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1.

Вид документа : Статья из журнала
Шифр издания : 54/E 43
Автор(ы) : Enyashin A. N., Medvedeva N. I., Medvedeva Yu. E., Ivanovskii A. L.
Заглавие : Electronic Structure and Magnetic States of Crystalline and Fullerene-Like Forms of Nickel Dichloride NiCl2
Место публикации : Physics of the Solid State. - 2005. - Vol. 47, № 3. - С. 527-530: il.
Примечания : Bibliogr. : p. 530 (12 ref.)
ISSN: 1063-7834
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): дихлорид никеля--фуллерены--ферромагнетики--стехиометрия
Аннотация: The electronic structure and magnetic properties of the crystalline and fullerene-like forms of nickel dichloride NiC² are investigated in the framework of the local spin density functional theory. It is demonstrated that the band gap can be reproduced in the energy band spectrum of the NiCl² compound with inclusion of the magnetic ordering in the calculation of the band structure. The metamagnetic nature of the NiCl² dichloride (i.e., the transition from an antiferromagnetic phase to a ferromagnetic phase in a weak magnetic field) is explained in terms of a small difference (0.025 eV/cell) between the total energies of the ferromagnetic and antiferromagnetic phases. Polyhedral three-shell nanoparticles of the NiCl² compound exhibit magnetic properties (the magnetic moment of nickel lies in the range 2.0–2.3 µβ). For isostructural nanoparticles of the FeCl² dichloride, the magnetic moment of iron is larger and falls in the range 4.2–4.5 µβ, whereas nanoparticles of the CdCl² dichloride are found to be nonmagnetic. The results of analyzing the interatomic interactions indicate that the composition of fullerene-like nanoparticles of the dichlorides under investigation can deviate from the 1 : 2 stoichiometric composition
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2.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания : 54/S 89
Автор(ы) : Kozhevnikov V. L., Leonidov I. A., Patrakeev M. V., Bahteeva J. A.
Заглавие : Structural stability and ion transport in LaSr2Fe1-yCryO8+δ
Место публикации : NATO Science Series II Mathematics, Physics and Chemistry, 2006, Volume 202, Fuel Cell Technologies State and Perspectives. - 2006. - Vol. 202: Fuel Cell Technologies State and Perspectives. - С. 149-155: il.
Примечания : Bibliogr. : p. 155 (2 ref.)
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): кислородная проводимость--электронная проводимость--ферриты лантан-стронциевые--перовскиты
Аннотация: Ceramic samples of LaSr2Fe3-yCryO8+δ are characterized with X-ray powder diffraction and total conductivity measurements in the temperature range 750- 950°C and at oxygen partial pressures between 10-22 and 0.5 atm. It is shown that partial replacement of iron for chromium is an effective means to prevent structural transformation at the loss of oxygen. The isothermal ion conductivity is obtained from the analysis of the total conductivity, and it is shown to decrease with the increase in chromium doping to y = 0.6. However further increase in the chromium content to y = 1 results in an increase in the oxygen ion conductivity level. This behavior is explained with a model where the oxygen ions coordinated to chromium are not excluded entirely from the transport mechanism
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3.

Вид документа : Статья из журнала
Шифр издания : 54/S 90
Автор(ы) : Gromilov S. A., D’yachkova T. V., Yusenko K. V., Kireenko I. B., Tyutyunnik A. P., Zainullin Yu. G.
Заглавие : Study of the Re0.50Rh0.50 products of thermobaric treatment
Место публикации : Journal of Structural Chemistry. - 2009. - Vol. 50, № 2. - С. 306-311: il.
Примечания : Bibliogr. : p. 310-311 (20 ref.)
ISSN: 0022-4766
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): родий--рений--микротвердость--рентгенофазовый анализ--термолиз
Аннотация: The products of thermobaric treatment of the metastable Re0.50Rh0.50 nanocrystalline phase (a = 2.733(2) Å, c = 4.364(4) Å, space group P63/mmc, CSR ~5 nm) in a high-pressure chamber were studied. Storage of the phase at 2000C and 1.5 GPa for 3 min led to the formation of a fused particle (diam.~1 mm). The initial composition did not change, but the coherent scattering region (CSR) increased to 52 nm. An increase to 4 GPa in pressure also did not lead to a decomposition of the metastable Re0.50Rh0.50 phase, the unit cell parameters remained the same, and the size of the CSR increased by a factor of four
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4.

