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1.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Attainable Superheat of Argon-Helium, Argon-Neon Solutions [Text] / V. G. Baidakov, A. M. Kaverin, V. N. Andbaeva // Journal of Physical Chemistry B. - 2008. - Vol. 112, № 41. - P12973-12975
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ARGON
Аннотация: The method of lifetime measurement has been used to investigate the kinetics of spontaneous boiling-up of superheated argonhelium and argon?neon solutions. Experiments were made at a pressure of p = 1.5 MPa and concentrations up to 0.33 mol% in the range of nucleation rates from 104 to 108 s1 m3. The homogeneous nucleation regime has been distinguished. With good agreement between experimental data and homogeneous nucleation theory in temperature and concentration dependences of the nucleation rate, a systematic underestimation by 0.250.34 K has been revealed in superheat temperatures over the saturated line attained by experiment as compared with theoretical values calculated in a macroscopic approximation. The revealed disagreement between theory and experiment is connected with the dependence of the properties of new-phase nuclei on their size.

\\EXPERT2\NBO\Journal of Physical Chemistry B\2008, v.112, p.12973.pdf
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2.
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   B 16


    Baidakov, V. G.
    Attainable Superheat of Argon-Helium, Argon-Neon Solutions [Text] / V. G. Baidakov, A. M. Kaverin, V. N. Andbaeva // Journal of Physical Chemistry B. - 2008. - Vol. 112, № 41. - P12973-12975
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ARGON
Аннотация: The method of lifetime measurement has been used to investigate the kinetics of spontaneous boiling-up of superheated argonhelium and argon?neon solutions. Experiments were made at a pressure of p = 1.5 MPa and concentrations up to 0.33 mol% in the range of nucleation rates from 104 to 108 s1 m3. The homogeneous nucleation regime has been distinguished. With good agreement between experimental data and homogeneous nucleation theory in temperature and concentration dependences of the nucleation rate, a systematic underestimation by 0.250.34 K has been revealed in superheat temperatures over the saturated line attained by experiment as compared with theoretical values calculated in a macroscopic approximation. The revealed disagreement between theory and experiment is connected with the dependence of the properties of new-phase nuclei on their size.

\\EXPERT2\NBO\Journal of Physical Chemistry B\2008, v.112, p.12973.pdf
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3.
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   B 16


    Baidakov, V. G.
    Attainable Superheating of Liquid Helium–Oxygen Solutions / V. G. Baidakov, A. M. Kaverin // High Temperature. - 2000. - Vol.38, №6. - С. 852-859
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
NUCLEATION -- THEORY OF HOMOGENEOUS NUCLEATION -- BOILING
Аннотация: The results are given of experimental investigations of the kinetics of nucleation in gas-saturated helium-oxygen solutions. The temperature dependences of the mean lifetime of solution in the metastable (superheated) state are determined for fixed values of pressure of 1.171 and 1.667 MPa and for several values of concentration. The experimental data are compared with the theory of homogeneous nucleation in a macroscopic approximation with due regard for the dependence of the properties of the nuclei on their size. The dimensional effect is included within van der Waals' gradient expansion. The problems associated with the construction of the kinetic theory of boiling of gas-saturated solutions are discussed, and good agreement is ascertained between the experimental data and the theory of nucleation when the latter includes the dimensional effect

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4.
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   B 16


    Baidakov, V. G.
    Attainable Superheating of Liquid Helium–Oxygen Solutions / V. G. Baidakov, A. M. Kaverin // High Temperature. - 2000. - Vol.38, №6. - С. 852-859
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
NUCLEATION -- THEORY OF HOMOGENEOUS NUCLEATION -- BOILING
Аннотация: The results are given of experimental investigations of the kinetics of nucleation in gas-saturated helium-oxygen solutions. The temperature dependences of the mean lifetime of solution in the metastable (superheated) state are determined for fixed values of pressure of 1.171 and 1.667 MPa and for several values of concentration. The experimental data are compared with the theory of homogeneous nucleation in a macroscopic approximation with due regard for the dependence of the properties of the nuclei on their size. The dimensional effect is included within van der Waals' gradient expansion. The problems associated with the construction of the kinetic theory of boiling of gas-saturated solutions are discussed, and good agreement is ascertained between the experimental data and the theory of nucleation when the latter includes the dimensional effect

