B 18 Balakireva, V. B. Proton and hole transport in CaO-doped erbia [Text] / V. B. Balakireva, V. P. Gorelov // Solid State Ionics. - 1989. - V. 36, N 3-4. - P217-218. - Bibliogr.: p. 217 ( 2 ref.) . - ISSN 0167-2738 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ХИМИЯ -- ОКСИД КАЛЬЦИЯ -- КАЛЬЦИЙ -- Ca -- ЭРБИЙ -- Er -- ПЕРЕНОС ПРОТОННЫЙ -- ПРОТОННЫЙ ПЕРЕНОС -- ПЕРЕНОС ДЫРОЧНЫЙ -- ДЫРОЧНЫЙ ПЕРЕНОС -- CaO |
N 48 Neuimin, A. D. Rare-earth elements-based solid electrolytes [Text] / A. D. Neuimin, V. B. Balakireva, S. F. Pal'guev // 29-th Meet. Int. Soc. Electrochem. (Budapest, 28 aug.-2 sept. 1978): Extend. Abstr. - 1978. - Part 1. - P327-329 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ЭЛЕКТРОЛИТ ТВЕРДЫЙ -- ЭЛЕМЕНТ РЕДКОЗЕМЕЛЬНЫЙ -- МЕТАЛЛЫ РЕДКОЗЕМЕЛЬНЫЕ |
C 73 Conductivity and thermal expansion of the Ce0.8Gd0.2O1.9 solid electrolyte in the oxidizing and reducing atmospheres [Текст] / V. P. Gorelov, V. B. Balakireva, I. Yu. Yaroslavtsev, V. A. Kazantsev, E. G. Vaganov // Russian Journal of Electrochemistry. - 2007. - Vol. 43, № 8. - С. 888-893. - Библиогр. : с. 893 (18 назв.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ПРОВОДИМОСТЬ ВЫСОКОТЕМПЕРАТУРНАЯ \\\\Cserver\\dist\\НБО\\Cтатьи БД ИВТЭ\\Russian Journal of Electrochemistry\\2007, V. 43, № 8, С. 888-893.pdf |
T 89 Tsidilkovski, V. I. Thermoelectric power of proton conducting oxides [Текст] / V. I. Tsidilkovski, V. P. Gorelov, V. B. Balakireva // Solid State Ionics. - 2003. - Vol. 162-163. - С. 55-61. Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): PROTON CONDUCTING OXIDES -- THERMOELECTRIC POWER Аннотация: A theory of thermopower for proton conducting oxides (PCO) with protons, oxide ions and different electron charge carriers has been developed. The thermopower альфа of SrCe0.95Y0.05O3 дельта, BaCe0.9Nd0.1O3 дельта and of a zirconium–yttrium electrolyte as a reference material was measured in both oxidizing and reducing atmospheres. The analysis of the data obtained for the region of pure protonic conduction of SrCe0.95Y0.05O3 дельта using our theoretical results and including vibrational and configurational contributions to альфа allowed determining both the partial entropy of protons and their heat of transport. The concentrations of protons and their temperature dependences determined from the entropy term agreed well with the experimental data available from hydrogen uptake studies. \\\\Cserver\\dist\\НБО\\Cтатьи БД ИВТЭ\\Solid State Ionics\\2003, V. 162-163, С. 55-61.pdf |
N 48 Neuimin, A. D. Rare-earth elements-based solid electrolytes [Text] / A. D. Neuimin, V. B. Balakireva, S. F. Pal'guev // 29-th Meet. Int. Soc. Electrochem. (Budapest, 1978, Aug. 28 - Sept. 2): Extend. Abstr. - 1978. - Part 1. - P327-329 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): METAL RARE-EARTH -- ELEMENT RARE-EARTH -- ELECTROLYTE SOLID |
D 48 Deuterium diffusion in proton conductors La0.9Sr0.1ScO3 -δ and BaZr0.9Y0.1O3 -δ at room temperature / V. B. Vykhodets, T. E. Kurennykh, O. A. Nefedova, V. P. Gorelov, A. Yu. Stroeva, V. B. Balakireva, E. V. Vykhodets, S. I. Obukhov // Solid State Ionics. - 2014. - P. 152-156. - Bibliogr. : p. 156 (15 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): КОЭФФИЦИЕНТ АКТИВНОСТИ КИСЛОРОДА -- ПРОТОННЫЕ ПРОВОДНИКИ -- ПАР Аннотация: Room-temperature measurements of diffusion coefficients for deuterium in proton conductors La0.9Sr0.1ScO3 -δ and BaZr0.9Y0.1O3 -δ which contain dissolved H2O vapor have been performed. The concentration of oxygen structure vacancies in oxides after treatment in vapor was close to zero. A diffusion source of deuterium was created by ion implantation; measurement of the concentration–distance distribution of deuterium in samples was performed in situ during implantation. The NRA technique and 2H(d,p)3H reaction at an energy of the incident beam of 650 keV were used. For the initial and boundary conditions of the diffusion problem which were realized in the work, a solution of the inhomogeneous Fick equation was obtained. Using the technique developed, measurements of the diffusion coefficients for hydrogen in proton conductors were for the first time performed directly. For the BaZr0.9Y0.1O3 -δ oxide, the directly gained values of diffusion coefficients agree rather well with those obtained from the proton conductivity with the use of Nernst–Einstein equation |
E 43 Electrical conductivity of CaZr1 - x (x = 0.01-0.20) in DrY and humid AIR / V. P. Gorelov, V. B. Balakireva, A. V. Kuz'min, S. V. Plaksin // Inorganic Materials . - 2014. - Vol. 50, № 5. - С. 495-502 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ПРОВОДИМОСТЬ -- СТРУКТУРА Аннотация: Изучена общая проводимость СaZr1 - xScxO3 - (x = 0.010.20) четырехзондовым методом на постоянном токе в интервале температур 600900°С в атмосфере влажного воздуха (рН2 = 402500 Па); методом импеданса изучен образец СaZr0.95Sc0.05O3 - . Измерены числа переноса ионов и протонов CaZr0.95Sc0.05O3 - при разных влажностях. Особенности на температурных зависимостях электропроводности сопоставлены с данными дилатометрии и трактуются как структурные изменения в кислородной подрешетке. |
H 99 Hydrogen isotope exchange in proton-conducting oxides during proton and deuteron irradiation / E. V. Vykhodets, T. E. Kurennykh, S. I. Obukhov, V. P. Gorelov , V. B. Balakireva, E. V. Vykhodets // Journal of Experimental and Theoretical Physics Letters (Jetp Letters). - 2013. - Vol. 97, № 11. - 624-627. Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ВОДОРОД -- ПРОТОННАЯ ПРОВОДИМОСТЬ |