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Каталог книг и продолжающихся изданий
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Нанотехнологии
Демидовские премии
Гибель династии Романовых
История Урала
Личная библиотека С. В. Вонсовского
Книжная коллекция Шубиных
Труды Института высокотемпературной электрохимии УрО РАН
Труды Института истории и археологии УрО РАН
Труды сотрудников Института горного дела УрО РАН
Труды сотрудников Института органического синтеза УрО РАН
Труды сотрудников Института теплофизики УрО РАН
Труды сотрудников Института химии твердого тела УрО РАН
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Труды сотрудников ЦНБ УрО РАН
Публикации Черешнева В.А.
Публикации Чарушина В.Н.
Каталог библиотеки ИЭРиЖ УрО РАН
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1.

Вид документа : Статья из журнала
Шифр издания : 54/H 99
Автор(ы) : Saloutin V. I., Skryabina Z. E., Burgart Ya. V., Kiseleva S. V.
Заглавие : Interaction of fluorine-containing 1,3-dicarbonyl compounds with polyamines [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1992. - Vol. 41, N 11. - С. 2046-2050
Систем. требования: http://www.springerlink.com/content/n45366ln48457h82/fulltext.pdf
Примечания : 21.10.2011
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: In the reaction of fluorinated copper (II) 1,3-diketonates with diethylenetriamine (or triethylenetetramine) in CHC13, N,N'-bis (1,3-aminovinylketones) are formed in 21-35% yields. Fluorine-containing 1,3-diketones and 1,3-ketoesters, upon interaction with polyamines without solvent, undergo acid cleavage, forming the corresponding amides
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\1992, 41 (11), 2046.pdf
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2.

Вид документа : Статья из журнала
Шифр издания : 54/K 81
Автор(ы) : Krasnov V. P., Koroleva M. A.
Заглавие : Nucleophilic-substitution of halogen in 4-halogenated derivatives of glutamic-acid. 1. Solvent effect [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1995. - Vol. 44, № 4. - С. 631-634
Систем. требования: http://www.springerlink.com/content/k9027577p356012q/fulltext.pdf
Примечания : 27.10.2011 г.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reaction of nucleophilic substitution of bromine by p-anisidine in dimethyl (2S,4S)- and (2S,4R)-N-phthaloyl-4-bromoglutamates proceeds according to the S(N)2 mechanism. The relative reactivity of diastereomers in various solvents was studied.
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\1995, 44 (4), 631.pdf
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3.

Вид документа : Статья из журнала
Шифр издания : 54/I-69
Автор(ы) : Filyakova V. I., Ratner V. G., Karpenko N. S., Pashkevich K. I.
Заглавие : Interaction of fluoroalkyl-containing beta-diketones with amines [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 1996. - Vol. 45, № 9. - С. 2163-2168
Систем. требования: http://www.springerlink.com/content/w341230mnk942876/fulltext.pdf
Примечания : 26.10.2011
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The composition of products of the interaction of asymmetric fluoroalkyl-containing -diketones with amines was studied. Mixtures of regioisomeric -aminovinylketones and products of cleavage and secondary condensation are formed, depending on the temperature, the solvent, the nature of the fluorinated and nonfluorinated substituents in the -diketone, and the basicity of the amine. The major product is a -aminovinylketone in which the NH2 group is removed from the fluoroalkyl substituent. No -aminovinylimines, products of condensation involving two electrophilic centers, were observed
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\1996, 45 (9), 2163.pdf
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4.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Rusinov G. L., Ishmetova R. I., Selezneva I. S., Kalugina T. A.
Заглавие : Synthesis of Aminomethyl Derivatives of 3-Methyl-4,7-dihydro-3H-imidazo[4,5-d][1,2,3]triazin-4-one
Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2000. - Vol. 36, № 6. - С. 873-876
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: New aminomethyl derivatives of 3-methyl-4,7-dihydro-3H-imidazo[4,5-d][1,2,3]triazin-4-one??were synthesized by Mannich reaction. These Mannich bases is also possible to prepare by reaction of??7(5)-hydroxymethyl-3-methyl-4,7(5)dihydro-3H-imidazo[4,5-d][1,2,3]triazin-4-one with amines.The??compounds obtained exist in solutions as mixtures of N5??and N7 isomers,and the fraction of the latter grows??with the polarity of the solvent.
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5.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Kozhevnikov V. N., Kozhevnikov D. N., Rusinov V. L., Chupakhin O. N., Konig B.
Заглавие : Synthesis of Functionalized Fluorescent Europium(III) Terpyridyl Chelates
Место публикации : Synthesis. - 2003. - № 15. - С. 2400-2404
Примечания : Bibliogr. : p. 2404 (19 ref.)
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The synthesis of substituted terpyridines via triazine intermediates is described. The intermediates allow the facile introduction of cyano groups, which are converted into amino diacetic acid moieties. Together with the terpyridine nitrogen atoms they shield coordinated europium(III) ions completely from the solvent. The terpyridines may be further functionalized for specific applications using ligands, bromo substituents, and standard transition metal mediated coupling methods. This makes the title compounds valuable intermediates for the preparation of luminescent probes in biochemistry, medicinal diagnostics or materials science.
\\\\Expert2\\nbo\\Synthesis\\2003, v.15. p.2400.Chupakhin.pdf
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6.

