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1.
Инвентарный номер: нет.
   
   S 34

    Schmelzer, J. W. P.
    Classical and generalized Gibbs' approaches and the work of critical cluster formation in nucleation theory [Electronic resource] / J. W. P. Schmelzer, G. Sh. Boltachev, V. G. Baidakov // Journal of Chemical Physics. - 2006. - Vol. 124, № 19. - P194503/1-194503/18
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CLUSTERS
Аннотация: In the theoretical interpretation of the kinetics of first-order phase transitions, thermodynamic concepts developed long ago by Gibbs are widely employed giving some basic qualitative insights into these processes. However, from a quantitative point of view, the results of such analysis, based on the classical Gibbs approach and involving in addition the capillarity approximation, are often not satisfactory. Some progress can be reached here by the van der Waals and more advanced density functional methods of description of thermodynamically heterogeneous systems having, however, its limitations in application to the interpretation of experimental data as well. Moreover, both mentioned theories—Gibbs’ and density functional approaches—lead to partly contradicting each other’s results. As shown in preceding papers, by generalizing Gibbs’ approach, existing deficiencies and internal contradictions of these two well-established theories can be removed and a new generally applicable tool for the interpretation of phase formation processes can be developed. In the present analysis, a comparative analysis of the basic assumptions and predictions of the classical and the generalized Gibbs approaches is given. It is shown, in particular, that—interpreted in terms of the generalized Gibbs approach—the critical cluster as determined via the classical Gibbs approach corresponds not to a saddle but to a ridge point of the appropriate thermodynamic potential hypersurface. By this reason, the classical Gibbs approach (involving the classical capillarity approximation) overestimates as a rule the work of critical cluster formation in nucleation theory and, in general, considerably.

\\\\Expert2\\NBO\\Journal of Chemical Physics\\2006, v.124, p.194503.pdf
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2.
Инвентарный номер: нет.
   
   S 61

   
    Simulation of radial pulsed magnetic compaction of a granulated medium in a quasi-static approximation [Electronic resource] / G. Sh. Boltachev, N. V. Volkov, S. V. Dobrov, V. V. Ivanov, A. A. Nozdrin, S. N. Paranin // Technical Physics. - 2007. - Vol. 52, № 10. - P1306-1315
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
MAGNETIC COMPACTION
Аннотация: Compression adiabats for alumina-based nanopowders are obtained experimentally, various conditions of pulsed magnetic cylindrically symmetric radial compaction of the nanopowders are tested, and the density distribution in the compacted powders are measured. Using the compression adiabats obtained, quasi-static compaction of a granulated (porous) medium, which is considered to be compact, is simulated. The conditions of uniform and equilibrium compaction on a rigid rod are analyzed. The voidage distribution, stress tensor, and amount of accumulated deformation are calculated. The features of nanopowder compaction, specifically, the presence (absence) of voidage nonuniform radial distribution, are explained.

\\\\Expert2\\NBO\\Technical Physics\\2007, v.52, N 10, p.1306.pdf
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3.
Инвентарный номер: нет.
   
   G 15

    Galashev, A. E.
    Dielectric characteristics of O2(H2O)i and (O2)2(H2O)i clusters. Computer-aided experiment [Текст] / A. E. Galashev, V. N. Chukanov, O. A. Galasheva // Colloid Journal (Translation of Kolloidnyi Zhurnal). - 2006. - Vol. 68, № 2. - С. 131-136
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
DIELECTRIC CONSTANT
Аннотация: Absorption of oxygen molecules by water clusters with sizes of 10 меньше либо равно i меньше либо равно 50 is studied by the molecular dynamics method using the modified TIP4P model. It is revealed that the total dipole moment of the clusters nonmonotonically increases with their sizes. Absorption of O2 molecules tends to raise the static permittivity of the ultradispersed medium formed by the clusters. The real and imaginary parts of the permittivity of water clusters with absorbed O2 molecules are aperiodic functions of frequency. The permittivity components turn out to be nonmonotonic functions of cluster sizes. The IR absorption and reflectance spectra are calculated for clusters of pure water and aggregates with absorbed O2 molecules. After the addition of oxygen molecules, the absorption coefficient of the clusters decreases, while the reflection coefficient increases. It is concluded that the capture of oxygen molecules by atmospheric moisture may reduce the greenhouse effect.

