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Труды Института высокотемпературной электрохимии УрО РАН
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Труды сотрудников Института теплофизики УрО РАН
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1.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    (Gas+liquid) critical temperatures and pressures of polyethelene-glycols from HOCH2CH2OH to H(OCH2CH2)v=132OH [Text] / E. D. Nikitin, P. A. Pavlov, A. P. Popov // Journal of Chemical Thermodynamics. - 1995. - V. 27, №1. - P43-51
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ЛИТЬЕ -- жидкости -- ТЕМПЕРАТУРА КРИТИЧЕСКАЯ -- КРИТИЧЕСКАЯ ТЕМПЕРАТУРА -- ДАВЛЕНИЕ -- ПОЛИЭТИЛЕН-ГЛЮКОЛЬ -- HOCH2CH2OH -- H(OCH2CH2)v=132OH -- H -- O (КИСЛОРОД) -- C -- ВОДОРОД -- КИСЛОРОД -- УГЛЕРОД
Аннотация: The critical temperatures and pressures of mono-, di-, tri-, and tetra-ethene glycols, and polyethene glycols with nominal molar massesM/M°(whereM°= 1 g·mol−1) equal to 300, 400, and 600, have been measured by the pulse-heating method applicable to thermally unstable substances. The results have been correlated as a function of the molar mass using the hole theory of liquids developed by Kurata and Isida with a slight modification

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2.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    (Gas+liquid) critical temperatures and pressures of polyethelene-glycols from HOCH2CH2OH to H(OCH2CH2)v=132OH [Text] / E. D. Nikitin, P. A. Pavlov, A. P. Popov // Journal of Chemical Thermodynamics. - 1995. - V. 27, №1. - P43-51
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ЛИТЬЕ -- жидкости -- ТЕМПЕРАТУРА КРИТИЧЕСКАЯ -- КРИТИЧЕСКАЯ ТЕМПЕРАТУРА -- ДАВЛЕНИЕ -- ПОЛИЭТИЛЕН-ГЛЮКОЛЬ -- HOCH2CH2OH -- H(OCH2CH2)v=132OH -- H -- O (КИСЛОРОД) -- C -- ВОДОРОД -- КИСЛОРОД -- УГЛЕРОД
Аннотация: The critical temperatures and pressures of mono-, di-, tri-, and tetra-ethene glycols, and polyethene glycols with nominal molar massesM/M°(whereM°= 1 g·mol−1) equal to 300, 400, and 600, have been measured by the pulse-heating method applicable to thermally unstable substances. The results have been correlated as a function of the molar mass using the hole theory of liquids developed by Kurata and Isida with a slight modification

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3.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    (Vapour+liquid) critical properties and accentric factors of fine low-molarmass methylphenysiloxanes [Text] / E. D. Nikitin, P. A. Pavlov, A. P. Popov // Journal of Chemical Thermodynamics. - 1994. - V. 26. - P1047-1050
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ПАР -- ЖИДКОСТИ -- СВОЙСТВА КРИТИЧЕСКИЕ -- КРИТИЧЕСКИЕ СВОЙСТВА -- МЕТИЛФЕНИСИЛОКСАН НИЗКОМОЛЯРНЫЙ -- НИЗКОМОЛЯРНЫЙ МЕТИЛФЕНИСИЛОКСАН -- МЕТИЛФЕНИСИЛОКСАН ТОНКИЙ -- ТОНКИЙ МЕТИЛФЕНИСИЛОКСАН -- ТЕПЛОФИЗИКА

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4.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    (Vapour+liquid) critical properties and accentric factors of fine low-molarmass methylphenysiloxanes [Text] / E. D. Nikitin, P. A. Pavlov, A. P. Popov // Journal of Chemical Thermodynamics. - 1994. - V. 26. - P1047-1050
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ПАР -- ЖИДКОСТИ -- СВОЙСТВА КРИТИЧЕСКИЕ -- КРИТИЧЕСКИЕ СВОЙСТВА -- МЕТИЛФЕНИСИЛОКСАН НИЗКОМОЛЯРНЫЙ -- НИЗКОМОЛЯРНЫЙ МЕТИЛФЕНИСИЛОКСАН -- МЕТИЛФЕНИСИЛОКСАН ТОНКИЙ -- ТОНКИЙ МЕТИЛФЕНИСИЛОКСАН -- ТЕПЛОФИЗИКА