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5.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Capillary constant and surface tension of methane-helium solution [Electronic resource] / V. G. Baidakov, K. A. Grishina // Fluid Phase Equilibria. - 2013. - Vol.354. - P245-249. - Bibliogr. : p. 249 (21 ref.)
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ADSORPTION -- CAPILLARY CONSTANT -- DIFFERENTIAL CAPILLARY METHOD
Аннотация: The differential capillary method has been used to measure the capillary constant a2 of methane-helium solutions in the temperature range from 95 to 175K at pressures up to 4MPa. The surface tension γ and adsorption have been calculated from the obtained values of a2 employing, in addition, literature data on the density of the liquid and vapor phases of the respective solutions. Equations, which approximate the temperature, pressure and concentration dependences of a2 and γ, are proposed

\\\\expert2\\NBO\\Fluid Phase Equilibria\\2013, v.354, p. 245-249.pdf
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6.
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   B 16


    Baidakov, V. G.
    Capillary constant and surface tension of methane-helium solution [Electronic resource] / V. G. Baidakov, K. A. Grishina // Fluid Phase Equilibria. - 2013. - Vol.354. - P245-249. - Bibliogr. : p. 249 (21 ref.)
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
ADSORPTION -- CAPILLARY CONSTANT -- DIFFERENTIAL CAPILLARY METHOD
Аннотация: The differential capillary method has been used to measure the capillary constant a2 of methane-helium solutions in the temperature range from 95 to 175K at pressures up to 4MPa. The surface tension γ and adsorption have been calculated from the obtained values of a2 employing, in addition, literature data on the density of the liquid and vapor phases of the respective solutions. Equations, which approximate the temperature, pressure and concentration dependences of a2 and γ, are proposed

\\\\expert2\\NBO\\Fluid Phase Equilibria\\2013, v.354, p. 245-249.pdf
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7.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Capillary constant and the surface tension for nitrogen-helium solutions / V. G. Baidakov, A. M. Kaverin // Russian Journal of Physical Chemistry A. - 2004. - Vol.78, №6. - С. 1000-1002
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
LIQUID -- HELIUM -- NITROGEN

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8.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Capillary constant and the surface tension for nitrogen-helium solutions / V. G. Baidakov, A. M. Kaverin // Russian Journal of Physical Chemistry A. - 2004. - Vol.78, №6. - С. 1000-1002
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
LIQUID -- HELIUM -- NITROGEN

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9.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Experimental investigations of nucleation in helium-oxygen mixtures / V. G. Baidakov, A. M. Kaverin, G. Sh. Boltachev // Journal of Physical Chemistry B. - 2002. - Vol.106, №1. - С. 167-175
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
SUPERSATURATED SOLUTIONS -- HOMOGENEOUS NUCLEATION -- SURFACE TENSION
Аннотация: The paper presents the results of experimental investigations of nucleation in helium-oxygen gas-filled mixtures. Temperature dependences of the mean lifetime of a mixture in the metastable (superheated) state have been determined, and nucleation rates have been calculated by experiments at fixed pressures of 1.171 and 1.667 MPa and at several values of concentrations. Experimental data are compared with results of the homogeneous nucleation theory in a macroscopic (capillary) approximation and with allowance for the dependence of the properties of nuclei on the curvature of their dividing surface. The size effect of nucleation is taken into account in the framework of the van der Waals, Cahn-Hilliard method. The equation of state of the mixture has been built, and the boundary of stability of homogeneous states, the diffusion spinodal, has been determined. The paper discusses the problems of building a nucleation theory for gas-filled mixtures and states a good agreement between theory and experiment at nucleation rates J similar or equal to 10(7) m(-1) s(-1) when the size effect in nucleation is taken into account

