N 89 Novoselova, A. V. Samarium and europium redox potentials in molten alkali chlorides [Text] / A. V. Novosielova, V. A. Khokhlov, V. Y. Shishkin // Progress in Molten Salt Chemistry: Proceedings from the EUCHEM 2000 Conference on Molten Salts (Denmark, August 20-25, 2000). - 2000. - V. 1. - P379-384. - Bibliogr.: p. 383-384 (12 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ХИМИЯ -- ХЛОРИДЫ РЕДКОЗЕМЕЛЬНЫХ МЕТАЛЛОВ -- МЕТАЛЛЫ РЕДКОЗЕМЕЛЬНЫЕ -- РЕДКОЗЕМЕЛЬНЫЕ МЕТАЛЛЫ -- ХЛОРИД САМАРИЯ -- ХЛОРИД ЕВРОПИЯ -- РЕДОКС-ПОТЕНЦИАЛЫ -- ХЛОРИДЫ ЩЕЛОЧНЫХ МЕТАЛЛОВ -- МЕТАЛЛЫ ЩЕЛОЧНЫЕ -- ЩЕЛОЧНЫЕ МЕТАЛЛЫ -- СОЛИ РАСПЛАВЛЕННЫЕ -- РАСПЛАВЛЕННЫЕ СОЛИ -- САМАРИЙ -- ЕВРОПИЙ -- Sm -- Eu -- SmCl3 -- EuCl3 -- Na -- K -- Cs -- NaCl -- KCl -- CsCl |
R 32 Redox reactions in molten electrolytes containing chlorides of rare-earth metals [Текст] / V. A. Khokhlov, A. V. Novoselova, E. V. Nikolaeva, O. Yu. Tkatcheva, A. B. Salyulev // Russian Journal of Electrochemistry. - 2007. - Vol. 43, № 8. - С. 961-967. - Bibliogr. : p. 966 (27 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): MOLTEN SALT ELECTROLYTES -- RARE-EARTH METALS -- CHLORIDES Аннотация: Solutions of rare-earth metals (REM, Ln) in molten chlorides, including mixtures MCl + LnCl 3 where M stands for an alkali metal, are studied by methods of potentiometry, voltammetry, and conductimetryin broad intervals of concentration and temperature. The results that had been obtained give sufficiently com-prehensive??and reliable enough information concerning the valence state of rare-earth metals, as well as the struc-tureand composition of complex ions that make a substantial impact on the properties of electrolytes. It is dem-onstrated??that the co-existence of ions of rare-earth metals in different oxidation states, which form as a result ofpossible redox reactions 2 Ln 3+ +Ln 3 Ln 2+ ,Ln 2+ +Ln 2 Ln + ,and nM + +Ln nM +Ln n ,??clearly manifests itself in the thermodynamic and transport properties of molten systems Ln- LnCl 3 –MCl. \\\\Cserver\\dist\\НБО\\Cтатьи БД ИВТЭ\\Russian Journal of Electrochemistry\\2007, V. 43, № 8,С. 961-967.pdf |
P 87 Potentiometric study of the interaction of Cr3+ and O2- ions in fused NaCl–2CsCl eutectic [Текст] / V. V. Smolenski, A. V. Novoselova, Ya. M. Luk’yanova, A. A. Mayorshin, A. G. Osipenko, M. V. Kormilitsyn // Electrochimica Acta. - 2010. - Vol. 55, № 17. - С. 4960-4963. - Bibliogr. : p. 4963 (23 ref.) . - ISSN 0013-4686 Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ПОТЕНЦИОМЕТРИЧЕСКОЕ ТИТРОВАНИЕ -- РАСТВОРИМОСТЬ -- СТАНДАРТНЫЙ ПОТЕНЦИАЛ -- NaCl–2CsCl Аннотация: The physical and chemical properties of chromium chlorides have been studied in fused NaCl–2CsCl eutectic at the temperature range 843–1008 K using an electrochemical cell containing a platinum-oxygen electrode with solid electrolyte membrane, which was used as pO2? indicator electrode. The concentration of oxygen ions in the solution was modifying by dropping the calculated amount of BaO. Titration of Cr3+ chlorocomplex by O2? ions demonstrated the precipitation of CrOCl and Cr2O3. The solubility constants of these compounds were calculated. E–pO2? and three-dimensional E–pO2?–T type diagrams, which summarized the properties of chromium species in the melt, were determined.?? \\\\Cserver\\dist\\НБО\\Cтатьи БД ИВТЭ\\Electrochimica Acta\\EA2010 V. 55, N 17. - P.4960-4963.pdf |
N 89 Novoselova, A. V. Electrochemical and thermodynamic properties of lanthanideS (ND, SM, EU, TM, YB) in alkali metal chloride melts / A. V. Novoselova, V. V. Smolensky // Radiochemistry . - 2013. - Vol. 55, № 3. - . P. 243-256. Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ЭЛЕКТРОХИМИЧЕСКИЕ СВОЙСТВА -- ХЛОРИДЫ -- TmCl3 |