Вид документа : Статья из журнала
Шифр издания : 54/K 46
Автор(ы) : Krasnov V. P., Levit G. L., Koroleva M. A., Bukrina I. M., Sadretdinova L. Sh., Andreeva I.N., Charushin V. N., Chupakhin O. N.
Заглавие : Kinetic resolution of heterocyclic amines by reaction with optically active acid chlorides. The effect of reaction conditions on the diastereoselectivity of acylation of (±)-3-methyl-2,3-dihydro-4H-1,4-benzoxazine [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2004. - Vol. 53, № 6. - С. 1253-1256
Систем. требования: http://www.springerlink.com/content/r4732rtu8517k4p2/fulltext.pdf
Примечания : 24.10.2011
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The influence of the reaction conditions (solvent, base) on the diastereoselectivity of acylation of (±)-3-methyl-2,3-dihydro-4H-1,4-benzoxazine with (S)-naproxen and N-tosyl-(S)-proline chlorides was studied. The highest diastereoselectivity was observed for the reaction carried out in benzene in the presence of aliphatic tertiary amines
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2004, 53 (6), 1253.pdf
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7.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Yatluk Yu. G., Eremin D.V., Neudachina L.K., Skorik Yu.A.
Заглавие : Synthesis and sorption properties of new hybrid chelating sorbents with ?-alanine functional groups [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2004. - Vol. 53, № 12. - С. 2730-2735
Систем. требования: http://www.springerlink.com/content/w88214314326un32/fulltext.pdf
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: A series of gamma-aminopropylsilylated sorbents was obtained from different oxide supports (silica gels, silica fillers, macroporous glasses, alumina) and by the direct synthesis (hydrolytic polycondensation of tetraalkoxysilanes with gamma-aminopropyltriethoxysilane). The highest degree of immobilization was achieved for silicas, while the most convenient solvent was methanol. Sorbents with beta-alanine functional groups were obtained by the subsequent reaction with acrylic acid. The degree of beta-carboxyethylation was 1.3–1.9, and the highest content of functional groups (vCOOH = 3.23 mmol g–1) was achieved for carboxyethylated xero gel synthesized by the copolycondensation of tetraethoxysilane with -aminopropyltriethoxysilane. The sorbents containing beta-alanine possess a higher selectivity of Cu2+ ion sorption than the initial gamma-aminopropylsilylated sorbents
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2004, 53 (12), 2730.pdf
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8.