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10.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Experimental investigations of nucleation in helium-oxygen mixtures / V. G. Baidakov, A. M. Kaverin, G. Sh. Boltachev // Journal of Physical Chemistry B. - 2002. - Vol.106, №1. - С. 167-175
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
SUPERSATURATED SOLUTIONS -- HOMOGENEOUS NUCLEATION -- SURFACE TENSION
Аннотация: The paper presents the results of experimental investigations of nucleation in helium-oxygen gas-filled mixtures. Temperature dependences of the mean lifetime of a mixture in the metastable (superheated) state have been determined, and nucleation rates have been calculated by experiments at fixed pressures of 1.171 and 1.667 MPa and at several values of concentrations. Experimental data are compared with results of the homogeneous nucleation theory in a macroscopic (capillary) approximation and with allowance for the dependence of the properties of nuclei on the curvature of their dividing surface. The size effect of nucleation is taken into account in the framework of the van der Waals, Cahn-Hilliard method. The equation of state of the mixture has been built, and the boundary of stability of homogeneous states, the diffusion spinodal, has been determined. The paper discusses the problems of building a nucleation theory for gas-filled mixtures and states a good agreement between theory and experiment at nucleation rates J similar or equal to 10(7) m(-1) s(-1) when the size effect in nucleation is taken into account

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11.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Kinetics of boiling-up of a gassed liquid / V. G. Baidakov, A. M. Kaverin, G. Sh. Boltachev // Heat Transfer Research. - 2007. - Vol.38, №3. - С. 211-221
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
LIQUID -- SOLUTIONS -- INERTIAL FORCES
Аннотация: A theory of the spontaneous boiling-up of supersaturated liquid solutions, which allows for all major factors limiting growth of a nucleus, such as volatility of solution components, viscous and inertial forces, and diffusional supply of a substance to the bubble, is proposed. Two approaches to determining the work of critical nucleus formation, based on the Gibbs method of diving surfaces and the Van der Waals theory of capillarity, are reviewed. Experimental data on the kinetics of boiling-up of nitrogen-helium and oxygen-helium solutions are presented. The results of the experiments are compared to the theoretical approaches to the problem of nucleation in gassed liquids, developed by the authors

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12.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Kinetics of boiling-up of a gassed liquid / V. G. Baidakov, A. M. Kaverin, G. Sh. Boltachev // Heat Transfer Research. - 2007. - Vol.38, №3. - С. 211-221
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
LIQUID -- SOLUTIONS -- INERTIAL FORCES
Аннотация: A theory of the spontaneous boiling-up of supersaturated liquid solutions, which allows for all major factors limiting growth of a nucleus, such as volatility of solution components, viscous and inertial forces, and diffusional supply of a substance to the bubble, is proposed. Two approaches to determining the work of critical nucleus formation, based on the Gibbs method of diving surfaces and the Van der Waals theory of capillarity, are reviewed. Experimental data on the kinetics of boiling-up of nitrogen-helium and oxygen-helium solutions are presented. The results of the experiments are compared to the theoretical approaches to the problem of nucleation in gassed liquids, developed by the authors

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13.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Nucleation in a superheated nitrogen-helium solution [] / V. G. Baidakov // Chemical Physics Letters. - 2008. - Vol. 462, № 4-6. - С. 201-204
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
HELIUM
Аннотация: The method of lifetime measurement has been used to investigate the nucleation of the vapor phase in a superheated liquid nitrogen–helium solution. Temperature dependences of the mean lifetime of a metastable solution have been obtained in experiments at pressures p = 0.5, 1.0 MPa and several values of the mixture concentration. The nucleation rate J has been calculated. It varied in experiments from 104 tо 108 s?1 m?3. The results of experiments are compared with homogeneous nucleation theory. The paper deals with the size effect on the surface tension of a nucleus and the work of its formation.

