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Каталог библиотеки ИЭРиЖ УрО РАН
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1.
Инвентарный номер: нет.
   
   A 10

   
    A new anionic palladium(II) complex as a highly efficient cross-coupling catalyst [Text] : доклад, тезисы доклада / A. Mechaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova, O. N. Chupakhin // 3rd EuCheMS Chemistry Congress "Chemistry - the Creative Force", Nuremberg, 29 august-02 ceptember2010. - Nuremberg, 2010. - P1353 : il.
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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2.
Инвентарный номер: нет.
   
   A 10

   
    A new route towards dithienoquinazoline and benzo[f]thieno[3,2-h]quinazoline systems using Pd-catalyzed intramolecular cyclization under microwave irradiation [Electronic resource] / E. V. Verbitskiy, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // ARKIVOC. - 2016. - № 4. - С. 204-216
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PYRIMIDINES -- INTRAMOLECULAR CYCLIZATIONS -- FUSED RING SYSTEMS -- THIENOACENES
Аннотация: A novel synthetic route to novel thienoacene systems bearing a fused pyrimidine ring is proposed. The commercially available 5-bromopyrimidine is used as the starting material to obtain various dithienoquinazoline and benzo[f]thieno[3,2-h] quinazoline systems through the Suzuki cross-coupling, nucleophilic aromatic substitution of hydrogen (the S-N(H) reaction), and finally palladium-catalyzed intramolecular cyclization under microwave irradiation. Redox properties of some of the new compounds have been investigated. The data obtained show that these systems have plausible potential for use in organic electronic applications.

\\\\expert2\\NBO\\ARKIVOC\\2016, p.204-216.pdf
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3.
Инвентарный номер: нет.
   
   A 10

   
    A new synthetic approach to fused nine-ring systems of the indolo[3,2-b] carbazole family through double Pd-catalyzed intramolecular C-H arylation [Electronic resource] / R. A. Irgashev, N. A. Kazin, G. A. Kim, G. L. Rusinov, V. N. Charushin // RSC Advances. - 2016. - Vol. 6, № 74. - С. 70106-70116
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
IGHT-EMITTING-DIODES -- BIPOLAR HOST MATERIALS -- HOLE-TRANSPORTING MATERIALS
Аннотация: A series of new polycyclic compounds bearing the 5,11-dihydroindolo[3,2-b] carbazole ring system, as the common motif of their nine-ring scaffolds, has been successfully prepared with the usage of an efficient two-step strategy, based on the double Friedel-Crafts acylation of 5,11-dihexyl-6,12-di(hetero) aryl-substituted 5,11-dihydroindolo[3,2-b] carbazoles with 2-iodobenzoyl chloride in the presence of SnCl4, followed by regioselective palladium-catalyzed cyclization of the obtained 2,8-bis(2-iodobenzoyl) derivatives into the desired fused 9H-fluoren-9-ones. Some modifications of these nine-ring structures have been performed to afford compounds of the same family bearing the 9H-fluorene fragments. Basic photophysical and electrochemical properties as well as thermal stability of the new fused indolo[3,2-b] carbazole derivatives have been determined.

\\\\expert2\\NBO\\RSC Advances\\2016. Vol. 6, N 74. P. 70106.pdf
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4.
Инвентарный номер: нет.
   

   
    Advances in transition-metal catalyzed carbonylative suzuki-miyaura coupling reaction: an update / D. Bhattacherjee, M. Rahman, S. Ghosh [et al.] // Advanced synthesis and catalysis. - 2021. - Vol. 363, № 6. - P1597-1624
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CARBONYLATION -- SUZUKI-MIYAURA COUPLING -- TRANSITION-METAL CATALYSIS
Аннотация: Transition metals have been an indispensable component of modern catalysis and among these palladium is the top-ranked choice of chemists as a catalyst. After the several important developments of palladium catalysed C−C cross-coupling reactions, carbonylative transformations have been realised as an attractive post modification of these reactions. Carbonylative Suzuki-Miyaura coupling reaction is among such transformations for direct incorporation of CO fragment for the preparation of biaryl or aryl/alkyl ketones via transition-metal catalysis. Ketone functionality is basically a valuable building block having huge pharmaceutical and agrochemical applications. Moreover, carbonylative Suzuki-Miyaura coupling is also used in the synthesis of various natural bioactive molecules through the direct joining of molecular fragments via CO bridge. In this review, the past decade developments in the carbonylative Suzuki-Miyaura coupling reactions are documented in detail with modern approaches in transition-metal catalysis.

