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Поисковый запрос: (<.>K=SENSOR<.>)
Общее количество найденных документов : 13
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 1-10    11-13 
1.
Инвентарный номер: нет.
   
   E 43


   
    Electrochemical sensor based on metal-containing receptors for urea measurements [Text] : доклад, тезисы доклада / A. Kozitsina [и др.] // International Congress on Analytical Sciences "ICAS - 2006",M., June 25-30 2006 : book of abstracts. - М., 2006. - Vol. 1. - P291 : табл. - Bibliogr. : p. 291 (1 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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2.
Инвентарный номер: нет.
   
   D 46


   
    Design of ICT-PET fluorescent probes for zinc(II) based on 5-aryl-2,2′-bipyridines / D. S. Kopchuk, A. M. Prokhorov, P. A. Slepukhin, D. N. Kozhevnikov // Tetrahedron Letters. - 2012. - Vol.53, №46. - С. 6265-6268
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ZINC(II) SENSOR -- BIPYRIDINES -- INTRAMOLECULAR CHARGE TRANSFER
Аннотация: Rational design of selective and sensitive ‘off-on’ fluorescent probes for Zn(II) cations exploiting both PET and ICT mechanisms of sensing is illustrated by the synthesis and application of 5-aryl-2,2′-bipyridines modified with a dipicolylaminomethyl fragment. The aryl substituent provides tuning of the prop

\\\\Expert2\\nbo\\Tetrahedron Letters\\2012, v. 53, p. 6265.pdf
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3.
Инвентарный номер: нет.
   
   I-83


   
    Iptycene-Based Fluorescent Sensors for Nitroaromatics and TNT / P. Anzenbacher, Jr. L. Mosca, M. A. Palacios, G. V. Zyryanov, P. Koutnik // Chemistry - A European Journal. - 2012. - Vol.18, №40. - С. 12712-12718. - Bibliogr. : p. 12718 (15 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
EXPLOSIVES -- FLUORESCENCE SPECTROSCOPY -- NANOFIBRES -- SENSORS
Аннотация: Small-molecule fluorescent sensors (1–5) for the recognition of nitroaromatic compounds, such as 2,4-dinitrotoluene and the explosive TNT, were obtained by using a three-step dehydrohalogenation cycloaddition protocol. The interaction of the receptors and nitroaromatics was studied both in solution and in the solid state by using fluorescence spectroscopy and X-ray crystallography, respectively. It is shown that the iptycene receptors 1–5 provide a cavity suitable for binding nitroaromatic compounds in an edge-to-face mode, rather than simple ring-stacking interactions. The results obtained inspired us to develop an inexpensive, reliable and robust sensor for vapour detection of explosives. Polymer nanofibres are particularly suitable for the production of such TNT sensors as they accelerate the mass exchange between the polymer and the vapours of TNT. Quenching of the sensors took place within 1 min compared to 10 min for a glass-slide assay. Hence, the sensor performance can be improved by optimising the matrix material and morphology without resynthesising the sensor moieties

\\\\expert2\\NBO\\Chemistry - A European Journal\\2012. v. 18, N 40. p. 12712.pdf
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4.
Инвентарный номер: нет.
   
   D 47


   
    Detection of nitroaromatic explosives by new D-π-A sensing fluorophores on the basis of the pyrimidine scaffold [Electronic resource] / E. V. Verbitskiy, A. A. Baranova, K. I. Ludovik, M. Z. Shafikov, K. O. Khokhlov, E. M. Cheprakova, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Analytical and Bioanalytical Chemistry. - 2016. - Ahead of Print
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
NITROAROMATIC EXPLOSIVES -- PYRIMIDINE SCAFFOLD
Аннотация: A series of D-​π-​A- type dyes based on pyrimidines, bearing various thiophene linkers, have been studied as sensing fluorophores. Fluorescence studies have demonstrated that the emission of all derivs. is sensitive to the presence of nitroarom. explosives, such as 2,​4,​6-​trinitrophenol (PA)​, 2,​4,​6-​trinitrotoluene (TNT)​, and 2,​4-​dinitrotoluene (DNT)​, in their acetonitrile solns. The detection limits of fluorophores to PA, TNT, and DNT proved to be in the range from 5.83 × 10-​6 to 2.38 × 10-​7 mol​/L, 1.70 × 10-​4 to 8.40 × 10-​6 mol​/L, and 8.39 × 10-​5 to 6.87 × 10-​6 mol​/L, resp. The theor. investigation into the quenching mechanism in the presence of fluorophore has been performed. All compds. have shown a good efficiency as sensor materials when tested as elements of the original device <> for detecting nitro-​contg. explosives in vapor phase

\\\\expert2\\nbo\\Analytical and Bioanalytical Chemistry\\2016, Ahead Print.pdf
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5.
Инвентарный номер: нет.
   