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5.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Corrigendum to “Critical temperatures and pressures of 1-alkanols with 13 to 22 carbon atoms” [Fluid Phase Equilibria, 149 (1998) 223–232] / E. D. Nikitin, P. A. Pavlov, A. P. Popov // Fluid Phase Equilibria. - 2000. - Vol.168, №2. - С. 281
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL TEMPERATURES -- 1-ALKANOLS -- CRITICAL PRESSURES

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6.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Corrigendum to “Critical temperatures and pressures of 1-alkanols with 13 to 22 carbon atoms” [Fluid Phase Equilibria, 149 (1998) 223–232] / E. D. Nikitin, P. A. Pavlov, A. P. Popov // Fluid Phase Equilibria. - 2000. - Vol.168, №2. - С. 281
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL TEMPERATURES -- 1-ALKANOLS -- CRITICAL PRESSURES

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7.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical point measurement of ferrocene and some of its derivatives [Электронный ресурс] / E. D. Nikitin, A. P. Popov // Fluid Phase Equilibria. - 2012. - Vol.324. - P13-16
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
1-ACETYLFERROCENE -- BENZOYLFERROCENE -- FERROCENE
Аннотация: The critical temperatures and the critical pressures of ferrocene, . n-butylferrocene, benzoylferrocene, and 1-acetylferrocene have been measured. All the compounds studied begin to decompose at temperatures below their critical points. A method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 1.0). ms, which resulted in little decomposition of the substances in the course of measuring. The contributions of the groups Fe. CH and Fe. C for the estimation of the critical properties of ferrocene derivatives by the method of Marrero and Gani have been determined from the experimental data

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8.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical point measurement of ferrocene and some of its derivatives [Электронный ресурс] / E. D. Nikitin, A. P. Popov // Fluid Phase Equilibria. - 2012. - Vol.324. - P13-16
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
1-ACETYLFERROCENE -- BENZOYLFERROCENE -- FERROCENE
Аннотация: The critical temperatures and the critical pressures of ferrocene, . n-butylferrocene, benzoylferrocene, and 1-acetylferrocene have been measured. All the compounds studied begin to decompose at temperatures below their critical points. A method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 1.0). ms, which resulted in little decomposition of the substances in the course of measuring. The contributions of the groups Fe. CH and Fe. C for the estimation of the critical properties of ferrocene derivatives by the method of Marrero and Gani have been determined from the experimental data

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9.
Инвентарный номер: нет.
   

    Nikitin, E. D.
    Critical Point Measurements for Five n-Alkylcyclohexanes (C6 to C10) by the Pulse-Heating Method / E. D. Nikitin, A. P. Popov, N. S. Bogatishcheva // Journal of Chemical & Engineering Data. - 2003. - Vol.48, №5. - С. 1137-1140
Кл.слова (ненормированные):
ALKYLCYCLOHEXANES -- CARBONS -- METHODS OF LYDERSEN
Аннотация: This paper presents experimental critical temperatures and pressures of five n-alkylcyclohexanes C6H11CnH2n+1 with the number of carbons in the side chain n = 0, 1, 2, 3, or 4. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.01 to 1) ms. Equations for the correlation of the critical temperatures and pressures of n-alkylcyclohexanes with the number of carbon atoms in the side chain, normal boiling point, and molar mass have been obtained. The experimental critical constants of alkylcyclohexanes have been compared with the values calculated by the group-contribution methods of Lydersen, Joback and Reid, and Constantinou and Gani

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10.
Инвентарный номер: нет.
   