\\\\Expert2\\NBO\\Colloid Journal\\2006, V.68, N2,131.pdf
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4.
Инвентарный номер: нет.
   
   N 64

    Nikitin, E. D.
    Critical Pressures and Temperatures of n-Diaminoalkanes (C2 to C12) [Текст] / E. D. Nikitin, A. P. Popov, Yu. G. Yatluk // Journal of Chemical & Engineering Data. - 2006. - Vol. 51, № 2. - С. 609-111
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
CRITICAL PRESSURES
Аннотация: The critical temperatures and pressures of eight n-diaminoalkanes NH2(CH2)nNH2 with n = 2, 3, 4, 6, 8, 9, 10, and 12 have been measured. The method of pulse heating of a wire probe immersed into the liquid under study has been used. Residence times are from (0.03 to 1) ms. The critical properties of diaminoalkanes have been estimated by the group-contribution methods by Joback and Reid, Constantinou and Gani, and Marrero and Gani. These properties have also been calculated using a method based on the assumption that the functions describing the dependence of the critical properties of homologous series on the number of mers in a molecule should be self-similar and provide the scaling behavior for long-chain molecules. The last method provides the best accuracy in calculating the critical properties of diaminoalkanes. For this method, the average absolute errors are equal to 0.4 % for the critical temperature and about 2 % for the critical pressure. ??

\\\\Expert2\\NBO\\Journal of Chemical and Engineering Data\\2006, v.51, p.609.pdf
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5.
Инвентарный номер: нет.
   
   B 93

    Bulanov, N. V.
    A method of explosive effervescence of disperse-phase droplets for analysis of emulsions [] / N. V. Bulanov, V. A. Khmylnin // Industrial Laboratory. - 1994. - V.60, Is.10. - С. 599-602
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
EFFERVESCENCE EXPLOSIVE -- DISPERSE-PHASE DROPLETS -- EMULSIONS
Аннотация: A method and an experimental setup for dispersion analysis of emulsions based on overheating and explosive effervescence of disperse-phase droplets are described. Formulas are derived and a procedure for determining the fitting parameters for a description of the dispersive composition of an emulsion is given. The maximum count rate was about 500 droplets per second for droplet diameters ranging from 5 to 200 mu m. The method can be automated to handle high-viscosity, opaque, unstable, and heavily contaminated emulsions

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6.
Инвентарный номер: нет.
   
   P 31

    Pastukhov, V. G.
    Adaptation of loop heat pipes to zero-g conditions / V. G. Pastukhov, Yu. F. Maydanik, Y. G. Fershtater // 6th European Symposium on Space Environmental Control Systems: Noordwijk, Netherlands, 20-22 may 1997 . - 1997. - Vol.400. - С. 385-391
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
LOOP HEAT PIPES -- HEAT-TRANSPORT -- THERMOCAPILLARY PHENOMENA
Аннотация: Loop heat pipes (LHPs) posses a great variety of valuable properties, which make them quite promising for application both on the Earth and in space. Among these are the LHP high heat-transport capacity at an any orientation in the field of mass forces, good mass-and-size parameters and the possibility of an arbitrary configuration of transport lines. At the same time such a drawback of LHPs of the conventional type as the instability of start up and operation in the region of low heat loads reduces their performance. The problem is connected, in a general case, with the unfavourable distribution of the vapor and the liquid phases of the working fluid in the evaporator. There is reason to believe that the LHP operation can also be significantly affected by zero-g conditions, in which the distribution of a working fluid is pre-determined only by the action of surface forces and the thermocapillary phenomena. The paper performs a general analysis of the necessary conditions imposed on the construction of LHP and some designs that contribute to the retention of serviceability in zero-g conditions at low heat loads. It gives the results of laboratory investigations of an adapted ammonia LHP with a heat-transfer capacity up to 2 kWxm

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7.
Инвентарный номер: нет.
   