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5.
Инвентарный номер: нет.
   
   A 89

   
    Asymmetric cyclopalladation of 6-ferrocenyl-2,2-bipyridine and 2-ferrocenyl-1,10-phenanthroline [Electronic resource] / L. A. Bulygina, V. I. Sokolov, I. A. Utepova, V. L. Rusinov, O. N. Chupakhin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2007. - Vol. 56, № 5. - P1080-1082
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Cyclopalladation of 6-ferrocenyl-2,2?-bipyridine and 2-ferrocenyl-1,10-phenanthroline in the presence of the N-acylamino acid salt as the asymmetric catalyst was performed. Some reactions of the resulting bicyclic palladium derivatives with tridentate (N,N,C) ligands were studied

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2007, 56 (5), 1080-1082.pdf
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6.
Инвентарный номер: нет.
   
   C 21

   
    Carboxyethenylation of polychlorobiphenyls / A. Mechaev, A. V. Pestov, Yu. G. Yatluk, M. G. Pervova, A. A. Panyukova // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2013. - Vol.49, №5. - С. 691-695. - Библиогр.: с. 695 (12 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BUTYL ACRYLATE -- PALLADIUM CATALYSTS -- POLYCHLOROBIPHENYLS
Аннотация: For the first time 2-carboxyethenylation was performed with butyl acrylate in the presence of palladium catalysts of bromine derivatives of polychlorobiphenyls obtained by bromination of polychlorobiphenyls. The haloderivatives of the butyl phenylcinnamate are readily hydrolyzed and hydrodehalogenized affording a mixture of phenylhydrocinnamic acids

\\\\expert2\\NBO\\Russian Journal of Organic Chemistry\\2013, 49, (5), 691-695.pdf
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7.
Инвентарный номер: нет.
   
   C 52

   
    Chiral palladium complexes with monoterpenoids oximes [Electronic resource] / O. A. Gur'eva, O. A. Zalevskaya, L. L. Frolova, I. N. Alekseev, P. A. Slepukhin, A. V. Kuchin // Russian Journal of General Chemistry. - 2014. - Vol.84, №1. - С. 137-142. - Bibliogr. : p. 142 (16 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CIS-VERBANONE -- MENTHONE -- OXIMES
Аннотация: Oximes of cis-caran-4-one, 3α- and 3β-hydroxycaran-4-ones, cis-verbanone, menthone, and 2β-hydroxybornan-3-one have been synthesized. The obtained oximes react with lithium tetrachloropalladate to give new chiral palladium complexes containing mono-or bidentate oxime ligands

\\\\expert2\\nbo\\Russian Journal of General Chemistry\\2014, V. 84, N 1, p. 137–142.pdf
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8.
Инвентарный номер: нет.
   
   C 52

   
    Chiroptical properties and new derivatives of cyclopalladated 6-ferrocenyl-2,2-bipyridine. Molecular structure of a tert-butyl isocyanide derivative [Electronic resource] / L. A. Bulygina, Z. A. Starikova, K. K. Babievskii, I. A. Utepova, V. L. Rusinov, O. N. Chupakhin, V. I. Sokolov // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2008. - Vol. 57, № 10. - P2214-2216
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Optically active cyclopalladated 6-ferrocenyl-2,2?-bipyridine has been studied by circular dichroism and luminescent spectroscopy; a replacement of the chloride ion at palladium with the rhodanide ion and tert-butyl isocyanide molecule has been carried out; molecular structure of the product in the latter case has been determined by X-ray diffraction analysis

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2008, 57 (10), 2214-2216.pdf
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9.
Инвентарный номер: нет.
   
   D 62

   
    Direct C(sp2)-H Bond Functionalization in Cyclic Aldonitrones: Palladium(II)-Catalyzed Oxidative Cross-Coupling and Eliminative SNH Reactions / M. V. Varaksin, O. N. Chupakhin, V. N. Charushin, S. V. Mikhaylov, I. A. Utepova, B. A. Trofimov // 18th European Symposium on Organic Chemistry ESOC-2013, Marseille, France, 7-12 July 2013 : book of abstracts. - Marseille, France, 2013. - С. 329
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PALLADIUM(II) -- SNH REACTIONS -- CYCLIC ALDONITRONES

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10.
Инвентарный номер: нет.
   