Вид документа : Статья из журнала
Шифр издания : 54/M 61
Автор(ы) : Denisova T. A., Maksimova L. G., Polyakov E. V., Zhuravlev N. A., Kovyazina S. A., Leonidova O. N., Khabibulin D. F., Yur`eva E. I.
Заглавие : Metatitanic Acid: Synthesis and Properties
Место публикации : Russian Journal of Inorganic Chemistry. - 2006. - Vol. 51, № 5. - С. 691-699: il.
Примечания : Bibliogr. : p. 699 (24 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): метатитановая кислота--титанат лития
Аннотация: Features of proton-for-lithium ion substitution in monoclinic and pseudocubic lithium titanate are studied by X-ray diffraction, NMR spectroscopy, and Raman spectroscopy. Proton incorporation into the lithium titanate structure decreases the parameter ac of the pseudocubic unit cell from 8.28 Å in Li2TiO3 to ≈ 8.15Å in H2TiO3. Metatitanic acid, like hydrous titania, has weak acid properties, but unlike titania, it sorbs hydrolyzable multicharged cations from aqueous solutions
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5.

Вид документа : Статья из журнала
Шифр издания : 54/B 33
Автор(ы) : Bazuev G. V., Chupakhina T. I., Melkozerova M. A.
Заглавие : Synthesis and Magnetic Properties of Quasi-Unidimensional Oxide Sr6.3Rh2.35Mn2.35O15
Место публикации : Russian Journal of General Chemistry. - 2008. - Vol. 78, № 10. - С. 1843-1848: il.
Примечания : Bibliogr. : p. 1847-1848 (33 ref.)
ISSN: 1070-3632
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): квазиодномерные оксиды--магнитные свойства
Аннотация: Attempts of the synthesis in air of complex oxides Sr3RhMnOx and Sr4Rh1.5Mn1.5Ox resulted in revealing formation of a new oxide phase Sr6.3Rh2.35Mn2.35O9 related to quasi-unidimensional family A3n+3mA'nВ3m+nO9m+6n at n = 1 and m = 1. Its structural characteristics and magnetic properties are studied. X-ray data of the obtained phase is indicated on the basis of trigonal cell (spatial group P321) with the parameters: a 9.6239(4) Å; с1 4.1130(4) Å, с2 2.4946(2) Å. Manganese and rhodium exist in the compound as the cations Mn4+, Rh3+ and Rh4+, as follows from the data of measuring of magnetic susceptibility in the range 2–300 K
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6.

Вид документа : Статья из журнала
Шифр издания : 54/E 27
Автор(ы) : Kosova N. V., Devyatkina E. T., Kaichev V. V., Kellerman D. G.
Заглавие : Effect of Electronic State of Ions on the Electrochemical Properties of Layered Cathode Materials LiNi1-2xCoxMnxO2
Место публикации : Russian Journal of Electrochemistry. - 2008. - Vol. 44, № 5. - С. 543-549
Примечания : Bibliogr. : p. 548-549 (31 ref.)
ISSN: 1023-1935
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): слоистые катодные материалы--литиево-ионные батареи--магнитная восприимчивость
Аннотация: The cathode materials of the composition LiNi1– 2xCoxMnxO2(x= 0.1, 0.2. 0.33) synthesized from the Ni, Co, Mn mixed hydroxides and LiOH by using mechanical activation method are studied. It is shown that all synthesized compounds have layered structure described by the space group R-3m. With the decreasing of the nickel content the cell volume and the degree of structure disordering decrease. According to XPS data, the electronic main state of d-ions at the prepared samples' surfaces corresponds to Ni2+,Co3+, and Mn4+. Anincrease in the nickel content leads to the increase of the Ni2p3/2and Co2p3/2binding energy, which points to the change in the Me–O bond covalence. According to magnetic susceptibility measurements data, the nickel ions in LiNi0.6Co0.2Mn2O 2 exist in the two oxidation states: Ni2+and Ni3+. It is shown that this sample has the highest specific discharge capacity (~170 mAh/g). The positions of redox peaks in the differential capacitance curves depend on the sample composition: with the increasing of nickel content they are shifted toward lower voltages
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7.