    Nikitin, E. D.
    Critical Point Measurements for Five n-Alkylcyclohexanes (C6 to C10) by the Pulse-Heating Method / E. D. Nikitin, A. P. Popov, N. S. Bogatishcheva // Journal of Chemical & Engineering Data. - 2003. - Vol.48, №5. - С. 1137-1140
Кл.слова (ненормированные):
ALKYLCYCLOHEXANES -- CARBONS -- METHODS OF LYDERSEN
Аннотация: This paper presents experimental critical temperatures and pressures of five n-alkylcyclohexanes C6H11CnH2n+1 with the number of carbons in the side chain n = 0, 1, 2, 3, or 4. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.01 to 1) ms. Equations for the correlation of the critical temperatures and pressures of n-alkylcyclohexanes with the number of carbon atoms in the side chain, normal boiling point, and molar mass have been obtained. The experimental critical constants of alkylcyclohexanes have been compared with the values calculated by the group-contribution methods of Lydersen, Joback and Reid, and Constantinou and Gani

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11.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical Point Measurements for n-Alkyl Benzoates (C8 to C13) [Текст] / E. D. Nikitin, A. P. Popov, Yu. G. Yatluk // Journal of Chemical & Engineering Data. - 2007. - Vol. 52, № 4. - С. 1336-1339
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ALKYL BENZOATES
Аннотация: The critical temperatures and critical pressures of six n-alkyl benzoates C6H5COO(CH2)nH with n = 1 to 6 have been measured. All the substances are thermally unstable at their critical points. The method of pulse-heating of a wire probe placed into the liquid under study has been used. Residence times are from (0.03 to 1) ms, which results in little decomposition of the liquid in the course of measuring. The experimental critical properties of alkylbenzoates have been compared with the values estimated by the group contribution methods of Constantinou and Gani and Marrero and Gani. ??

\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2007, v.52, p.1336.pdf
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12.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical Point Measurements for n-Alkyl Benzoates (C8 to C13) [Текст] / E. D. Nikitin, A. P. Popov, Yu. G. Yatluk // Journal of Chemical & Engineering Data. - 2007. - Vol. 52, № 4. - С. 1336-1339
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ALKYL BENZOATES
Аннотация: The critical temperatures and critical pressures of six n-alkyl benzoates C6H5COO(CH2)nH with n = 1 to 6 have been measured. All the substances are thermally unstable at their critical points. The method of pulse-heating of a wire probe placed into the liquid under study has been used. Residence times are from (0.03 to 1) ms, which results in little decomposition of the liquid in the course of measuring. The experimental critical properties of alkylbenzoates have been compared with the values estimated by the group contribution methods of Constantinou and Gani and Marrero and Gani. ??

\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2007, v.52, p.1336.pdf
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13.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical Pressures and Temperatures of n-Diaminoalkanes (C2 to C12) [Текст] / E. D. Nikitin, A. P. Popov, Yu. G. Yatluk // Journal of Chemical & Engineering Data. - 2006. - Vol. 51, № 2. - С. 609-111
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL PRESSURES
Аннотация: The critical temperatures and pressures of eight n-diaminoalkanes NH2(CH2)nNH2 with n = 2, 3, 4, 6, 8, 9, 10, and 12 have been measured. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.03 to 1) ms. The critical properties of diaminoalkanes have been estimated by the group-contribution methods by Joback and Reid, Constantinou and Gani, and Marrero and Gani. These properties have also been calculated using a method based on the assumption that the functions describing the dependence of the critical properties of homologous series on the number of mers in a molecule should be self-similar and provide the scaling behavior for long-chain molecules. The last method provides the best accuracy in calculating the critical properties of diaminoalkanes. For this method, the average absolute errors are equal to 0.4 % for the critical temperature and about 2 % for the critical pressure. ??