   
    Effect of the degree of sulfoethylation of polyethylenimine on the selectivity of sorption of palladium(II) from binary solutions / E. I. Kapitanova, A. R. Sinelshchikova, Yu. S. Petrova [et al.] // Russian chemical bulletin. - 2021. - Vol. 70, № 6. - P1161-1166
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
POLYETHYLENIMINE -- SULFOETHYLATION -- SORPTION -- PLATINUM(IV) -- PALLADIUM(II) -- GOLD(III)

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11.
Инвентарный номер: нет.
   
   F 33

   
    Features of sorption preconcentration of noble metal ions with sulfoethylated amino polymers / L. M. Alifkhanova, K. Y. Lopunova, A. A. Marchuk [и др.] // Russian journal of inorganic chemistry. - 2021. - Vol. 66, № 6. - С. 909-915
ББК Г
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Dependencies for the sorption of palladium(II), gold(III), and platinum(IV) chloro complexes from individual and binary solutions with sorbents based on sulfoethylated polyallylamine and poly(aminostyrene) have been obtained. It has been found that predominant sorption mechanism is complexation with functional groups of the sorbents for gold(III) and palladium(II) and ion exchange for platinum(IV). It has been shown that increase in the sulfoethylation degree of aminopolymer matrix leads to decrease of platinum(IV) sorption and therefore, to increase in palladium(II) sorption selectivity relative to this ion. This effect is the largest for the sorbents based on polyallylamine. The conditions of quantitative desorption of the studied metals from sorbent surface have been determined. The sorption of gold(III) by the sorbent based on polyallylamine has been shown to be complicated by gold(III) reduction in sorbent phase.

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12.
Инвентарный номер: нет.
   
   F 76

   
    Formation of polynuclear palladium complexes with the benzimidazole-2-thiolate anion [Electronic resource] / M. O. Talismanova, A. A. Sidorov, G. G. Aleksandrov, V. N. Charushin, S. K. Kotovskaya, I. L. Eremenko, I. I. Moiseeva // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2008. - Vol. 57, № 1. - P47-55
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of palladium(II) salts with 2-mercaptobenzimidazole (HL) and its 5,6-difluorinated derivative (HLF) were investigated. In the presence of hydrochloric acid, PdCl2 and K2PdCl4 react with HL and HLF in the ethanol—water and acetonitrile—water systems to form the mono-nuclear dicationic complexes [Pd(HL)4]Cl2 (1) and [Pd(LF)4]Cl2 (2). In the absence of HCl, the reactions afford the tetranuclear complex Pd4[(L)2(3-S,N-(L))2(S,N-(L))4] (3). The reaction of triethylamine with an ethanolic solution of 3 leads to degradation of 3 and the formation of the lantern-type dinuclear complex Pd2[2-(L)4] (4), in which the palladium atoms are in the nonequivalent coordination environment, PdN4 and PdS4. The reaction of K2PdCl4 with HL or HLF in the THF—water or acetonitrile—water systems (for the reaction with HLF) in the presence of Et3N produces the lantern-type dinuclear complexes Pd2[(?S,N-(L3))4] and Pd2[(S,N)(LF))4] (5), in which the metal atoms are in the equivalent coordination environment (cis-PdN2S2)

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2008, 57 (1), 47.pdf
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13.
Инвентарный номер: нет.
   
   I-60

   
    Influence of the degree of chitosan sulfoethylation on the sorption of palladium(ii) chloride complexes from multicomponent solutions / E. I. Kapitanova, A. A. Ibragimova, Y. S. Petrova, A. V. Pestov, L. K. Neudachina // Russian Journal of Applied Chemistry. - 2018. - Vol. 91, № 2. - P297-303
ББК Г
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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14.
Инвентарный номер: нет.
   