Вид документа : Статья из журнала
Шифр издания : 54/C 51
Автор(ы) : Cherkashenko V. M., Kurmaev E. Z., Zainulin Yu. G.
Заглавие : Influence of pressure on the x-ray spectra and electronic structure of vanadium oxycarbide and vanadium oxynitride
Место публикации : Journal of Structural Chemistry. - 1988. - Vol. 29, № 2. - С. 311-313: il.
Примечания : Bibliogr. : p. 313 (8 ref.)
ISSN: 0022-4766
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): оксинитрид ванадия--оксикарбид ванадия
Аннотация: Investigations of the oxides of titaniumand vanadium following treatment under the conditions of high pressures (P) and temperatures (t) [1-3] showed that such treatment results in changes in a number of structural physical characteristics (the lattice constant, the number of particles in the unit cell, and the volume of the latter) and electronic properties (the magnetic susceptibility and x-ray emission spectra)
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8.

Вид документа : Статья из журнала
Шифр издания : 54/Г 96
Автор(ы) : Гусев А. И.
Заглавие : Сверхструктуры Ti2O5 кубического монооксида титана
Место публикации : Журнал экспериментальной и теоретической физики. - 2013. - Т. 144, № 2. - С. 340-357: ил.
Примечания : Библиогр.: с. 356-357 (40 назв.)
ISSN: 0044-4510
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): монооксид титана--нестехиометрия
Аннотация: A cubic model is proposed for the Ti5O5 (Ti5 O5 ≡ Ti90 18O90 18) superstructure of nonsto ichiometric titanium monoxide TixOz with double imperfection. The unit cell of the cubic Ti5O5 superstruc ture has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of TixOz monoxide and belongs to space group Pm m. The channel of the disorder–order transition, i.e., TixOz (space groupFm m)–Ti5O5 (space group Pm m), includes 75 superstructure vectors of seven stars {k10}, {k7}, {k6(1)}, {k6(2)}, {k4(1)}, {k4(2)}, and {k1}. The distribution functions of Ti and O atoms over the sites of the cubic Ti5O5 superstructure are calculated. A comparison of the X ray and electron diffraction data obtained for ordered TiO1.087 monoxide with the theoretical simulation results supports the existence of the cubic Ti5O5 super structure. The cubic (space group Pm m) Ti5O5 superstructure is shown to be a high temperature structure relative to the well known monoclinic (space group C2/m) superstructure of the same type
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9.