   T 44

   
    The proof-of-feasibility of multiple evaporator loop heat pipes / W. B. Bienert, D. A. Wolf, M. N. Nikitkin, Yu. F. Maydanik, Y. G. Fershtater, S. V. Vershinin, J. M. Gottschlich // 6th European Symposium on Space Environmental Control Systems: Noordwijk, Netherlands, 20-22 may 1997 . - 1997. - Vol.400. - С. 393-398
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
LOOP HEAT PIPES -- THERMAL CONTROL -- MULTIPLE THERMAL INTERFACE
Аннотация: This paper presents results that demonstrate the proof-of-feasibility of multiple evaporator Loop Heat Pipes (LHP). It was demonstrated that a multiple evaporator LHP can successfully operate as a thermal control system component. A breadboard LHP with multiple evaporators (two) that retained the reliable self starting behavior of the single thermal interface LHP was developed. Program efforts were concentrated on a two pump system and investigated the performance of the dual evaporator LHP. Analytical predictons and experimental test data are compared, and important issues are discussed that will be a baseline for continued development of multiple thermal interface LHPs. All of the conclusions are based on test results, analytic modeling and the correlation of the two. Although a mathematical model that predicts the multiple evaporator LHP behavior was developed, the primary focus of the program was the development, fabrication, and test of a breadboard multi-evaporator LHP. The program clearly demonstrated that multi-evaporator LHPs are feasible and merit further development as a viable thermal control components

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8.
Инвентарный номер: нет.
   
   V 50

    Vershinin, S. V.
    Effect of the thermal contact resistance on heat-transfer during boiling from fine porous capillary structures / S. V. Vershinin, Y. G. Fershtater, Yu. F. Maydanik // High Temperature. - 1992. - Vol.30, №4. - С. 668-673
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
HEAT TRAHSFER -- VAPOR FORMATION
Аннотация: The dependence of the heat transfer rate on the geometry of vapor channels is investigated analytically and experimentally with a consideration of the thermal contact resistance during vapor formation in fine porous structures for carrying away the vapor. It is shown that the larger the contact resistance, the greater the distance between the channels must be to maximize the values of the heat-transfer coefficients

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9.
Инвентарный номер: нет.
   
   B 16

    Baidakov, V. G.
    Metastable extensions of phase equilibrium lines and singular points of simple substance / V. G. Baidakov, S. P. Protsenko // Journal of Experimental and Theoretical Physics. - 2006. - Vol.103, №6. - С. 876-886
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
THERMODYNAMIC PROPERTIES -- CRYSTAL -- LIQUID -- GAS
Аннотация: The thermodynamic properties of crystal, liquid, and gas in the stable and metastable states have been determined by molecular dynamics simulation of a system of 2048 Lennard-Jones particles. The spinodals of a superheated crystal, a superheated liquid, and a supersaturated vapor have been approximated; the spinodal for a supercooled liquid turns out to be nonexistent. The liquid-vapor, liquid-crystal, and crystal-vapor equilibrium curves and their extensions beyond the triple point have been calculated. It has been shown that, as distinct from the metastable extension of the saturation curve, which terminates at the zero isotherm, the metastable melting and sublimation curves terminate at, respectively, the stretched liquid and superheated crystal spinodals. The properties of the critical end points of metastable equilibrium of extended phases are considered

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10.
Инвентарный номер: нет.
   
   B 16

    Baidakov, V. G.
    Effect of the cut-off radius of the intermolecular potential on phase equilibrium and surface tension in Lennard–Jones systems / V. G. Baidakov, G. G. Chernykh, S. P. Protsenko // Chemical Physics Letters. - 2000. - Vol.321, №3-4. - С. 315-320
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
MOLECULAR-DYNAMICS SIMULATION -- LIQUID-VAPOR INTERFACE -- LENNARD-JONES FLUID
Аннотация: We present the molecular dynamic simulation results for the liquid–vapour interface of the pure Lennard–Jones fluid. The thermodynamical properties, the surface tension, the effective thickness of interfacial layer and the mean-square amplitude of capillary waves are determined. Calculations have been performed at cut-off radii of the intermolecular potential rc1=2.6σ and rc2=6.78σ. It is shown that the cut-off radius of the interaction potential in the two-phase systems should be chosen to be larger than that in the one-phase systems for an adequate representation of properties

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