Вид документа : Статья из журнала
Шифр издания : 54/S 53
Автор(ы) : Shcherbakov K. V., Burgart Ya. V., Saloutin V. I.
Заглавие : Reactions of 2(3)-ethoxycarbonyl-5,6,7,8-tetrafluorochromones with methylamine [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2005. - Vol. 54, № 9. - С. 2157-2162
Систем. требования: http://www.springerlink.com/content/2kp6nx3774074v11/fulltext.pdf
Примечания : Bibliogr. : p. 2162 (18 ref.). - 26.10.2011.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 2-Ethoxycarbonyl-5,6,7,8-tetrafluorochromone reacts with methylamine differently, depending on the solvent nature and the amount of the amine: in DMSO and MeCN, the fluorine atom at the C(7) atom is initially replaced and then the C(2) and/or C(9) are attacked, while in ethanol, the reaction involves the C(2) atom with opening of the pyrone ring. The reaction of 3-ethoxycarbonyl-5,6, 7,8-tetrafluoro-2-methylchromone with methylamine results, regardless of the solvent, in opening of the chromone ring and the formation of intermediate ethyl 3-(3,4,5,6-tetrafluoro-2-hydroxyphenyl)-2-(1-methylamino)ethylidene-3- oxopropionate, which undergoes intramolecular cyclization to give 5,6,7,8-tetrafluoro-3-(1-methylamino)ethylidene-3,4-dihydro-2H-benzopyran-2, 4-dione.
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2005, 54 (9), 2157-2162.pdf
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9.

Вид документа : Статья из журнала
Шифр издания : 54/C 98
Автор(ы) : Shchepin V. V., Silaichev P. S., Shchepin R.V., Ezhikova M. A., Kodess M. I.
Заглавие : Cyclopropanation of N-Substituted 2-Oxochromene- and 6-Bromo-2-oxochromene-3-carboxamides with Zinc Enolates Derived from 1-Aryl-2,2-dibromoalkanones [Electronic resource]
Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2005. - Vol. 41, № 4. - С. 527-534
Систем. требования: http://www.springerlink.com/content/t64r8082010l8686/fulltext.pdf
Примечания : 31.10.2011 г.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Zinc enolates derived from 1-aryl-2,2-dibromoalkanones react with N-cyclohexyl-2-oxochromene-3-carboxamides to give N-cyclohexyl-1-alkyl-1-aroyl-2-oxo-1a,7b-dihydrocyclopropa[c]chromene-1a-carboxamides mainly as cis isomers with respect to the substituents in positions 1 and 1a. Reactions of the same zinc enolates with N-benzyl-2-oxochromene-3-carboxamide and N-benzyl-6-bromo-2-oxochromene-3-carboxamide lead to formation of 1-aryl-2-benzyl- and 1-aryl-2-benzyl-6-bromo-1-hydroxy-9c-alkyl-1,2,9b,9c-tetrahydro-5-oxa-2-azacyclopenta[2,3]cyclopropa[1,2-a]naphthalene-3,4-diones. The reaction of zinc enolates with N-aryl-2-oxochromene-3-carboxamides in a weakly polar solvent (diethyl ether or ethyl acetate) affords mixtures of cis-N-aryl-1-aroyl-1-alkyl-2-oxo-1a,7b-dihydrocyclopropa[c]chromene-1a-carboxamides and their cyclic isomers, 9c-alkyl-1,2-diaryl-1-hydroxy-1,2,9b,9c-tetrahydro-5-oxa-2-azacyclopenta[2,3]cyclopropa[1,2-a]naphthalene-3,4-diones, the latter prevailing. N-Substituted 1-alkyl-1-aroyl-2-oxo-1a,7b-dihydrocyclopropa[c]chromene-1a-carboxamides in which the aroyl group on C1 and the carboxamide group on C1a are arranged trans are formed by reactions of zinc enolates with the corresponding 2-oxochromene-3-carboxamides in the presence of hexamethylphosphoric triamide
\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2005, 41 (4), 527.pdf
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10.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Saloutina L. V., Zapevalov A. Ya., Saloutin V. I., Kodess M. I., Kirichenko V. E., Pervova M. G., Chupakhin O. N.
Заглавие : Synthesis of 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-1,4-benzoxazines from oxides of internal perfluoroolefins
Место публикации : Journal of Fluorine Chemistry. - 2005. - Vol. 126, № 6. - С. 976-983
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of oxides of internal trans-, cis-perfluoroolefins with o-phenylenediamine and 2-aminophenol in dioxane gave 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-2H-1,4-benzoxazin-2-ols respectively in yields of 23–67%. When N,N-dimethylacetamide was used as a solvent an anionic isomerization of the oxides into ketones, which further yielded 2-(perfluoroalkyl)benzimidazoles in the case of o-phenylenediamine and 2-hydroxy-N-perfluoroalkanoylanilines in the case of 2-aminophenol, became the main path of these reactions. Unusual cyclization resulting in 2-pentafluoroethyl-2-pentafluoropropanoylbenzoxazolidine occurs on interaction between dodecafluoro-3,4-epoxyhexane and 2-aminophenol in N,N-dimethylacetamide.
\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2005, v.126, p.976.pdf
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11.