Вид документа : Статья из журнала
Шифр издания : 54/C 91
Автор(ы) : Tyutyunnik A. P., Leonidov I. A., Surat L. L., Berger I. F., Zubkov V. G.
Заглавие : Crystal structure, morphotropic phase transition and luminescence in the new cyclosilicates Sr3R2(Si3O9)2, R=Y, Eu–Lu
Место публикации : Journal of Solid State Chemistry. - 2013. - Vol. 197. - С. 447-455: il.
Примечания : Bibliogr. : p. 454-455 (71 ref.)
ISSN: 0022-4596
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): рентгеновская дифракция--силикаты--люминесценция
Аннотация: A new series of promising luminescent materials, cyclosilicates Sr3R2(Si3O9)2, R=Y, Eu–Lu, has been synthesized via a solid-state reaction. X-ray and neutron powder diffraction studies show that these oxides crystallize in the monoclinic crystal system (S.G. C2/c, Z=4) and have a morphotropic phase transition between Er and Tm compounds followed by a step-like change of the unit cell constants. Isolated [Si3O9] rings located in layers are basic building units and stack with Sr/R layers along the [1 0 ] direction. The rare earth atoms are distributed among three independent Sr/R sites coordinated by 8, 7 and 6 oxygen atoms, and the Sr-R populations change from mixed to 0.5/0.5 over site (1) and full occupation of sites (2) and (3) by Sr and R, respectively, at the transition. Changes of the conformation and mutual arrangement of [Si3O9] rings, as well as exchange of oxygen atoms from the first and the second coordination sphere of two Sr/R sites also feature the phase transition. Luminescence in Sr3Y2(Si3O9)2:Eu3+ under ultraviolet (UV) excitation has been discussed
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10.

Вид документа : Статья из журнала
Шифр издания : 54/C 91
Автор(ы) : Leonidova O. N., Voronin V. I., Leonidov I. A., Samigullina R. F., Slobodin B. V.
Заглавие : Crystal structures of double vanadates LiCoVO4 and Li0:5Co1:25VO4
Место публикации : Journal of Structural Chemistry. - 2003. - Vol. 44, № 2. - С. 243-247: il.
Примечания : Bibliogr. : p. 247 (9 ref.)
ISSN: 0022-4766
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): ванадаты--шпинели--электронная структура--литий
Аннотация: The crystal structures of vanadates Li1-2xCo1+xVO4 with x = 0 and 0:25 have been studied by a full pattern analysis. It has been shown that in cubic spinel LiCoVO4 (space group Fd3m), the 8a tetrahedral sites contain a majority of vanadium and a small amount of lithium; all cobalt, lithium, and a small amount of vanadium occupy the 16d octahedral sites. Li0.5Co1.25VO4 crystals belong to the rhombic system (Imma space group) with unit cell parameters a = 5:939(1) A, b = 5:810(1) A, and c = 8:303(1) A. On substitution of lithium by cobalt according to the scheme 2Li+ - Co2+ + , half of the lithium and 70% of the vacancies formed are in the 4a octahedral sites, and one-third of lithium and most of cobalt occupy the 4d octahedral sites. The 4e tetrahedral sites are completely occupied by vanadium and lithium in a ratio of 0:92=0:08. The interatomic distances in LiCoVO4 and Li0.5Co1.25VO4 are calculated, and the sizes of lithium ion transport channels are evaluated
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11.

Вид документа : Статья из журнала
Шифр издания : 54/L 36
Автор(ы) : Zuev M. G., Perelyaeva L. A., Arkhipova E. V., Kiiko V. S.
Заглавие : Lattice dynamics in LaTa2-2xNb2xVO9-delta (x = 0-0.1) solid solutions
Место публикации : Journal of Structural Chemistry. - 2003. - Vol. 44, № 2. - С. 206-210: il.
Примечания : Bibliogr. : p. 210 (9 ref.)
ISSN: 0022-4766
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): твердые растворы--кислородная нестехиометрия--спектроскопия
Аннотация: The oxygen nonstoichiometry delta(x) of LaTa2-2xNb2xVO9-delta (x = 0{0.1) solid solutions was studied using X-ray phase analysis, vibrational spectroscopy, and radiospectroscopy. A correlation was found between delta(x) and the unit cell volume V (x) of the solid solutions. It was shown that the infrared spectra of LaTa2VO9 change in passing from delta = 0 to delta/= 0. The structural position of the oxygen vacancy in LaTa2-2xNb2xVO9-delta is discussed
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12.

