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1.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P., Nikitina N. E.
Заглавие : Critical properties of hydrogen peroxide determined from direct measurements
Место публикации : Journal of Chemical Thermodynamics. - 1995. - V. 27, №9. - С. 945-952
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): свойства критические--критические свойства--гидроген пероксид--измерения прямые--прямые измерения--теплофизика
Аннотация: The critical temperatures and the critical pressures of aqueous solutions with mass fractions of hydrogen peroxide from 0 to 0.9 have been measured using the pulse-heating method applicable to thermally unstable substances. The critical temperature and the critical pressure of pure hydrogen peroxide have been determined by extrapolation. The results are compared with the values predicted by various methods
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2.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P., Nikitina N. E.
Заглавие : Critical properties of hydrogen peroxide determined from direct measurements
Место публикации : Journal of Chemical Thermodynamics. - 1995. - V. 27, №9. - С. 945-952
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): свойства критические--критические свойства--гидроген пероксид--измерения прямые--прямые измерения--теплофизика
Аннотация: The critical temperatures and the critical pressures of aqueous solutions with mass fractions of hydrogen peroxide from 0 to 0.9 have been measured using the pulse-heating method applicable to thermally unstable substances. The critical temperature and the critical pressure of pure hydrogen peroxide have been determined by extrapolation. The results are compared with the values predicted by various methods
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3.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical properties of some tetraalkoxysilanes and tetraalkoxytitaniums with branched alkyl radicals
Место публикации : Fluid Phase Equilibria. - 2012. - Vol.331. - С. 1-5
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): branched alkyl radicals--critical properties --tetraalkoxysilanes
Аннотация: The critical pressures and the critical temperatures of tetraisopropoxytitanium, tetra-tert-butoxytitanium, and tetraisopropoxysilane have been measured. The decomposition of the substances studied begins at temperatures below their critical ones. A pulse-heating method which allows measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from 0.03 to 1 ms. The short residence times provided little degradation of the substances in the course of the experiments. The critical constants of tetraalkoxytitaniums and tetraalkoxysilanes with branched and straight alkyl chains have been compared. The experimental critical constants of tetraalkoxytitaniums and tetraalkoxysilanes have also been compared with those calculated using various group-contribution methods
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4.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical properties of some tetraalkoxysilanes and tetraalkoxytitaniums with branched alkyl radicals
Место публикации : Fluid Phase Equilibria. - 2012. - Vol.331. - С. 1-5
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): branched alkyl radicals--critical properties --tetraalkoxysilanes
Аннотация: The critical pressures and the critical temperatures of tetraisopropoxytitanium, tetra-tert-butoxytitanium, and tetraisopropoxysilane have been measured. The decomposition of the substances studied begins at temperatures below their critical ones. A pulse-heating method which allows measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from 0.03 to 1 ms. The short residence times provided little degradation of the substances in the course of the experiments. The critical constants of tetraalkoxytitaniums and tetraalkoxysilanes with branched and straight alkyl chains have been compared. The experimental critical constants of tetraalkoxytitaniums and tetraalkoxysilanes have also been compared with those calculated using various group-contribution methods
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5.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical Temperatures and Pressures of Some Tetraalkoxytitaniums
Место публикации : Journal of Chemical & Engineering Data. - 2010. - Vol.55, №1. - С. 178-183
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical pressures--critical temperatures--tetraalkoxytitaniums
Аннотация: The critical pressures and the critical temperatures of nine tetraalkoxytitaniums, Ti[O(CH2)nH]4 with n = 2 to 10, have been measured. All of the substances studied begin to decompose at temperatures below their critical points. The method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 0.46) ms, which resulted in little decomposition of the substances during measuring. The contributions of the titanium(IV) atom in the group contribution methods of Constantinou and Gani and Marrero and Gani have been calculated from the experimental data. The critical pressures and temperatures of tetraalkoxytitaniums have been estimated by these methods
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6.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Yatluk Yu. G., Simakina V. A.
Заглавие : Critical Temperatures and Pressures of Some Tetraalkoxytitaniums
Место публикации : Journal of Chemical & Engineering Data. - 2010. - Vol.55, №1. - С. 178-183
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical pressures--critical temperatures--tetraalkoxytitaniums
Аннотация: The critical pressures and the critical temperatures of nine tetraalkoxytitaniums, Ti[O(CH2)nH]4 with n = 2 to 10, have been measured. All of the substances studied begin to decompose at temperatures below their critical points. The method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 0.46) ms, which resulted in little decomposition of the substances during measuring. The contributions of the titanium(IV) atom in the group contribution methods of Constantinou and Gani and Marrero and Gani have been calculated from the experimental data. The critical pressures and temperatures of tetraalkoxytitaniums have been estimated by these methods
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7.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S., Kuznetsov V. A.
Заглавие : Critical temperatures and pressures of straight-chain alkanediols (C3 to C12)
Место публикации : Fluid Phase Equilibria. - 2013. - Vol.355. - С. 40-45
Примечания : Bibliogr. : p. 45 (30 ref.)
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): alkanediols--critical properties --pulse-heating method
Аннотация: The critical pressures pc and the critical temperatures Tc of diols with straight alkylchains HO(CH2)nOH and n=3, 4, 5, 6, 8, 9, 10, 12 have been measured. All the alkanediols studied decompose at near-critical temperatures. A pulse-heating method which allows measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from (0.03 to 0.46)ms. The short residence times provided little degradation of the substances in the course of the experiments. The uncertainties of the measurement of the critical properties of alkanediols are 0.04 pc and 0.015 Tc, where Tc is the absolute temperature. The critical properties obtained have been compared with the values measured earlier by various techniques. The experimental critical constants of alkanediols have also been compared with those calculated using the group-contribution methods of Lydersen, Wilson and Jasperson, and Marrero and Gani
\\\\expert2\\NBO\\Fluid Phase Equilibria\\2013, v.355, p. 40-45.pdf
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8.

