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1.
Инвентарный номер: нет.
   
   G 96


    Gusev, A. I.
    Mechanical Milling Process Modeling and Making WC Nanocrystalline Powder / A. I. Gusev, A. S. Kurlov // Inorganic Materials. - 2009. - Vol. 45, № 1. - P. 35-42 : il. - Bibliogr. : p. 42 (19 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КАРБИД ВОЛЬФРАМА -- ПОРОШКИ НАНОКРИСТАЛЛИЧЕСКИЕ
Аннотация: A model of mechanical milling of powders is proposed. It is demonstrated that, during milling, the energy is partially spent in generating microstresses, which hinders the milling process. The model is compared with experiment for tungsten carbide (WC) powder. The average particle size and the value of the microstrains in the as-milled powder are determined from the broadening of x-ray diffraction reflections. Particle size is also evaluated by scanning electron microscopy and sedimentation analysis. It is shown that, with all other things being equal, upon grinding in a planetary-type mill, the resulting particle size is less, the greater the angular velocity of the mill rotation, the longer the milling time, the lighter the weight of the powder milled, and the smaller the initial powder particle size

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2.
Инвентарный номер: нет.
   
   K 93


    Kurlov, A. S.
    Effect of WC Nanoparticle Size on the Sintering Temperature, Density, and Microhardness of WC–8 wt % Co Alloys / A. S. Kurlov, A. A. Rempel // Inorganic Materials. - 2009. - Vol. 45, № 4. - P. 380-385 : il. - Bibliogr. : p. 385 (10 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
НАНОЧАСТИЦЫ -- КАРБИД ВОЛЬФРАМА -- МИКРОТВЕРДОСТЬ -- КОБАЛЬТ -- СПЛАВЫ
Аннотация: Using X-ray diffraction, scanning electron microscopy, and density measurements, we have studied the effect of WC particle size (20 to 150 nm) on the optimal sintering temperature of the WC–8 wt % Co alloy and the effect of sintering temperature (800–1600°C) on its phase composition, density, and microhardness. The results indicate that, during sintering of the starting powder mixture, the first to form is the ternary carbide phase Co6W6C. At sintering temperatures of 1100°C and above, this phase reacts with carbon to form Co3W3C. Sintering above 1000°C leads to the formation of a cubic solid solution of tungsten carbide in cobalt, β-Co(WC), along with the ternary carbide phases. The density and microhardness of the alloy have been measured as functions of sintering temperature. The use of WC nanopowder has been shown to reduce the optimal sintering temperature of the WC–Co alloy by about 100°C

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3.
Инвентарный номер: нет.
   
   B 22


   
    Band Structure and Properties of Polymorphic Modifications of Lower Tungsten Carbide W2C / D. V. Suetin, I. R. Shein, A. S. Kurlov, A. I. Gusev, A. L. Ivanovskii // Physics of the Solid State. - 2008. - Vol. 50, № 8. - P1420-1426 : il. - Bibliogr. : p. 1426 (20 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КАРБИД ВОЛЬФРАМА -- ПОЛИМОРФНЫЕ МОДИФИКАЦИИ
Аннотация: The structural and electronic properties are investigated and the relative stabilities of all the known polymorphic modifications (α,β,γ,ε) of the lower tungsten carbide W2C are numerically estimated using the ab initio full-potential linearized augmented plane wave (FLAPW) method within the generalized gradient approximation (GGA) of the local spin density. The equilibrium parameters of the crystal lattices, the band structures, and the total and partial densities of states are determined for the first time within a unified approach. The energies of formation of the α,β,γ, and ε polymorphic modifications of the lower tungsten carbide [in the reactions W2C<-> 2W + C (graphite)] are calculated and used to discuss their relative stabilities

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4.
Инвентарный номер: нет.
   
   K 93


    Kurlov, A. S.
    Effect of sintering temperature on the phase composition and microhardness of WC-8 wt % Co cemented carbide [Text] / A. S. Kurlov, A. A. Rempel // Inorganic Materials. - 2007. - Vol. 43, № 6. - P602-607 : il. - Библиогр. : с. 607 (15 назв.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КАРБИД КОБАЛЬТА -- КАРБИД ВОЛЬФРАМА -- ПОРОШКИ -- СПЕКАНИЕ
Аннотация: The effect of sintering temperature (800–1600°C) on the phase composition, density, and microhardness of WC–8 wt % Co cemented carbide has been studied using x-ray diffraction, scanning electron microscopy, optical microscopy, and density measurements. The results indicate that, during sintering of the starting powder mixture, containing not only WC and Co but also the lower carbide W2C and free carbon, W2C reacts with cobalt metal to form Co3W. At sintering temperatures from 900 to 1200°C, the reaction intermediate is the ternary carbide phase Co6W6C. During sintering at 1300°C, this phase reacts with carbon to form Co3W3C. Sintering at 1000°C and higher temperatures is accompanied by the formation of a cubic solid solution of tungsten carbide in cobalt, β-Co(WC) . The density and microhardness of the sintered samples have been measured as functions of sintering temperature, and the optimal sintering temperature has been determined

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5.
Инвентарный номер: нет.
   
   A 90


   
    Atomic ordering as a new way ofnanostructure creation in solids [Text] / A. I. Gusev, A. S. Kurlov, V. N. Lipatnikov, A. A. Rempel // Journal of Structural Chemistry. - 2004. - Vol. 45, Suppl. - S14-S22. - Bibliogr. : p. S22 (19 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
НЕСТЕХИОМЕТРИЯ -- НАНОСТРУКТУРЫ -- КАРБИД ВАНАДИЯ
Аннотация: Structural and functional peculiarities of four types of nitrate reductases are considered: assimilatory nitrate reductase of eukaryotes, as well as cytoplasmic assimilatory, membrane nitrate reductases. Arguments are presented showing that eukaryotic organisms are capable of nitrate dissimilation. Data concerning new classes of extremophil nitrate reductases, whose active center does not contain molybdocofactor, are summarized.