Вид документа : Статья из журнала
Шифр издания : 54/E 43
Автор(ы) : Medvedeva N. I., Zhukov V. P., Novikov D. L., Gubanov V. A.
Заглавие : Electronic structure and chemical bonding of delta-Bi203
Место публикации : Journal of Structural Chemistry. - 1996. - Vol. 37, № 1. - С. 41-50: il.
Примечания : Bibliogr. : p. 49-50 (21 ref.)
ISSN: 0022-4766
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): оксид висмута--флюоритоподобная структура--лмто метод
Аннотация: The band structure of the fluorite-type 6-Bi203 was calculated by the linear LMTO methods in the approximation of overlapping atomic spheres using the basis set of orthogonal orbitals (LMTO-ASA) and by the full-potential LMTO method (LMTO-FP) for two vacancy orientations over a wide range of oxygen concentrations. The calculated parameters of chemical bonds - the binding energy Ebin and the pressure of the electron-nuclear system - show that the most stable compound is that with two vacancies per unit cell, oriented predominantly along the (111) direction. The hybrid Bi-O bonds are weak, and mostly the Bi-Bi bonds are responsible for the structural stabilization of c5-Bi203 . The mechanism of the formation of a semiconductor gap in the band structure of 6-Bi203 is discussed
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13.

Вид документа : Статья из журнала
Шифр издания : 54/N 52
Автор(ы) : Chupakhina T. I., Zaitseva N. A., Melkozerova M. A., Bazuev G. V.
Заглавие : New Representatives of the Raddlesden–Popper Homologous Series: Anion-Deficient Oxides Sr3Co2-xZnxO6+δ(=0.5, 0,75)
Место публикации : Russian Journal of Inorganic Chemistry. - 2006. - Vol. 51, № 8. - С. 1157-1162: il.
Примечания : Bibliogr. : p. 1162 (19 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): комплексные оксиды--раддлесдена-поппера структура
Аннотация: New complex oxides Sr3Co2 –ZnxO6+δ with x= 0.50 and 0.75, which belong to the Raddlesden– Popper homologous series (An+ 1BnO3n+ 1;n= 2), are synthesized. The structural and magnetic properties of these oxides are studied. The unit cell parameters a and c for the x= 0.5 and 0.75 compounds are 0.38541(2) and 0.38573(2) nm and 2.03543(1) and 2.03999(11) nm, respectively. The magnetic susceptibility of Sr3Co1.5Zn0.5O6.25 as a function of temperature obeys the Curie–Weiss law (χ=C/(T–θ)) only within a narrow temperature range from 250 to 300 K. At low temperatures, this compound has spin-glass properties with a characteristic magnetic and temperature hystereses and a freezing temperature of Tg= 25–30 K
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14.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Tyutyunnik A. P., Krasil'nikov V. N., Zubkov V. G., Perelyaeva L. A., Baklanova I. V.
Заглавие : Synthesis, Structure, and Properties of V2O3(XO4)2 (X = S, Se)
Место публикации : Russian Journal of Inorganic Chemistry. - 2010. - Vol. 55, № 4. - С. 501-507: il.
Примечания : Bibliogr. : p. 507 (14 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): оксид ванадия--сульфат ванадия
Аннотация: Compounds described as V2O3(XO4)2, where X = S or Se, were prepared from vanadium(V) oxide mixtures with concentrated sulfuric and selenic acids. The physicochemical properties of the products were studied; for V2O3(SeO4)2, the crystal structure was determined by powder X ray diffraction and neutron diffraction, and its key differences from the structure of V2O3(SO4)2 were identified. V2O3(SeO4)2 crystallizes in the monoclinic system with the unit cell parameters a = 15.3831(2) Å, b = 5.54096(5) Å, c = 9.71644(7) Å, β =111.886(1)°, V = 768.51 Å3, space group C2/c
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15.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Krasil'nikov V. N., Shtin A. P., Perelyaeva L. A., Baklanova I. V., Tyutyunnik A. P., Zubkov V. G.
Заглавие : Synthesis and Physicochemical Study of M4Na2V10O28 · 10H2O (M = K, Rb, NH4)
Место публикации : Russian Journal of Inorganic Chemistry. - 2010. - Vol. 55, № 2. - С. 162-166: il.
Примечания : Bibliogr. : p. 166 (6 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): декаванадаты двойные--кристаллизация
Аннотация: The formation conditions and physicochemical properties of binary decavanadates M4Na2V10O28 · 10H2O (M = K, Rb, NH4), synthesized by crystallization from saturated solutions of the NaVO3–MH2AsO4–H2O systems, were studied by chemical analysis, X-ray powder diffraction, microscopy, thermogravimetry, and IR spectroscopy. To optimize the synthesis conditions of M4Na2V10O28 · 10H2O, the (1 – x)NaVO3 · 2H2O · xMH2AsO4–H2O (0.2 ≤ x ≤ 0.8) isomolar series method was applied to studying the interaction in the NaVO3–MH2AsO4–H2O systems (M = K, Rb, Cs) at the 0.4 mol/L total molar concentration of NaVO3 and MH2AsO4 in solutions. The studied M4Na2V10O28 · 10H2O compounds were shown to be isostructural with triclinic crystals (Z = 1, space group P ), and their unit cell parameters were estimated
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16.