Вид документа : Статья из журнала
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S., Kuznetsov V. A.
Заглавие : Critical temperatures and pressures of straight-chain alkanediols (C3 to C12)
Место публикации : Fluid Phase Equilibria. - 2013. - Vol.355. - С. 40-45
Примечания : Bibliogr. : p. 45 (30 ref.)
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): alkanediols--critical properties --pulse-heating method
Аннотация: The critical pressures pc and the critical temperatures Tc of diols with straight alkylchains HO(CH2)nOH and n=3, 4, 5, 6, 8, 9, 10, 12 have been measured. All the alkanediols studied decompose at near-critical temperatures. A pulse-heating method which allows measuring the critical properties of thermally unstable compounds has been used. The times of heating from the beginning of a pulse to the moment of reaching the critical temperature were from (0.03 to 0.46)ms. The short residence times provided little degradation of the substances in the course of the experiments. The uncertainties of the measurement of the critical properties of alkanediols are 0.04 pc and 0.015 Tc, where Tc is the absolute temperature. The critical properties obtained have been compared with the values measured earlier by various techniques. The experimental critical constants of alkanediols have also been compared with those calculated using the group-contribution methods of Lydersen, Wilson and Jasperson, and Marrero and Gani
\\\\expert2\\NBO\\Fluid Phase Equilibria\\2013, v.355, p. 40-45.pdf
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9.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S., Yatluk Yu. G.
Заглавие : Critical Temperatures and Pressures of Straight-Chain Saturated Dicarboxylic Acids (C4 to C14)
Место публикации : Journal of Chemical & Engineering Data. - 2004. - Vol.49, №6. - С. 1515-1520
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): dicarboxylic acids --methods of ambrose--pressures
Аннотация: The critical temperatures and pressures of nine saturated straight-chain dicarboxylic acids HOOC(CH2)nCOOH with n = 2, 3, 4, 5, 6, 7, 8, 10, and 12 have been measured. All of the acids investigated are thermally unstable at their critical points. The method of pulse heating of a wire probe immersed in the liquid under study has been used. Residence times are from (0.01 to 1) ms. The experimental critical properties of dicarboxylic acids have been compared with the values calculated by the group-contribution methods of Ambrose, Joback, and Reid, Constantinou and Gani, and Marrero and Gani
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10.