   N 52


   
    New 4,5-di(hetero)arylpyrimidines as sensing elements for detection of nitroaromatic explosives in vapor phase / E. V. Verbitskiy, A. A. Baranova, K. I. Lugovik, K. O. Khokhlov, E. M. Cheprakova, M. Z. Shafikov, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Dyes and Pigments. - 2016. - Vol. 137. - С. 360-371. - Bibliogr. : p. 370-371 (50 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
4,5-DI(HETERO)ARYLPYRIMIDINES -- NITROAROMATIC EXPLOSIVES -- VAPOR PHASE
Аннотация: A series of D–π–A–π–D type dyes based on pyrimidines, bearing thiophene linkers, have been studied as sensing fluorophores. Fluorescence studies have demonstrated that the emission of all derivatives is sensitive to the presence of 2,4,6-trinitrotoluene (TNT) and other nitroaromatic compounds (NACs), in their acetonitrile solutions. The detection limits of fluorophores to NACs proved to be in the range from 10−4 to 10−6 mol/L. The time-resolved fluorescence measurements and theoretical investigation into the quenching mechanism in the presence of fluorophore has been performed. The two types of sensor prototypes for handheld sniffer «Nitroscan» (Plant «Promautomatika», Ekaterinburg, Russia) on the basis of non-woven dry wipe and spunlace non-woven fabric with various quantities of the most sensitive fluorophore have been fabricated. The reusable, reversible and sensitive response of the designed prototypes to NACs enables one to qualify these compounds as promising fluorescent sensory materials for detection of NACs.

\\\\expert2\\nbo\\Dyes and Pigments\\2016, v. 137, p.360-371.pdf
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6.
Инвентарный номер: нет.
   
   M 65


   
    Microwave-assisted synthesis of 4-(2,2'-bithiophen-5-yl)-5-phenylpyrimidine derivatives as sensors for detection of nitroaromatic explosives = Микроволновый синтез производных 4-(2,2'-битиофенил-5-ил)-5-фенилпиримидина и их применение в качестве сенсоров нитроароматических взрывчатых веществ / E. V. Verbitskiy, E. M. Cheprakova, A. A. Baranova, K. O. Khokhlov, K. I. Ludovik, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Chemistry of Heterocyclic Compounds. - 2016. - Vol. 52, № 11. - С. 904-909. - Bibliogr. : p. 909 (27 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PYRIMIDINE TRIPHENYLAMINE -- NITROAROMATIC EXPLOSIVES -- FLUORESCENCE QUENCHING
Аннотация: A reaction sequence involving microwave-assisted Suzuki cross-coupling steps and bromination with N-bromosuccinimide was used to synthesize 4-{4-[4',5'-bis(4-diphenylaminophenyl)-3'-hexyl-2,2'-bithiophen-5-yl]pyrimidin-5-yl}benzonitrile. The optical properties of the obtained compound were studied to evaluate it for possible applications as a sensor of nitroaromatic compounds in acetonitrile solutions and gas phase

\\\\expert2\\NBO\\Chemistry of Heterocyclic Compounds\\2016, v.52, N 11, p. 904-909.pdf
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7.
Инвентарный номер: нет.
   
   N 52


   
    New 4,5-di(hetero)arylpyrimidines as sensing elements for detection of nitroaromatic explosives in vapor phase / E. V. Verbitskiy, A. A. Baranova, K. I. Lugovik, K. O. Khokhlov, E. M. Cheprakova, M. Z. Shafikov, G. L. Rusinov, O. N. Chupakhin, V. N. Charushin // Dyes and Pigments. - 2017. - Vol. 137. - P360-371
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
FLUORESCENCE QUENCHING -- NITROAROMATIC EXPLOSIVES -- TRIPHENYLAMINES -- CARBAZOLES -- PYRIMIDINES
Аннотация: A series of D–π–A–π–D type dyes based on pyrimidines, bearing thiophene linkers, have been studied as sensing fluorophores. Fluorescence studies have demonstrated that the emission of all derivatives is sensitive to the presence of 2,4,6-trinitrotoluene (TNT) and other nitroaromatic compounds (NACs), in their acetonitrile solutions. The detection limits of fluorophores to NACs proved to be in the range from 10−4 to 10−6 mol/L. The time-resolved fluorescence measurements and theoretical investigation into the quenching mechanism in the presence of fluorophore has been performed. The two types of sensor prototypes for handheld sniffer «Nitroscan» (Plant «Promautomatika», Ekaterinburg, Russia) on the basis of non-woven dry wipe and spunlace non-woven fabric with various quantities of the most sensitive fluorophore have been fabricated. The reusable, reversible and sensitive response of the designed prototypes to NACs enables one to qualify these compounds as promising fluorescent sensory materials for detection of NACs.