Вид документа : Статья из журнала
Шифр издания : 54/S 53
Автор(ы) : Shaikhlislamova A. R., Zhuravlev N. A., Yaroslavtsev A. B.
Заглавие : Li+/H+ Ion Exchange in Li3 – 2xNbxM2 – x(PO4)3 (M = In, Fe) Materials with a NASICON Structure
Место публикации : Russian Journal of Inorganic Chemistry. - 2010. - Vol. 55, № 1. - С. 18-22: il.
Примечания : Bibliogr. : p. 22 (13 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): ионный обмен--протонная проводимость
Аннотация: H3 – 2xNbxM2 – x(PO4)3 (M = In, Fe) acid phosphates have been obtained by ion exchange from their lithium forms and X ray powder diffraction, impedance measurements, and 7Li and 1H NMR spectroscopy. The parameters of the hexagonal unit cell of the proton exchanged forms differ only slightly from those of the initial lithium compounds. According to 1H NMR data, the proton in the acid phosphates is not hydrated. The conductivity of the acid phosphates at high temperatures depends weakly on their composition and is ~1.7 × 10–7 S cm–1 at 620 K. The activation energy of conduction is 30–33 kJ/mol (430–770 K)
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17.

Вид документа : Статья из журнала
Шифр издания : 54/M 76
Автор(ы) : Yaremchenko A. A., Kharton V. V., Kolotygin V. A., Patrakeev M. V. , Tsipis E. V. , Waerenborgh J. C.
Заглавие : Mixed conductivity, thermochemical expansion and electrochemical activity of Fe-substituted (La,Sr)(Cr,Mg)O3-δ for solid oxide fuel cell anodes
Место публикации : Journal of Power Sources. - 2014. - Vol. 249. - С. 483-496
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): поляризация--хромит лантана--нестехиометрия--тотэ
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18.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Krasil'nikov V. N., Tyutyunnik A. P., Zubkov V. G., Berger I. F., Perelyaeva L. A., Baklanova I. V.
Заглавие : Synthesis, Structure, and Properties of M3VO2(SO4)2 (M = Rb, Cs)
Место публикации : Russian Journal of Inorganic Chemistry. - 2010. - Vol. 55, № 9. - С. 1331-1338: il.
Примечания : Bibliogr. : p. 1338 (27 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): ванадий пятивалентный--катализаторы
Аннотация: Vanadium(V) complexes of general composition M3VO2(SO4)2 (M = Rb, Cs) were synthesized by a solid state route. The individuality of the synthesized compounds was proved by X ray and neutron diffraction, vibrational spectroscopy, and microscopic analysis. The X-ray diffraction patterns of M3VO2(SO4)2 were indexed to fit the monoclinic system (space group P2/c, Z = 4) with the following unit cell parameters: a =11.6487(2) Å, b = 8.4469(2) Å, c = 12.1110(2) Å, β = 109.483(1)°, V = 1123.43 Å3 (Rb); a = 12.0546(3) Å, b = 8.7706(2) Å, c = 12.6496(3) Å, β = 109.843(2)°, V = 1257.99 Å3 (Cs). In the crystal structure of M3VO2(SO4)2, [VO2(SO4)2]3– complex anions can be discerned in which the vanadium atom is surrounded by five oxygen atoms: two oxygen atoms form short terminal V–O bonds, and three oxygen atoms are from the two sulfato groups, one of which acts as a monodentate ligand and the other acts as a bidentate chelating ligand
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19.