Вид документа :
Шифр издания : 53/C 89
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S., Yatluk Yu. G.
Заглавие : Critical Temperatures and Pressures of Straight-Chain Saturated Dicarboxylic Acids (C4 to C14)
Место публикации : Journal of Chemical & Engineering Data. - 2004. - Vol.49, №6. - С. 1515-1520
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): dicarboxylic acids --methods of ambrose--pressures
Аннотация: The critical temperatures and pressures of nine saturated straight-chain dicarboxylic acids HOOC(CH2)nCOOH with n = 2, 3, 4, 5, 6, 7, 8, 10, and 12 have been measured. All of the acids investigated are thermally unstable at their critical points. The method of pulse heating of a wire probe immersed in the liquid under study has been used. Residence times are from (0.01 to 1) ms. The experimental critical properties of dicarboxylic acids have been compared with the values calculated by the group-contribution methods of Ambrose, Joback, and Reid, Constantinou and Gani, and Marrero and Gani
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11.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P.
Заглавие : (Gas+liquid) critical temperatures and pressures of polyethelene-glycols from HOCH2CH2OH to H(OCH2CH2)v=132OH
Место публикации : Journal of Chemical Thermodynamics. - 1995. - V. 27, №1. - С. 43-51
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): литье--жидкости--температура критическая--критическая температура--давление--полиэтилен-глюколь--hoch2ch2oh--h(och2ch2)v=132oh--h--o (кислород)--c--водород--кислород--углерод
Аннотация: The critical temperatures and pressures of mono-, di-, tri-, and tetra-ethene glycols, and polyethene glycols with nominal molar massesM/M°(whereM°= 1 g·mol−1) equal to 300, 400, and 600, have been measured by the pulse-heating method applicable to thermally unstable substances. The results have been correlated as a function of the molar mass using the hole theory of liquids developed by Kurata and Isida with a slight modification
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12.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P.
Заглавие : (Gas+liquid) critical temperatures and pressures of polyethelene-glycols from HOCH2CH2OH to H(OCH2CH2)v=132OH
Место публикации : Journal of Chemical Thermodynamics. - 1995. - V. 27, №1. - С. 43-51
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): литье--жидкости--температура критическая--критическая температура--давление--полиэтилен-глюколь--hoch2ch2oh--h(och2ch2)v=132oh--h--o (кислород)--c--водород--кислород--углерод
Аннотация: The critical temperatures and pressures of mono-, di-, tri-, and tetra-ethene glycols, and polyethene glycols with nominal molar massesM/M°(whereM°= 1 g·mol−1) equal to 300, 400, and 600, have been measured by the pulse-heating method applicable to thermally unstable substances. The results have been correlated as a function of the molar mass using the hole theory of liquids developed by Kurata and Isida with a slight modification
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13.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P.
Заглавие : (Vapour+liquid) critical properties and accentric factors of fine low-molarmass methylphenysiloxanes
Место публикации : Journal of Chemical Thermodynamics. - 1994. - V. 26. - С. 1047-1050
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): пар--жидкости--свойства критические--критические свойства--метилфенисилоксан низкомолярный--низкомолярный метилфенисилоксан--метилфенисилоксан тонкий--тонкий метилфенисилоксан--теплофизика
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14.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P.
Заглавие : (Vapour+liquid) critical properties and accentric factors of fine low-molarmass methylphenysiloxanes
Место публикации : Journal of Chemical Thermodynamics. - 1994. - V. 26. - С. 1047-1050
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): пар--жидкости--свойства критические--критические свойства--метилфенисилоксан низкомолярный--низкомолярный метилфенисилоксан--метилфенисилоксан тонкий--тонкий метилфенисилоксан--теплофизика
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15.

Вид документа :
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P.
Заглавие : Corrigendum to “Critical temperatures and pressures of 1-alkanols with 13 to 22 carbon atoms” [Fluid Phase Equilibria, 149 (1998) 223–232]
Место публикации : Fluid Phase Equilibria. - 2000. - Vol.168, №2. - С. 281
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical temperatures--1-alkanols--critical pressures
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16.

