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 Найдено в других БД:Труды Института высокотемпературной электрохимии УрО РАН (1)Труды сотрудников Института органического синтеза УрО РАН (100)Труды сотрудников Института химии твердого тела УрО РАН (6)Публикации Чарушина В.Н. (2)
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1.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical properties of some tetraalkoxysilanes and tetraalkoxytitaniums with branched alkyl radicals
Место публикации : Fluid Phase Equilibria. - 2012. - Vol.331. - С. 1-5
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): branched alkyl radicals--critical properties --tetraalkoxysilanes
Аннотация: The critical pressures and the critical temperatures of tetraisopropoxytitanium, tetra-tert-butoxytitanium, and tetraisopropoxysilane have been measured. The decomposition of the substances studied begins at temperatures below their critical ones. A pulse-heating method which allows measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from 0.03 to 1 ms. The short residence times provided little degradation of the substances in the course of the experiments. The critical constants of tetraalkoxytitaniums and tetraalkoxysilanes with branched and straight alkyl chains have been compared. The experimental critical constants of tetraalkoxytitaniums and tetraalkoxysilanes have also been compared with those calculated using various group-contribution methods
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2.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical properties of some tetraalkoxysilanes and tetraalkoxytitaniums with branched alkyl radicals
Место публикации : Fluid Phase Equilibria. - 2012. - Vol.331. - С. 1-5
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): branched alkyl radicals--critical properties --tetraalkoxysilanes
Аннотация: The critical pressures and the critical temperatures of tetraisopropoxytitanium, tetra-tert-butoxytitanium, and tetraisopropoxysilane have been measured. The decomposition of the substances studied begins at temperatures below their critical ones. A pulse-heating method which allows measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from 0.03 to 1 ms. The short residence times provided little degradation of the substances in the course of the experiments. The critical constants of tetraalkoxytitaniums and tetraalkoxysilanes with branched and straight alkyl chains have been compared. The experimental critical constants of tetraalkoxytitaniums and tetraalkoxysilanes have also been compared with those calculated using various group-contribution methods
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3.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical Temperatures and Pressures of Some Tetraalkoxytitaniums
Место публикации : Journal of Chemical & Engineering Data. - 2010. - Vol.55, №1. - С. 178-183
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical pressures--critical temperatures--tetraalkoxytitaniums
Аннотация: The critical pressures and the critical temperatures of nine tetraalkoxytitaniums, Ti[O(CH2)nH]4 with n = 2 to 10, have been measured. All of the substances studied begin to decompose at temperatures below their critical points. The method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 0.46) ms, which resulted in little decomposition of the substances during measuring. The contributions of the titanium(IV) atom in the group contribution methods of Constantinou and Gani and Marrero and Gani have been calculated from the experimental data. The critical pressures and temperatures of tetraalkoxytitaniums have been estimated by these methods
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4.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical Temperatures and Pressures of Some Tetraalkoxytitaniums
Место публикации : Journal of Chemical & Engineering Data. - 2010. - Vol.55, №1. - С. 178-183
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical pressures--critical temperatures--tetraalkoxytitaniums
Аннотация: The critical pressures and the critical temperatures of nine tetraalkoxytitaniums, Ti[O(CH2)nH]4 with n = 2 to 10, have been measured. All of the substances studied begin to decompose at temperatures below their critical points. The method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 0.46) ms, which resulted in little decomposition of the substances during measuring. The contributions of the titanium(IV) atom in the group contribution methods of Constantinou and Gani and Marrero and Gani have been calculated from the experimental data. The critical pressures and temperatures of tetraalkoxytitaniums have been estimated by these methods
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5.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S., Yatluk Yu. G.
Заглавие : Critical Temperatures and Pressures of Straight-Chain Saturated Dicarboxylic Acids (C4 to C14)
Место публикации : Journal of Chemical & Engineering Data. - 2004. - Vol.49, №6. - С. 1515-1520
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): dicarboxylic acids --methods of ambrose--pressures
Аннотация: The critical temperatures and pressures of nine saturated straight-chain dicarboxylic acids HOOC(CH2)nCOOH with n = 2, 3, 4, 5, 6, 7, 8, 10, and 12 have been measured. All of the acids investigated are thermally unstable at their critical points. The method of pulse heating of a wire probe immersed in the liquid under study has been used. Residence times are from (0.01 to 1) ms. The experimental critical properties of dicarboxylic acids have been compared with the values calculated by the group-contribution methods of Ambrose, Joback, and Reid, Constantinou and Gani, and Marrero and Gani
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6.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S., Yatluk Yu. G.