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6.
Инвентарный номер: нет.
   
   K 93


    Kurlov, A. S.
    Vacuum sintering of WC–8 wt.% Co hardmetals from WC powders withdifferent dispersity / A. S. Kurlov, A. I. Gusev, A. A. Rempel // International Journal of Refractory Metals and Hard Materials. - 2011. - vol. 29, № 2. - P221-231 : il. - Bibliogr. : p. 231 (27 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
МЕТАЛЛЫ ТВЕРДЫЕ -- КАРБИД ВОЛЬФРАМА -- ОБЖИГ -- МИКРОСТРУКТУРА
Аннотация: The effect of sintering temperature and particle size of tungsten carbide WC on phase composition, density and microstructure of hardmetals WC–8 wt.%Co has been studied using X-ray diffraction, scanning electron microscopy and density measurements. The sintering temperature has been varied in the range from 800 to 1600 °C. The coarse-grained WC powder with an average particle size of 6 мm, submicrocrystalline WC??powder with an average particle size of 150 nm and two nanocrystalline WC powders with average sizes of particles 60 and 20 nm produced by a plasma-chemical synthesis and high-energy ball milling, respectively, have been used for synthesis of hardmetals. It is established that ternary Co6W6C carbide phase is the first to form as a result of sintering of the starting powder mixture. At sintering temperature of 1100–1300 °C, this??phase reacts with carbon to form Co3W3C phase. A cubic solid solution of tungsten carbide in cobalt, в-Co(WC), is formed along with ternary carbide phases at sintering temperature above 1000 °C. Dependences ofdensity and microhardness of sintering hardmetals on sintering temperature are found. The use of nanocrystalline WC powders is shown to reduce the optimal sintering temperature of the WC–Co hardmetals by about 100 °C

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7.
Инвентарный номер: нет.
   
   K 93


    Kurlov, A. S.
    High-energy milling of nonstoichiometric carbides: effect of nonstoichiometry on particle size of nanopowders / A. S. Kurlov, A. I. Gusev // Journal of Alloys and Compounds. - 2014. - Vol. 582. - P108-118
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КАРБИДЫ -- НЕСТЕХИОМЕТРИЯ -- НАНОПОРОШКИ

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8.
Инвентарный номер: нет.
   
   E 27


   
    Effect of the nonstoichiometry of tantalum carbide tac y on the particle size of nanopowders prepared by milling / A. S. Kurlov, A. M. Bel'kov, T. D. Vyrodova, A. I. Gusev // Physics of the Solid State. - 2015. - Vol. 57, № 1. - P70-78
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КАРБИД ТИТАНА -- ПОРОШКИ -- НЕСТЕХИОМЕТРИЯ -- СТРУКТУРА КРИСТАЛЛИЧЕСКАЯ -- НАНОПОРОШКИ

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9.
Инвентарный номер: нет.
   
   A 58


   
    Anisotropy of strain distortions in nanopowders of nonstoichiometric vanadium and tantalum carbides / A. I. Gusev, A. S. Kurlov, T. D. Bel'kova, A. M. Bel'kov // International Journal of Refractory Metals and Hard Materials. - 2015. - Vol. 51. - P70-80
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
КАРБИД ВАНАДИЯ, , , -- ЛУЧИ РЕНТГЕНОВСКИЕ -- НАНОЧАСТИЦЫ -- ПОРОШКИ НАНОКРИСТАЛЛИЧЕСКИЕ
Аннотация: For the first time, the effect of milling energy and nonstoichiometry of vanadium carbide VC0.875 and tantalum carbide TaCy (0.81 ≤ y ≤ 0.96) on microstrains anisotropy and the particle size of nanocrystalline powders has been studied experimentally by the X-ray diffraction method. A functional dependence of reduced broadening of diffraction reflections on the scattering vector has been obtained, which takes into consideration the contributions from size, strain and inhomogeneity broadenings. The average size of coherent scattering regions and the value of microstrains in crystallites accounting for anisotropy of strain distortions have been estimated. It is shown that allowance for anisotropy of microstrains and inhomogeneity broadening gives more accurate description of the experimental results on diffraction reflection broadening and more accurate determination of the nanoparticle size.

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10.
Инвентарный номер: нет.
   
   K 93


    Kurlov, A. S.
    Ordering of Nonstoichiometric Hexagonal Compounds M2X: A Sequence of Special Figures / A. S. Kurlov, A. I. Gusev // Physics of the Solid State. - 2009. - Vol. 51, № 10. - P2051-2057 : il. - Bibliogr. : p. 2057 (15 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
НЕСТЕХИОМЕТРИЯ -- АТОМНО-ВАКАНСИОННОЕ УПОРЯДОЧЕНИЕ -- ГЕКСАГОНАЛЬНАЯ СТРУКТУРА
Аннотация: An ensemble of figures required for the analysis of the atomic–vacancy ordering in nonstoichio metric compounds M2Xy (M2Xy 1 – y) with an L'3 hexagonal structure has been determined by the order parameter functional method. It has been demonstrated reasoning from the crystal lattice geometry that, in order to describe M2Xy compounds with an L'3 structure, it is necessary to use the basis cluster in the form of a trigonal prism consisting of six sites of the nonmetal lattice with a metal atom at the center. The overlapping figures that, together with the basis cluster, form a sequence of special figures uniquely describing the L'3 structure have been found. The equilibrium conditions for disorder–order transformations in nonstoichiometric compounds M2Xy have been determined in the general form

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