Вид документа : Статья из журнала
Шифр издания : 54/R 30
Автор(ы) : Saloutina L. V., Zapevalov A. Ya., Saloutin V. I., Kodess M. I., Kirichenko V. E., Pervova M. G., Chupakhin O. N.
Заглавие : Reactions of epoxides derived from internal perfluoroolefins with o-phenylenediamine and 2-aminophenol [Electronic resource]
Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2006. - Vol. 42, № 4. - С. 558-566
Систем. требования: http://www.springerlink.com/content/u77x227t21251826/fulltext.pdf
Примечания : 31.10.2011 г.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of epoxy derivatives of internal perfluoroolefins with o-phenylenediamine and 2-aminophenol in dioxane gave 23–67% of the corresponding 2,3-bis(perfluoroalkyl)quinoxalines and 2,3-bis(perfluoroalkyl)-2H-1,4-benzoxazin-2-ols, respectively. When N,N-dimethylacetamide was used as a solvent, the main reaction pathway was anionic isomerization of epoxides into ketones which were then converted into 2-perfluoroalkylbenzimidazoles (in the reactions with o-phenylenediamine) or 2-hydroxy-N-perfluoroalkanoylanilines (in the reactions with 2-aminophenol). The reaction of 3,4-epoxydodecafluorohexane with 2-aminophenol in N,N-dimethylacetamide was accompanied by unusual cyclization to afford 2-pentafluoropropanoyl-2-pentafluoroethyl-1,3-benzoxazolidine
\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2006, 42 (4), 558.pdf
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12.

Вид документа : Статья из журнала
Шифр издания : 54/O-57
Автор(ы) : Putilova E. S., Troitskii N. A., Zlotin S. G., Khudina O. G., Burgart Ya. V., Saloutin V. I., Chupakhin O. N.
Заглавие : One-step solvent-free synthesis of fluoroalkyl-substituted 4-hydroxy-2-oxo(thioxo)hexahydropyrimidines in the presence of 1-butyl-3-methylimidazolium tetrafluoroborate [Electronic resource]
Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2006. - Vol. 42, № 9. - С. 1392-1395
Систем. требования: http://www.springerlink.com/content/41m7k71138p144gx/fulltext.pdf
Примечания : 28.10.2011 г.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: A convenient procedure has been developed for the synthesis of fluoroalkyl-substituted 6-aryl-4-hydroxy-2-oxo-(thioxo)hexahydropyrimidine derivatives by three-component condensation of fluorinated ?-dicarbonyl compounds with aromatic aldehydes and urea or thiourea in the absence of a solvent using 6 mol % of 1-butyl-3-methylimidazolium tetrafluoroborate as catalyst.
\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2006, 42 (9), 1392.pdf
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13.