Вид документа : Статья из журнала
Шифр издания : 54/S 98
Автор(ы) : Chupakhina T. I., Matskevich N. I., Bazuev G. V., Ovechkina N. A., Galakhov V. R., Raeckers M., Neumann M.
Заглавие : Synthesis, Crystal and Electronic Structures, and Thermodynamic Characteristics of BaCe1 – xInxO3 – x/2 Solid Solutions
Место публикации : Russian Journal of Inorganic Chemistry. - 2010. - Vol. 55, № 7. - С. 1002-1009: il.
Примечания : Bibliogr. : p. 1008-1009 (37 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): перовскиты--твердые растворы--оксид церия
Аннотация: New perovskite oxide phases BaCe1 – xInxO3 – x/2 (x = 0.1–0.8) (space group Pbnm) have been synthesized. The unit cell volume of the resulting solid solutions monotonically decreases with an increase in the degree of substitution of indium for cerium due to the contraction of octahedra in perovskite blocks. The thermodynamic stability of the compound BaCe0.75In0.25O2.875 was studied by the solution calorimetry method, and barium cerates were shown to be thermodynamically stable with respect to binary oxides at room temperature. The structure of occupied and vacant states in BaCe1 – xInxO3 – x/2 was determined on the basis of X ray emission, absorption, and photoelectron spectra, and the energy gap was estimated at ~2 eV
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20.

Вид документа : Статья из журнала
Шифр издания : 54/C 91
Автор(ы) : Tyutyunnik A. P., Zubkov V. G., Berger I. F., Krasil'nikov V. N., Perelyaeva L. A., Baklanova I. V.
Заглавие : Crystal Structure and Spectroscopic Properties of AVO2SO4 (A = K, Rb) Compounds
Место публикации : Russian Journal of Inorganic Chemistry. - 2007. - Vol. 52, № 9. - С. 1424-1429: il.
Примечания : Bibliogr. : p. 1429 (20 ref.)
ISSN: 0036-0236
ББК : 54
Предметные рубрики: ХИМИЧЕСКИЕ НАУКИ
Ключевые слова (''Своб.индексиров.''): кристаллическая структура--ванадаты
Аннотация: The crystal structure of alkali-metal dioxovanadium(V) sulfates AVO2SO4, where A is K or Rb, has been determined based on a combination of neutron and X-ray diffraction data. The compounds are isostructural and have an orthorhombic lattice (space group P212121, Z = 4) with unit cell parameters a = 11.1004(2) and 10.8193(1) Å; b = 8.2626(2) and 8.9042(1) Å; c = 5.4772(1) and 5.5722(1) Å, respectively. The structures are of the chain type. Zigzag chains are formed by vertex-sharing VO6 octahedra. Sulfate groups SO4 link neighboring chains and form a spatial framework with cavities accommodating alkali-metal atoms with CN = 9 (K) and 8 (Rb). IR and Raman spectroscopy data are reported
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