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8.
Инвентарный номер: нет.
   


   
    N-Substituted-3-aminopropylsilsesquioxanes: synthesis, physicochemical properties, and application / M. E. Evseev, A. S. Kholmogorova, L. K. Neudachina [et al.] // Russian chemical bulletin. - 2021. - Vol. 70, № 6. - P1154-1160
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
SILSESQUIOXANES -- SOL-GEL -- CARBON PASTE ELECTRODES -- RUBEANIC ACID -- DETERMINATION OF SILVER(I)
Аннотация: Synthesis and study of the physicochemical properties of silsesquioxanes modified with 3-aminopropyl, 2-aminoethyl-3-aminopropyl, and dithiooxamide groups was carried out. The obtained sorbents were characterized by thermal stability, porosity, and a high degree of functionalization; the concentration of groups grafted to the particle surface reached 2.80 mmol g−1. Modified silsesquioxanes were used as an electroactive substance for the development of indicator carbon paste electrodes (CPEs). When using a CPE with a 5% dithiooxamidated silsesquioxane content, the conditions selected for potentiometric titration of aqueous solutions containing silverI were pH 3–4, the titrant was potassium iodide. The designed sensor was successfully tested by analyzing a standard sample and a drug for silver ion content.

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9.
Инвентарный номер: нет.
   


   
    Variation in tumor pH affects pH-triggered delivery of peptide-modified magnetic nanoparticles / A. G. Pershina, O. Y. Brikunova, S. V. Vtorushin [et al.] // Nanomedicine: nanotechnology, biology and medicine. - 2021. - Vol. 32. - P102317
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
PH PROFILE -- ENDOCYTOSIS -- IRON OXIDE MAGNETIC NANOPARTICLES
Аннотация: Acidification of the extracellular matrix, an intrinsic characteristic of many solid tumors, is widely exploited for physiologically triggered delivery of contrast agents, drugs, and nanoparticles to tumor. However, pH of tumor microenvironment shows intra- and inter-tumor variation. Herein, we investigate the impact of this variation on pH-triggered delivery of magnetic nanoparticles (MNPs) modified with pH-(low)-insertion peptide (pHLIP). Fluorescent flow cytometry, laser confocal scanning microscopy and transmission electron microscopy data proved that pHLIP-conjugated MNPs interacted with 4T1 cells in two-dimensional culture and in spheroids more effectively at pH 6.4 than at pH 7.2, and entered the cell via clathrin-independent endocytosis. The accumulation efficiency of pHLIP-conjugated MNPs in 4T1 tumors after their intravenous injection, monitored in vivo by magnetic resonance imaging, showed variation. Analysis of the tumor pH profiles recorded with implementation of original nanoprobe pH sensor, revealed obvious correlation between pH measured in the tumor with the amount of accumulated MNPs.

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10.
Инвентарный номер: нет.
   


   
    Benzo[de]naphtho[1,8-gh]quinolines: synthesis, photophysical studies and nitro explosives detection / I. L. Nikonov, I. A. Khalymbadzha, L. K. Sadieva [et al.] // Chimica Techno Acta. - 2021. - Vol. 8, № 4. - Ст. 20218415
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
BENZO[DE]NAPHTHA [1,8-GH]QUINOLONES -- FLUORESCENCE -- SENSOR -- EXPLOSIVES
Аннотация: A rational synthetic approach to substituted naphtho[1,8-gh]quinolines based on intramolecular cyclization in the presence of potassium in the series of (naphthalen-1-yl)isoquinolines is described. The photophysical properties of the obtained compounds were studied; in particular, fluorescence emission was detected in the range 454-482 nm with a quantum yield of up to 54%. We also calculated the HOMO-LUMO energies and optimized molecular structures for the resulting fluorophores. Based on the results of fluorescence titration, the Stern-Volmer constants (up to 21587 M-1) and the detection limits of nitroanalytes (up to 1.4 ppm) were calculated, confirming the possibility of their use as potential chemosensors for the visual detection of nitro-containing explosives.

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 1-10    11-13 
 

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