Вид документа :
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Pavlov P. A., Popov A. P.
Заглавие : Corrigendum to “Critical temperatures and pressures of 1-alkanols with 13 to 22 carbon atoms” [Fluid Phase Equilibria, 149 (1998) 223–232]
Место публикации : Fluid Phase Equilibria. - 2000. - Vol.168, №2. - С. 281
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): critical temperatures--1-alkanols--critical pressures
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17.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Popov A. P.
Заглавие : Critical point measurement of ferrocene and some of its derivatives
Место публикации : Fluid Phase Equilibria. - 2012. - Vol.324. - С. 13-16
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): 1-acetylferrocene--benzoylferrocene--ferrocene
Аннотация: The critical temperatures and the critical pressures of ferrocene, . n-butylferrocene, benzoylferrocene, and 1-acetylferrocene have been measured. All the compounds studied begin to decompose at temperatures below their critical points. A method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 1.0). ms, which resulted in little decomposition of the substances in the course of measuring. The contributions of the groups Fe. CH and Fe. C for the estimation of the critical properties of ferrocene derivatives by the method of Marrero and Gani have been determined from the experimental data
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18.

Вид документа : Статья из журнала
Шифр издания : 53/N 64
Автор(ы) : Nikitin E. D., Popov A. P.
Заглавие : Critical point measurement of ferrocene and some of its derivatives
Место публикации : Fluid Phase Equilibria. - 2012. - Vol.324. - С. 13-16
ББК : 53
Предметные рубрики: ФИЗИКА
Ключевые слова (''Своб.индексиров.''): 1-acetylferrocene--benzoylferrocene--ferrocene
Аннотация: The critical temperatures and the critical pressures of ferrocene, . n-butylferrocene, benzoylferrocene, and 1-acetylferrocene have been measured. All the compounds studied begin to decompose at temperatures below their critical points. A method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 1.0). ms, which resulted in little decomposition of the substances in the course of measuring. The contributions of the groups Fe. CH and Fe. C for the estimation of the critical properties of ferrocene derivatives by the method of Marrero and Gani have been determined from the experimental data
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19.

Вид документа :
Шифр издания :
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S.
Заглавие : Critical Point Measurements for Five n-Alkylcyclohexanes (C6 to C10) by the Pulse-Heating Method
Место публикации : Journal of Chemical & Engineering Data. - 2003. - Vol.48, №5. - С. 1137-1140
Ключевые слова (''Своб.индексиров.''): alkylcyclohexanes--carbons --methods of lydersen
Аннотация: This paper presents experimental critical temperatures and pressures of five n-alkylcyclohexanes C6H11CnH2n+1 with the number of carbons in the side chain n = 0, 1, 2, 3, or 4. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.01 to 1) ms. Equations for the correlation of the critical temperatures and pressures of n-alkylcyclohexanes with the number of carbon atoms in the side chain, normal boiling point, and molar mass have been obtained. The experimental critical constants of alkylcyclohexanes have been compared with the values calculated by the group-contribution methods of Lydersen, Joback and Reid, and Constantinou and Gani
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20.

Вид документа :
Шифр издания :
Автор(ы) : Nikitin E. D., Popov A. P., Bogatishcheva N. S.
Заглавие : Critical Point Measurements for Five n-Alkylcyclohexanes (C6 to C10) by the Pulse-Heating Method
Место публикации : Journal of Chemical & Engineering Data. - 2003. - Vol.48, №5. - С. 1137-1140
Ключевые слова (''Своб.индексиров.''): alkylcyclohexanes--carbons --methods of lydersen
Аннотация: This paper presents experimental critical temperatures and pressures of five n-alkylcyclohexanes C6H11CnH2n+1 with the number of carbons in the side chain n = 0, 1, 2, 3, or 4. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.01 to 1) ms. Equations for the correlation of the critical temperatures and pressures of n-alkylcyclohexanes with the number of carbon atoms in the side chain, normal boiling point, and molar mass have been obtained. The experimental critical constants of alkylcyclohexanes have been compared with the values calculated by the group-contribution methods of Lydersen, Joback and Reid, and Constantinou and Gani
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