   M 65

   
    Microwave-assisted palladium-catalyzed C–C coupling versus nucleophilic aromatic substitution of hydrogen (SNH) in 5-bromopyrimidine by action of bithiophene and its analogues [Электронный ресурс] / E. V. Verbitskiy, E. M. Cheprakova, E. F. Zhilina, M. I. Kodess, M. A. Ezhikova, M. G. Pervova, P. A. Slepukhin, V. N. Charushin // Tetrahedron. - 2013. - Vol.69, №25. - P5164-5172
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
C–H BOND ACTIVATIONS -- PYRIMIDINES -- PALLADIUM
Аннотация: 5-Bromopyrimidine reacts with 2,2′-bithiophene, [2,2′:5′,2″]terthiophene and 2-phenylthiophene in the presence of a palladium catalyst to give 5-(het)aryl substituted pyrimidines due to the palladium-catalyzed aryl–aryl C–C coupling. However 5-bromo-4-(het)aryl-pyrimidines have been prepared from the same starting materials through the SNH-reaction catalyzed by a Lewis acid. Conditions for both types of reactions were optimized. All components of the reaction mixtures, including by-products, have been elucidated by gas–liquid chromatography/mass-spectrometry. Evidence for the structure of 4- and 5-bithiophenyl-substituted pyrimidines has first been obtained by means of X-ray crystallography analysis. Molecular orbital calculations (TDDFT), as well as the redox and optical measurements for all new compounds have also been performed

\\\\Expert2\\NBO\\Tetrahedron\\2013, v. 68, p. 5164.pdf
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15.
Инвентарный номер: нет.
   
   N 10

   
    N-(2-(2-Pyridyl)ethyl)chitosan (PEC) for Pd(II) and Pt(IV) sorption from HCl solutions [] / L. A. Santos Sorena, M. Ruiz, A. V. Pestov, A. M. Sastre, Yu. G. Yatluk, E. Guibal // Cellulose. - 2010. - 6 December. - Online first : рис., табл.
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Chitosan was modified by grafting 2-pyridyl-ethyl moieties on the biopolymer backbone for the synthesis of a Platinum Group Metal (PGM) sorbent. The sorbent was tested for Pd(II) and Pt(IV) sorption from HCl solutions. Stable for HCl concentrations below 0.5 M, the sorbent reached sorption capacities as high as 3.2 and 2.6 mmol metal g1 for Pd(II) and Pt(IV), respectively. Metal sorption mainly proceeds by electrostatic attraction in acidic solutions, though a contribution of complexation mechanism cannot be totally rejected. The resistance to intraparticle diffusion is the main controlling mechanism for uptake kinetics. While agitation speed has a limited effect on kinetics, metal concentration and sorbent dosage have a greater effect on the kinetic profiles. The intraparticle diffusivity varies between 3 10?11 and 4.5 1010 m2 min1. Thiourea (combined with HCl solution) is used for Pd(II) and Pt(IV) desorption. The resin could be desorbed and recycled for a minimum of five cycles maintaining high efficiencies of sorption and desorption

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16.
Инвентарный номер: нет.
   
   N 10

   
    N-(2-(2-Pyridyl)ethyl)chitosan (PEC) for Pd(II) and Pt(IV) sorption from HCl solutions [Text] / L. A. Santos Sorena, M. Ruiz, A. V. Pestov, A. M. Sastre, Yu. G. Yatluk, E. Guibal // Cellulose. - 2011. - Vol. 18, № 2. - P309-325. - Bibliogr. : p. 324-325 (32 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Chitosan was modified by grafting 2-pyridyl-ethyl moieties on the biopolymer backbone for the synthesis of a Platinum Group Metal (PGM) sorbent. The sorbent was tested for Pd(II) and Pt(IV) sorption from HCl solutions. Stable for HCl concentrations below 0.5 M, the sorbent reached sorption capacities as high as 3.2 and 2.6 mmol metal g?1 for Pd(II) and Pt(IV), respectively. Metal sorption mainly proceeds by electrostatic attraction in acidic solutions, though a contribution of complexation mechanism cannot be totally rejected. The resistance to intraparticle diffusion is the main controlling mechanism for uptake kinetics. While agitation speed has a limited effect on kinetics, metal concentration and sorbent dosage have a greater effect on the kinetic profiles. The intraparticle diffusivity varies between 3 ? 10?11 and 4.5 ? 10?10 m2 min?1. Thiourea (combined with HCl solution) is used for Pd(II) and Pt(IV) desorption. The resin could be desorbed and recycled for a minimum of five cycles maintaining high efficiencies of sorption and desorption

\\\\Expert2\\nbo\\Cellulose\\2011, v.18, p. 309.pdf
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17.
Инвентарный номер: нет.
   