Заглавие : Critical Temperatures and Pressures of Straight-Chain Saturated Dicarboxylic Acids (C4 to C14)
Место публикации : Journal of Chemical & Engineering Data. - 2004. - Vol.49, №6. - С. 1515-1520
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): dicarboxylic acids --methods of ambrose--pressures
Аннотация: The critical temperatures and pressures of nine saturated straight-chain dicarboxylic acids HOOC(CH2)nCOOH with n = 2, 3, 4, 5, 6, 7, 8, 10, and 12 have been measured. All of the acids investigated are thermally unstable at their critical points. The method of pulse heating of a wire probe immersed in the liquid under study has been used. Residence times are from (0.01 to 1) ms. The experimental critical properties of dicarboxylic acids have been compared with the values calculated by the group-contribution methods of Ambrose, Joback, and Reid, Constantinou and Gani, and Marrero and Gani
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7.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G.
Заглавие : Critical Point Measurements for n-Alkyl Benzoates (C8 to C13)
Место публикации : Journal of Chemical & Engineering Data. - 2007. - Vol. 52, № 4. - С. 1336-1339
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): alkyl benzoates
Аннотация: The critical temperatures and critical pressures of six n-alkyl benzoates C6H5COO(CH2)nH with n = 1 to 6 have been measured. All the substances are thermally unstable at their critical points. The method of pulse-heating of a wire probe placed into the liquid under study has been used. Residence times are from (0.03 to 1) ms, which results in little decomposition of the liquid in the course of measuring. The experimental critical properties of alkylbenzoates have been compared with the values estimated by the group contribution methods of Constantinou and Gani and Marrero and Gani. ??
\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2007, v.52, p.1336.pdf
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8.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G.
Заглавие : Critical Point Measurements for n-Alkyl Benzoates (C8 to C13)
Место публикации : Journal of Chemical & Engineering Data. - 2007. - Vol. 52, № 4. - С. 1336-1339
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): alkyl benzoates
Аннотация: The critical temperatures and critical pressures of six n-alkyl benzoates C6H5COO(CH2)nH with n = 1 to 6 have been measured. All the substances are thermally unstable at their critical points. The method of pulse-heating of a wire probe placed into the liquid under study has been used. Residence times are from (0.03 to 1) ms, which results in little decomposition of the liquid in the course of measuring. The experimental critical properties of alkylbenzoates have been compared with the values estimated by the group contribution methods of Constantinou and Gani and Marrero and Gani. ??
\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2007, v.52, p.1336.pdf
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9.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G.
Заглавие : Critical Pressures and Temperatures of n-Diaminoalkanes (C2 to C12)
Место публикации : Journal of Chemical & Engineering Data. - 2006. - Vol. 51, № 2. - С. 609-111
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical pressures
Аннотация: The critical temperatures and pressures of eight n-diaminoalkanes NH2(CH2)nNH2 with n = 2, 3, 4, 6, 8, 9, 10, and 12 have been measured. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.03 to 1) ms. The critical properties of diaminoalkanes have been estimated by the group-contribution methods by Joback and Reid, Constantinou and Gani, and Marrero and Gani. These properties have also been calculated using a method based on the assumption that the functions describing the dependence of the critical properties of homologous series on the number of mers in a molecule should be self-similar and provide the scaling behavior for long-chain molecules. The last method provides the best accuracy in calculating the critical properties of diaminoalkanes. For this method, the average absolute errors are equal to 0.4 % for the critical temperature and about 2 % for the critical pressure. ??
\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2006, v.51, p.609.pdf
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10.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G.
Заглавие : Critical Pressures and Temperatures of n-Diaminoalkanes (C2 to C12)
Место публикации : Journal of Chemical & Engineering Data. - 2006. - Vol. 51, № 2. - С. 609-111
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical pressures
Аннотация: The critical temperatures and pressures of eight n-diaminoalkanes NH2(CH2)nNH2 with n = 2, 3, 4, 6, 8, 9, 10, and 12 have been measured. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.03 to 1) ms. The critical properties of diaminoalkanes have been estimated by the group-contribution methods by Joback and Reid, Constantinou and Gani, and Marrero and Gani. These properties have also been calculated using a method based on the assumption that the functions describing the dependence of the critical properties of homologous series on the number of mers in a molecule should be self-similar and provide the scaling behavior for long-chain molecules. The last method provides the best accuracy in calculating the critical properties of diaminoalkanes. For this method, the average absolute errors are equal to 0.4 % for the critical temperature and about 2 % for the critical pressure. ??
\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2006, v.51, p.609.pdf
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