Вид документа : Статья из журнала
Шифр издания : 54/S 53
Автор(ы) : Shcherbakov K. V., Burgart Ya. V., Saloutin V. I.
Заглавие : Reactions of 5,6,7,8-tetrafluoro-4-hydroxycoumarin derivatives with benzylamine and aniline [Electronic resource]
Место публикации : Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2006. - Vol. 55, № 7. - С. 1215-1219
Систем. требования: http://www.springerlink.com/content/t5754161175p6lw1/fulltext.pdf
Примечания : 24.10.2011
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 5,6,7,8-Tetrafluoro-4-hydroxycoumarin reacted with benzylamine under mild conditions to give a stable salt, while its refluxing with aniline or benzylamine in xylene afforded 5,6,7,8-tetrafluoro-4-phenyl(benzyl)aminocoumarins. Reactions of 3-acetyl(acetimidoyl)-5,6,7,8-tetrafluoro-4-hydroxycoumarins with benzylamine followed different pathways, depending on the solvent. Condensation at the acyl substituent can be accompanied by replacement of the F atom in position 7. 3-Acetylcoumarin formed a salt, while 3-acetimidoylcoumarin yielded a 7-monosubstituted product. 3-Acetyl(acetimidoyl)-5,6,7,8-tetrafluoro-4-hydroxycoumarins reacted with aniline to give only 5,6,7,8-tetrafluoro-4-hydroxy-3-(N-phenylacetimidoyl)coumarin
\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2006, 55 (7), 1215-1219.pdf
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14.

Вид документа : Статья из журнала
Шифр издания : 54/S 53
Автор(ы) : Shchegol'kov E. V., Burgart Ya. V., Saloutin V. I.
Заглавие : Reactions of 5,6,7,8-Tetrafluoro-4-hydroxy-2H-chromen-2-ones with methylamine [Electronic resource]
Место публикации : Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2006. - Vol. 42, № 12. - С. 1838-1844
Систем. требования: http://www.springerlink.com/content/a75478702j526218/fulltext.pdf
Примечания : 28.10.2011 г.
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 5,6,7,8-Tetrafluoro-4-hydroxy-2H-chromen-2-one reacts with methylamine to give methylammonium 5,6,7,8-tetrafluoro-2-oxo-2H-chromen-4-olate, regardless of the solvent. The reaction of 3-acetyl-5,6,7,8-tetrafluoro-4-hydroxy-2H-chromen-2-one with the same amine in ethanol or acetonitrile leads to the formation of methylammonium 3-acetyl-5,6,7,8-tetrafluoro-2-oxo-2H-chromen-4-olate, while in dimethyl sulfoxide 5,6,8-trifluoro-7-methylamino-3-(1-methylaminoethylidene)-3,4-dihydro-2H-chromene-2,4-dione is formed. The latter is also formed in the reaction of 5,6,7,8-tetrafluoro-4-hydroxy-3-(1-iminoethyl)-2H-chromen-2-one with methylamine in DMSO, whereas in ethanol and acetonitrile 5,6,7,8-tetrafluoro-3-(1-methylaminoethylidene)-3,4-dihydro-2H-chromene-2,4-dione is obtained. 5,6,7,8-Tetrafluoro-3-(1-methylaminoethylidene)-3,4-dihydro-2H-chromene-2,4-dione reacts with methylamine, yielding 7-mono-or 5,7-bis(methylamino)-substituted derivatives
\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2006, 42 (12), 1838.pdf
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15.

Вид документа : Статья из журнала
Шифр издания : 54/A 10
Автор(ы) : Saloutina L. V., Zapevalov A. Ya., Saloutin V. I., Slepukhin P. A., Kodess M. I., Kirichenko V. E., Pervova M. G., Chupakhin O. N.
Заглавие : A route to fluorocontaining N,S-heterocycles via octafluoro-2,3-epoxybutane
Место публикации : Journal of Fluorine Chemistry. - 2007. - Vol. 128, № 7. - С. 769-778
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reaction of octafluoro-2,3-epoxybutane 1 with 2-aminothiophenol gave three kinds of novel fluorocontaining N,S-heterocyclic compounds depending on the solvent nature: 2,3-bis(trifluoromethyl)-3,4-dihydro-2H-1,4-benzothiazin-2-ol 2, 2-trifluoromethyl-2-[1-(2-aminophenylthio)-2,2,2-trifluoroethyl]-1,3-benzothiazolidine 6 and 5a,11a-bis(trifluoromethyl)-5a,6,11a,12-tetrahydro-5,11-dithia-6,12-diazanaphthacene 5. Use of the toluene, dioxane, tetrahydrofuran, acetonitrile and dimethoxyethane gave the unexpected dihydrobenzothiazine 2 (RS,SR RR,SS) in good to moderate yields. In dimethylsulfoxide and N,N-dimethylacetamide, unusual cyclization occurred resulting in benzothiazolidine 6 (RS,SR/RR,SS 1:1) in moderate yields. Formation of minor 1,1,1,3,4,4,4-heptafluoro-3-(2-aminophenylthio)-2,2-dihydroxybutane 4 which was converted into bis(benzothiazine) 5 was observed in all solvents tested with the exception of toluene and dioxane. The molecular structure of the RS,SR-diastereomer of dihydrobenzothiazine 2, bis(benzothiazine) 5 and the RS,SR-diastereomer of benzothiazolidine 6 has been established by X-ray crystallography.
\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2007, v.128. p.769.pdf
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16.

