoluene (TNT) and 2,4-dinitrotoluene (DNT) has become a challenging task due to concerns over national security, criminal investigations and environment protections. Among various known detection methods, fluorescence sensors have gained special attention in recent time. The family of fluorescent sensors based on push-pull systems that incorporate nitrogen heterocycles as an electron-withdrawing group have a growing interest due to their high sensitivity, selectivity and easy tuning. The fluorescent sensors discussed in this review are classified and organized according to used azaheterocyclic scaffold, their functionality and their ability to detect of nitroaromatics by fluorescence quenching.
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9.

Вид документа : Статья из журнала
Шифр издания : Г/E 27
Автор(ы) : Abu el-Soad A. M., Pestov A. V., Martemyanov N. A., Kovaleva E. G., Lazzara G., Cavallaro G.
Заглавие : Effect of polarity of solvent on silanization of halloysite nanoclay using (3-glycidyloxy propyl) trimethoxy silane
Место публикации : Journal of inorganic and organometallic polymers and materials. - 2021. - № 31. - С. 2569–2578
ББК : Г
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The grafting of silane groups on clay surfaces has been recently investigated in order to fabricate versatile compounds with new potential applications in materials science and ecological engineering. This work explored the influence of variety of solvents with variable polarity on the silanization of halloysite nanoclay (HNT) surface by (3-Glycidyloxy propyl) trimethoxy silane. To this purpose, the functionalization of HNT by 3-Glycidyloxypropyltrimethoxysilane (GOPTMS) has been conducted in Ethanol (polar protic solvent), Tetrahydrofuran (THF) and Acetonitrile (polar aprotic solvents), and Hexane, 1,4-Dioxane and Toluene (non polar solvents). The silane grafted materials were characterized by using several techniques, including Fourier Transform Infrared Spectroscopy (FT-IR), elemental analysis, Scanning Electron Microscopy (SEM), Thermogravimetry (TGA), X-ray Diffraction Analysis (XRD) and Nitrogen adsorption/desorption isotherms. The largest silane loading has been detected for the hybrid nanomaterials prepared in Hexane as a dispersing medium.
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10.

Вид документа : Статья из журнала
Шифр издания : 54/F 70
Автор(ы) : Boltacheva N. S., Fedorova O. V., Ovchinnikova I. G., Kazheva O. N., Chekhlov A. N., Dyachenko O. A., Rusinov G. L., Filyakova V. I., Charushin V. N.
Заглавие : Fluorinated lithium 1,3-diketonates as reagents to modify podands and crown-ethers
Место публикации : Journal of Fluorine Chemistry. - 2007. - Vol. 128, № 7. - С. 762-768
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Fluorinated enaminoketones, a new type of ligands, bearing two independent coordination centers (polyether's and fluorinated enaminoketones fragments) have been obtained. The crystal structure of the Cu(II) complex of 1,5-bis-[2-(4`,4`,4`-trifluoro-1`-methyl-3`oxo-but-1`-enylamino)-phenoxy]-3-oxapentane (10) has been elucidated by X-ray crystallography. The results obtained show that the complex 10 consists of two crystallographically independent molecules C26H24CuF6N2O5 (A and B), and the metal atom in the complex 10 has four-coordinated arrangement, as a polyhedron with a distorted square with two nitrogen and two oxygen atoms located in corners.
\\\\expert2\\nbo\\Journal of Fluorine Chemistry\\2007, v.128. p.762.pdf
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