\\\\Expert2\\nbo\\Chemical Physics Letters\\2008, v. 462, p.201.pdf
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14.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Nucleation in a superheated nitrogen-helium solution [] / V. G. Baidakov // Chemical Physics Letters. - 2008. - Vol. 462, № 4-6. - С. 201-204
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
HELIUM
Аннотация: The method of lifetime measurement has been used to investigate the nucleation of the vapor phase in a superheated liquid nitrogen–helium solution. Temperature dependences of the mean lifetime of a metastable solution have been obtained in experiments at pressures p = 0.5, 1.0 MPa and several values of the mixture concentration. The nucleation rate J has been calculated. It varied in experiments from 104 tо 108 s?1 m?3. The results of experiments are compared with homogeneous nucleation theory. The paper deals with the size effect on the surface tension of a nucleus and the work of its formation.

\\\\Expert2\\nbo\\Chemical Physics Letters\\2008, v. 462, p.201.pdf
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15.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Surface tension of helium-oxygen and helium-ethane solutions [Text] / V. G. Baidakov, I. I. Sulla // International Journal of Thermophysics. - 1995. - V. 16, N 4. - P909-927
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
НАТЯЖЕНИЕ ПОВЕРХНОСТНОЕ -- ПОВЕРХНОСТНОЕ НАТЯЖЕНИЕ -- РАСТВОРЫ -- ГЕЛИЙ-КИСЛОРОД -- ГЕЛИЙ-ЭТАН -- ГЕЛИЙ -- He (ГЕЛИЙ) -- КИСЛОРОД -- O (КИСЛОРОД) -- ЭТАН -- C2H6 -- ГАЗЫ -- зависимости температурные -- ТЕМПЕРАТУРНАЯ ЗАВИСИМОСТЬ -- ДАВЛЕНИЕ -- ТЕПЛОФИЗИКА
Аннотация: На основе измерений высоты подъема в капиллярных трубках насыщенных газом растворов He-O2 и He-C2H6 определены их константы капиллярности а и поверхностное натяжение сигма. Измерения проведены в диапазоне от температуры замерзания раствора до 0,9Тс (Тс-критическая температура растворителя) при давлениях от давления насыщения до 5 МПа. предложены формулы, аппроксимирующие зависимости а от p и сигма от концепции. Полученные данные описываются теорией поверхностного слоя конечной толщины, мономолекулярное приближение не удовлетворительно даже ниже нормальной температуры кипения

\\EXPERT2\NBO\International Journal of Thermophysics\1995, V.16, N 4, p.909.pdf
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16.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    Surface tension of helium-oxygen and helium-ethane solutions [Text] / V. G. Baidakov, I. I. Sulla // International Journal of Thermophysics. - 1995. - V. 16, N 4. - P909-927
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
НАТЯЖЕНИЕ ПОВЕРХНОСТНОЕ -- ПОВЕРХНОСТНОЕ НАТЯЖЕНИЕ -- РАСТВОРЫ -- ГЕЛИЙ-КИСЛОРОД -- ГЕЛИЙ-ЭТАН -- ГЕЛИЙ -- He (ГЕЛИЙ) -- КИСЛОРОД -- O (КИСЛОРОД) -- ЭТАН -- C2H6 -- ГАЗЫ -- зависимости температурные -- ТЕМПЕРАТУРНАЯ ЗАВИСИМОСТЬ -- ДАВЛЕНИЕ -- ТЕПЛОФИЗИКА
Аннотация: На основе измерений высоты подъема в капиллярных трубках насыщенных газом растворов He-O2 и He-C2H6 определены их константы капиллярности а и поверхностное натяжение сигма. Измерения проведены в диапазоне от температуры замерзания раствора до 0,9Тс (Тс-критическая температура растворителя) при давлениях от давления насыщения до 5 МПа. предложены формулы, аппроксимирующие зависимости а от p и сигма от концепции. Полученные данные описываются теорией поверхностного слоя конечной толщины, мономолекулярное приближение не удовлетворительно даже ниже нормальной температуры кипения

\\EXPERT2\NBO\International Journal of Thermophysics\1995, V.16, N 4, p.909.pdf
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17.
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   B 16