Вид документа : Статья из журнала
Шифр издания : 54/C 78
Автор(ы) : Kuznetsova O. A., Khmara E. F., Filyakova V. I., Uimin M. A., Ermakov A. E., Rhee C. K., Charushin V. N.
Заглавие : Copper and Copper Oxides Nanopowders in the Oxidative Condensations of Phenylacetylene and Tert-Butylacetylene [Electronic resource]
Место публикации : Russian Journal of General Chemistry. - 2007. - Vol. 77, № 3. - С. 404-408
Систем. требования: http://www.springerlink.com/content/q63v45313150n82x/fulltext.pdf
Примечания : Библиогр. : с. 408 (12 назв.). - 17.10.2011
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Transformations of phenylacetylene and tert-butylacetylene in the presence of copper and copper oxide (Cusub2/subO, CuO) nanopowders prepared by gas-phase condensation of copper in argon were studied. The reaction of phenylacetylene with copper oxide nanopowders having different phase compositions in the absence of a solvent at room temperature resulted in oxidative condensation of phenylacetylene and complex formation of the condensation product. The complex undergoes decomposition by the action of acids, bases, and compounds capable of forming complexes. According to the X-ray diffraction data, one of the products is a new “parquet” modification of diphenyldiacetylene. Under analogous conditions, tert-butylacetylene gave rise to a complex mixture of products among which di- tert-butyldiacetylene was identified by gas chromatography-mass spectrometry. No copper complexes with the tert-butylacetylene condensation products were detected.
\\\\expert2\\nbo\\Russian Journal of General Chemistry\\2007, V. 77, N 3, p.404.pdf
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17.

Вид документа : Статья из журнала
Шифр издания : 54/R 59
Автор(ы) : Pryadeina M. V., Burgart Ya. V., Saloutin V. I., Chupakhin O. N.
Заглавие : Ring-chain isomerism of ethyl 7-polyfluoroalkyl-7-hydroxy-4,7-dihydro[1,2,4]triazolo[1,5-a]pyrimidine-6-carboxylates [Электронный ресурс]
Место публикации : Mendeleev Communications. - 2008. - Vol. 18, № 5. - С. 276-277
Систем. требования: http://www.sciencedirect.com/science/article/pii/S0959943608001387
Примечания : Bibliogr. : p.277 (10 ref.) . - 12.10.2011
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Cyclisation of ethyl 2-ethoxymethylidene-3-oxo-3-polyfluoroalkylpropionates with 3-amino-1H-[1,2,4]triazole gives ethyl 7-polyfluoroalkyl-7-hydroxy-4,7-dihydro[1,2,4]triazolo[1,5-a]pyrimidine-6-carboxylates that are subject to ring–chain isomerisation in solution, depending on the solvent and the length of the polyfluoroalkyl substituent, to yield ethyl 3-polyfluoroalkyl-3-oxo-2-{([1,2,4]triazol-3-yl)aminomethylidene}propionates via heterocyclic ring opening at the C(7)–N(8) bond
\\\\Expert2\\nbo\\Mendeleev Communications\\2008, v.18, p.276.pdf
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18.