   N 10

   
    N-(2-(2-Pyridyl)ethyl)chitosan (PEC) for Pd(II) and Pt(IV) sorption from HCl solutions / L. A. Santos Sorena, M. Ruiz, A. V. Pestov, A. M. Sastre, Yu. G. Yatluk, E. Guibal // Cellulose. - 2011. - Vol. 18, № 2. - С. 309-325
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
CHITOSAN – PYRIDYL GROUPS -- PALLADIUM -- PLATINUM
Аннотация: Chitosan was modified by grafting 2-pyridyl-ethyl moieties on the biopolymer backbone for the synthesis of a Platinum Group Metal (PGM) sorbent. The sorbent was tested for Pd(II) and Pt(IV) sorption from HCl solutions. Stable for HCl concentrations below 0.5 M, the sorbent reached sorption capacities as high as 3.2 and 2.6 mmol metal g?1 for Pd(II) and Pt(IV), respectively. Metal sorption mainly proceeds by electrostatic attraction in acidic solutions, though a contribution of complexation mechanism cannot be totally rejected. The resistance to intraparticle diffusion is the main controlling mechanism for uptake kinetics. While agitation speed has a limited effect on kinetics, metal concentration and sorbent dosage have a greater effect on the kinetic profiles. The intraparticle diffusivity varies between 3 ? 10?11 and 4.5 10?10 m2 min?1. Thiourea (combined with HCl solution) is used for Pd(II) and Pt(IV) desorption. The resin could be desorbed and recycled for a minimum of five cycles maintaining high efficiencies of sorption and desorption. ??

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18.
Инвентарный номер: нет.
   

   
    Oxidative C–H functionalization of arenes: main tool of 21st century green chemistry. A review / A. V. Shchepochkin, F. V. Antipin, V. N. Charushin, O. N. Chupakhin // Doklady Chemistry. - 2021. - Vol. 499, № 1. - P123-157
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Recent advances in the field of direct oxidative C–H functionalization of inactivated arenes, as one of the main tools of green chemistry, are discussed. Examples of building carbon–carbon, carbon–oxygen, carbon–nitrogen, and carbon–sulfur bonds, using catalysis with palladium compounds, oxidation with hypervalent iodine derivatives, and through electrochemical and photochemical transformations, are given.

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19.
Инвентарный номер: нет.
   
   P 17

   
    Palladium and platinum sorption on a thiocarbamoyl-derivative of chitosan [Text] / A. Butewicz, K. Campos Galivan, A. V. Pestov, Yu. G. Yatluk, A. W. Trochimczuk, E. Guibal // Journal of Applied Polymer Science . - 2010. - Vol. 116, № 6. - P3318-3330 : рис.
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Immobilizing thiourea onto chitosan allowed using the polymer for the recovery of platinum groups metals (PGMs) in acidic solutions (up to 1–2M HCl concentrations). At low HCl concentration protonated amine groups may sorb chloroanionic metal species (electrostatic attraction mechanism); however, most of sorption proceeds through chelation on sulfur containing groups (less sensitive to acidic conditions). The bi-site Langmuir equation was used for fitting sorption isotherms. The sorption of PGMs was weakly affected by the composition of the solution (presence of high concentration of anions and base metals). Maximum sorption capacities for Pd(II) and Pt(IV) ranged between 274 and 330 mg g?1 in 0.25M HCl solutions and decreased to 150–198 mg g?1 in 2M HCl solutions: Pd(II) sorption was systematically higher than Pt(IV) sorption. The pseudo-second rate equation was used for modeling the uptake kinetics. Agitation speed hardly affected uptake kinetics indicating that external diffusion resistance is not the rate controlling step. Desorption yield higher than 85% were obtained using thiourea in 0.1M HCl solution. The adsorbents could be reused for at least three cycles

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20.
Инвентарный номер: нет.
   
   P 17

   
    Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one: Synthesis, structure, and catalytic activity / A. Mechaev, A. V. Pestov, P. A. Slepukhin, Yu. G. Yatluk, M. G. Pervova, M. A. Samorukova, O. N. Chupakhin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2011. - Vol.47, №9. - С. 1366-1369
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
HECK REACTION -- ARYL
Аннотация: Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (S (N) (H) reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2011, 47 (9), 1366.pdf
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