    Baidakov, V. G.
    The attainable superheating of nitrogen-helium solutions [Electronic resource] / V. G. Baidakov // Russian Journal of Physical Chemistry A. - 2009. - Vol.83, №10. - P1751-1756
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
HOMOGENEOUS NUCLEATION -- OXYGEN -- KRYPTON
Аннотация: The nucleation of the vapor phase in superheated nitrogen-helium liquid solutions was studied by lifetime measurements. The temperature dependences of the mean lifetime of metastable solutions were obtained at p = 0.5 and 1.0 MPa and several concentrations. The nucleation rate J was found to vary from 10(4) to 10(8) s(-1) m(-3). The adsorption of the high-volatility component on the metastable liquid-critical bubble boundary was shown to play a determining role in decreasing the temperature of the attainable solution super-heating as the solution concentration increased. The experimental data were compared with homogeneous nucleation theory. Systematic discrepancies were obtained; these discrepancies were related to the influence of the size effect on the surface tension of a nucleus and the work of its formation

\\\\Expert2\\nbo\\Russian Journal of Physical Chemistry A, Focus on Chemistry\\2009, v. 83, N 10, p.1751.pdf
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18.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    The attainable superheating of nitrogen-helium solutions [Electronic resource] / V. G. Baidakov // Russian Journal of Physical Chemistry A. - 2009. - Vol.83, №10. - P1751-1756
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
HOMOGENEOUS NUCLEATION -- OXYGEN -- KRYPTON
Аннотация: The nucleation of the vapor phase in superheated nitrogen-helium liquid solutions was studied by lifetime measurements. The temperature dependences of the mean lifetime of metastable solutions were obtained at p = 0.5 and 1.0 MPa and several concentrations. The nucleation rate J was found to vary from 10(4) to 10(8) s(-1) m(-3). The adsorption of the high-volatility component on the metastable liquid-critical bubble boundary was shown to play a determining role in decreasing the temperature of the attainable solution super-heating as the solution concentration increased. The experimental data were compared with homogeneous nucleation theory. Systematic discrepancies were obtained; these discrepancies were related to the influence of the size effect on the surface tension of a nucleus and the work of its formation

\\\\Expert2\\nbo\\Russian Journal of Physical Chemistry A, Focus on Chemistry\\2009, v. 83, N 10, p.1751.pdf
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19.
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   B 16


    Baidakov, V. G.
    The sugden parameter and the surface tension of solutions of helium on liquefied gases [Text] / V. G. Baidakov, I. I. Sulla // XI IUPAC Conference on Chemical Thermodynamics, Como, Italy, 1990, 26 - 31 Aug. - 1990. - P459
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
НАТЯЖЕНИЕ ПОВЕРХНОСТНОЕ -- ПОВЕРХНОСТНОЕ НАТЯЖЕНИЕ -- РАСТВОРЫ ГЕЛИЯ -- ГАЗЫ ЖИДКИЕ -- ЖИДКИЕ ГАЗЫ -- ТЕПЛОФИЗИКА -- КОНФЕРЕНЦИИ -- ДОКЛАДЫ

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20.
Инвентарный номер: нет.
   
   B 16


    Baidakov, V. G.
    The sugden parameter and the surface tension of solutions of helium on liquefied gases [Text] / V. G. Baidakov, I. I. Sulla // XI IUPAC Conference on Chemical Thermodynamics, Como, Italy, 1990, 26 - 31 Aug. - 1990. - P459
ББК 53
Рубрики: ФИЗИКА
Кл.слова (ненормированные):
НАТЯЖЕНИЕ ПОВЕРХНОСТНОЕ -- ПОВЕРХНОСТНОЕ НАТЯЖЕНИЕ -- РАСТВОРЫ ГЕЛИЯ -- ГАЗЫ ЖИДКИЕ -- ЖИДКИЕ ГАЗЫ -- ТЕПЛОФИЗИКА -- КОНФЕРЕНЦИИ -- ДОКЛАДЫ

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