Вид документа : Статья из журнала
Шифр издания : 54/I-60
Автор(ы) : Bushkova O. V., Koryakova I.P., Skorik Yu.A., Lirova B.I. , Pestov A. V., Zhukovskii V.M.
Заглавие : Influence of metal coordination on conductivity behavior in poly(butadiene-acrylonitrile)-CoCl2 system
Место публикации : Electrochimica Acta. - 2008. - Vol. 53, № 16. - С. 5322-5333
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The metal complex formation and the electrical properties of amorphous solid polymer electrolytes, based on poly(butadiene-acrylonitrile) copolymer (PBAN) and CoCl2, have been studied over the homogeneity region of the system limited by the CoCl2 concentration of 1.89 mol kg-1. It has been found that ionic conductivity is carried out by the unipolar anion transfer at lower CoCl2 concentrations (up to 0.10 mol kg-1). As the CoCl2 concentration increases, electronic conductivity appears in addition to ionic conductivity, and the former becomes dominant, starting from 0.38 mol kg-1. It has been shown that the nature of charge carriers is determined by the composition of metal complexes formed by CoCl2 and the macromolecular solvent PBAN. At lower concentrations, the [Co2L2Cl4]0 dimers are the predominant species (L being macromolecule side groups C{triple bond, long}N), and their dissociation is followed by the formation of mobile Cl- anions and immobile binuclear [Co2Cl3]+ complexes. As CoCl2 concentration increases, polynuclear [ConL2Cl2n]0 (n 2) complexes appear (L being C{triple bond, long}N and C{double bond, long}C groups of PBAN). Specific features of chemical bonds in ?-complexes of transition metals result in the appearance of electronic charge carriers. The abrupt increase in conductivity observed at the highest CoCl2 concentration is connected with the formation of a percolation network of polynuclear [ConL2Cl2n]0 complexes
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19.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Saloutina L. V., Zapevalov A. Ya., Saloutin V. I., Slepukhin P. A., Kodess M. I., Chupakhin O. N.
Заглавие : Synthesis of fluorine containing glycolurils and oxazolines from oxides of internal perfluoroolefins
Место публикации : Journal of Fluorine Chemistry. - 2009. - Vol. 130, № 10. - С. 853-860
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reaction of oxides of internal perfluoroolefins 1–3 with urea gave two kinds of novel fluorine containing N-heterocyclic compounds depending on the solvent nature: 1,5-bis(perfluoroalkyl)tetraazabicyclo[3.3.0]octane-3,7-diones 4a–c and 2-amino-5-fluoro-4,5-bis(perfluoroalkyl)-4,5-dihydrooxazol-4-ols 7a–d. Use of polar dimethylsulfoxide, N,N-dimethylacetamide and acetonitrile afforded glycolurils 4a–c in moderate yields. In dioxane, unexpected cyclization occurred resulting in oxazolines 7a–d in high yields. A similar reaction of oxiranes 2, 3 with urea in aqueous dioxane gave mixtures of 4,5-dihydroxy-4,5-bis(perfluoroalkyl)imidazolidine-2-ones 9b, c, glycolurils 4b, c and oxazolines 7b–d. The molecular structure of trans-isomers of oxazoline 7b and imidazolidine 9b has been established by X-ray crystallography??
\\\\Expert2\\nbo\\Journal of Fluorine Chemistry\\2009, V. 130, P. 853.pdf
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20.

Вид документа : Статья из журнала
Шифр издания : 54/R 35
Автор(ы) : Usachev B. I., Obydennov D.L., Kodess M. I., Sosnovskikh V. Ya.
Заглавие : Regioselective solvent-sensitive reactions of 6-(trifluoromethyl)comanic acid and its derivatives with phenylhydrazine
Место публикации : Tetrahedron Letters. - 2009. - Vol. 50, № 31. - С. 4446-4448
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 6-(Trifluoromethyl)comanic acid reacts regioselectively with phenylhydrazine in water to give 5-[3,3,3-trifluoro-2-(phenylhydrazono)propyl]-1-phenyl-1H-pyrazole-3-carboxylic acid. Similar reaction in dioxane leads to 3-[3,3,3-trifluoro-2-(phenylhydrazono)propyl]-1-phenyl-1H-pyrazole-5-carboxylic acid. A strong solvent influence on the reaction route was also found for 6-(trifluoromethyl)comanic acid derivatives
\\\\Expert2\\nbo\\Tetrahedron Letters\\2009, v. 50, p.4446.pdf
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