\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2006, v.51, p.609.pdf
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14.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical Pressures and Temperatures of n-Diaminoalkanes (C2 to C12) [Текст] / E. D. Nikitin, A. P. Popov, Yu. G. Yatluk // Journal of Chemical & Engineering Data. - 2006. - Vol. 51, № 2. - С. 609-111
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL PRESSURES
Аннотация: The critical temperatures and pressures of eight n-diaminoalkanes NH2(CH2)nNH2 with n = 2, 3, 4, 6, 8, 9, 10, and 12 have been measured. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.03 to 1) ms. The critical properties of diaminoalkanes have been estimated by the group-contribution methods by Joback and Reid, Constantinou and Gani, and Marrero and Gani. These properties have also been calculated using a method based on the assumption that the functions describing the dependence of the critical properties of homologous series on the number of mers in a molecule should be self-similar and provide the scaling behavior for long-chain molecules. The last method provides the best accuracy in calculating the critical properties of diaminoalkanes. For this method, the average absolute errors are equal to 0.4 % for the critical temperature and about 2 % for the critical pressure. ??

\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2006, v.51, p.609.pdf
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15.
Инвентарный номер: нет.
   
   C 89

   
    Critical properties of hydrogen peroxide determined from direct measurements [Text] / E. D. Nikitin, P. A. Pavlov, A. P. Popov, N. E. Nikitina // Journal of Chemical Thermodynamics. - 1995. - V. 27, №9. - P945-952
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
СВОЙСТВА КРИТИЧЕСКИЕ -- КРИТИЧЕСКИЕ СВОЙСТВА -- ГИДРОГЕН ПЕРОКСИД -- ИЗМЕРЕНИЯ ПРЯМЫЕ -- ПРЯМЫЕ ИЗМЕРЕНИЯ -- ТЕПЛОФИЗИКА
Аннотация: The critical temperatures and the critical pressures of aqueous solutions with mass fractions of hydrogen peroxide from 0 to 0.9 have been measured using the pulse-heating method applicable to thermally unstable substances. The critical temperature and the critical pressure of pure hydrogen peroxide have been determined by extrapolation. The results are compared with the values predicted by various methods

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16.
Инвентарный номер: нет.
   
   C 89

   
    Critical properties of hydrogen peroxide determined from direct measurements [Text] / E. D. Nikitin, P. A. Pavlov, A. P. Popov, N. E. Nikitina // Journal of Chemical Thermodynamics. - 1995. - V. 27, №9. - P945-952
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
СВОЙСТВА КРИТИЧЕСКИЕ -- КРИТИЧЕСКИЕ СВОЙСТВА -- ГИДРОГЕН ПЕРОКСИД -- ИЗМЕРЕНИЯ ПРЯМЫЕ -- ПРЯМЫЕ ИЗМЕРЕНИЯ -- ТЕПЛОФИЗИКА
Аннотация: The critical temperatures and the critical pressures of aqueous solutions with mass fractions of hydrogen peroxide from 0 to 0.9 have been measured using the pulse-heating method applicable to thermally unstable substances. The critical temperature and the critical pressure of pure hydrogen peroxide have been determined by extrapolation. The results are compared with the values predicted by various methods

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17.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical properties of some aliphatic symmetrical ethers [Electronic resource] / E. D. Nikitin, A. P. Popov, N. S. Bogatishcheva // Journal of Chemical Thermodynamics. - 2014. - Vol.68. - С. 288-292. - Bibliogr. : p. 292 (30 ref.)
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL PROPERTIES -- GROUP-CONTRIBUTION METHOD -- ETHERS
Аннотация: The critical temperatures Tc and the critical pressures p c of dihexyl, dioctyl, and didecyl ethers have been measured. According to the measurements, the coordinates of the critical points are T c = (665 ± 7) K, pc = (1.44 ± 0.04) MPa for dihexyl ether, Tc = (723 ± 7) K, pc = (1.19 ± 0.04) MPa for dioctyl ether, and Tc = (768 ± 8) K, pc = (1.03 ± 0.03) MPa for didecyl ether. All the ethers studied degrade chemically at near-critical temperatures. A pulse-heating method applicable to measuring the critical properties of thermally unstable compounds has been used. The times from the beginning of a heating pulse to the moment of reaching the critical temperature were from 0.06 to 0.46 ms. The short residence times provide little decomposition of the substances in the course of the experiments. The critical properties of the ethers investigated in this work have been discussed together with those of methyl to butyl ethers. The experimental critical constants of the ethers have been compared with those estimated by the group-contribution methods of Wilson and Jasperson and Marrero and Gani. The Wilson/Jasperson method provides a better estimation of the critical temperatures and pressures of simple aliphatic ethers in comparison with the Marrero/Gani method if reliable normal boiling temperatures are used in the method of Wilson and Jasperson

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18.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical properties of some aliphatic symmetrical ethers [Electronic resource] / E. D. Nikitin, A. P. Popov, N. S. Bogatishcheva // Journal of Chemical Thermodynamics. - 2014. - Vol.68. - С. 288-292. - Bibliogr. : p. 292 (30 ref.)
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL PROPERTIES -- GROUP-CONTRIBUTION METHOD -- ETHERS
Аннотация: The critical temperatures Tc and the critical pressures p c of dihexyl, dioctyl, and didecyl ethers have been measured. According to the measurements, the coordinates of the critical points are T c = (665 ± 7) K, pc = (1.44 ± 0.04) MPa for dihexyl ether, Tc = (723 ± 7) K, pc = (1.19 ± 0.04) MPa for dioctyl ether, and Tc = (768 ± 8) K, pc = (1.03 ± 0.03) MPa for didecyl ether. All the ethers studied degrade chemically at near-critical temperatures. A pulse-heating method applicable to measuring the critical properties of thermally unstable compounds has been used. The times from the beginning of a heating pulse to the moment of reaching the critical temperature were from 0.06 to 0.46 ms. The short residence times provide little decomposition of the substances in the course of the experiments. The critical properties of the ethers investigated in this work have been discussed together with those of methyl to butyl ethers. The experimental critical constants of the ethers have been compared with those estimated by the group-contribution methods of Wilson and Jasperson and Marrero and Gani. The Wilson/Jasperson method provides a better estimation of the critical temperatures and pressures of simple aliphatic ethers in comparison with the Marrero/Gani method if reliable normal boiling temperatures are used in the method of Wilson and Jasperson

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19.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical properties of some alkylnaphthalenes / E. D. Nikitin, A. P. Popov, N. S. Bogatishcheva // Fluid Phase Equilibria. - 2013. - Vol.358. - 296-s300. - Bibliogr. : p. s300 (41 ref.)
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ALKYLNAPHTHALENES -- GROUP-CONTRIBUTION METHOD -- CRITICAL PROPERTIES
Аннотация: The critical pressures and the critical temperatures of 1-methylnaphthalene, 2-methylnaphthalene, 1,3-dimethylnaphthalene, 1,4-dimethylnaphthalene, 2-ethylnaphthalene have been measured. All the alkylnaphthalenes investigated decompose at near-critical temperatures. A pulse-heating method applicable to measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from 0.03 to 0.46. ms. The short residence times provided little degradation of the substances in the course of the experiments. Comparisons with experimental results of other workers have been presented. The experimental critical constants of alkylnaphthalenes have been compared with those calculated by the group-contribution methods of Wilson and Jasperson and Marrero and Gani

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20.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical properties of some alkylnaphthalenes / E. D. Nikitin, A. P. Popov, N. S. Bogatishcheva // Fluid Phase Equilibria. - 2013. - Vol.358. - 296-s300. - Bibliogr. : p. s300 (41 ref.)
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ALKYLNAPHTHALENES -- GROUP-CONTRIBUTION METHOD -- CRITICAL PROPERTIES
Аннотация: The critical pressures and the critical temperatures of 1-methylnaphthalene, 2-methylnaphthalene, 1,3-dimethylnaphthalene, 1,4-dimethylnaphthalene, 2-ethylnaphthalene have been measured. All the alkylnaphthalenes investigated decompose at near-critical temperatures. A pulse-heating method applicable to measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from 0.03 to 0.46. ms. The short residence times provided little degradation of the substances in the course of the experiments. Comparisons with experimental results of other workers have been presented. The experimental critical constants of alkylnaphthalenes have been compared with those calculated by the group-contribution methods of Wilson and Jasperson and Marrero and Gani

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