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Общее количество найденных документов : 23
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1.
Инвентарный номер: нет.
   
   K 81


    Krasil'nikov, V. N.
    Synthesis of fine and nanosized oxide materials, using metal carboxylates and products of their chemical modification by ethylene glycol as precursors [Текст] / V. N. Krasil'nikov, O. I. Gyrdasova, G. V. Bazuev // Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya. - 2006. - Vol. 70, № 7. - С. 988-991
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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2.
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   P 91


   
    Preparation of MnCo2O4 whiskers and spheroids through thermal decomposition of Mn1/3Co2/3C2O4.bul.2H2O [Text] / O. I. Gyrdasova, G. V. Bazuev, I. G. Grigorov, O. V. Koryakova // Inorganic Materials. - 2006. - Vol. 42, № 10. - P1126-1132. - Библиогр. : с. 1132 (20 назв.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
МАНГАНИТЫ -- НАНОМАТЕРИАЛЫ -- ОКСАЛАТЫ
Аннотация: The mixed oxalate Mn1/3Co2/3C2O4 * 2H2O has been prepared in the form of whiskers 2-5 µm in diameter and up to 50 µm in length and spheroidal nanofiber arrays 20 µm in diameter using two different coprecipitation procedures. Thermal decomposition of this oxalate in air has led to the formation of MnCo2O4 particles very similar in morphology to their oxalate precursor. The materials have been characterized by chemical analysis, thermogravimetry, x-ray diffraction, IR spectroscopy, and scanning electron microscopy

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3.
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   E 27


   
    Effect of ethylene glycol on the formation of extended crystals of M1/3Co2/3C2O4·2H2O (M = Zn, Mn) oxalates and their thermolysis products [Текст] / O. I. Gyrdasova, V. N. Krasil'nikov, I. G. Grigorov, G. V. Bazuev // Zhurnal Neorganicheskoi Khimii. - 2006. - Vol. 51, № 6. - С. 1020-1026
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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4.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and magnetic properties of a new complex oxide Sr3ScMnO6.49 [Текст] / T. I. Chupakhina, N. A. Zaitseva, M. A. Melkozerova, O. I. Gyrdasova, G. V. Bazuev // Zhurnal Neorganicheskoi Khimii. - 2005. - Vol. 50, № 3. - С. 362-366
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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5.
Инвентарный номер: нет.
   
   P 91


   
    Preparation of ZnCo2O4 spinel whiskers from zinc cobalt oxalate [Text] / G. V. Bazuev, O. I. Gyrdasova, I. G. Grigorov, O. V. Koryakova // Inorganic Materials. - 2005. - Vol. 41, № 3. - P288-292. - Библиогр. : с. 291 (12 назв.)
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Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ШПИНЕЛИ -- ОКСАЛАТ ЦИНКА -- ОКСАЛАТ КОБАЛЬТА
Аннотация: ZnCo2O whiskers 2-5 µm in diameter and up to 50 µm in length, retaining their composition and shape up to 800°C, are prepared via decomposition of the mixed oxalate Zn1/3Co2/3C2O4 * 2H2O in air and are characterized using chemical analysis, x-ray diffraction, IR spectroscopy, and scanning electron microscopy

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6.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and physicochemical properties of Ni1-xZnxFe2O4 spinel produced by thermal decomposition of complex oxalates [Текст] / O. I. Gyrdasova, G. V. Bazuev, A. Yu. Kuznetsov, I. G. Grigorov, V. A. Tsurin, S. I. Novikov, V. A. Barinov // Izvestiya Akademii Nauk, Seriya Fizicheskaya. - 2004. - Vol. 68, № 5. - С. 720-722
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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7.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and Study of Photocatalytic Activity of Nanoscale Quasi-One-Dimensional Ti1 – xVxO2 (0 ≤ x ≤ 0.13) and Zn1 – xCoxO (0 ≤ x ≤ 0.3) Oxides / O. I. Gyrdasova, V. N. Krasil'nikov, G. V. Bazuev, L. Yu. Buldakova, M. Yu. Yanchenko // Bulletin of the Russian Academy of Sciences: Physics. - 2009. - Vol. 73, № 8. - P. 1113-1116 : il. - Bibliogr. : p. 1116 (10 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ФОТОКАТАЛИТИЧЕСКАЯ АКТИВНОСТЬ -- ОКСИВАНАДАТ ТИТАНА -- ОКСИКОБАЛЬТИТ ЦИНКА
Аннотация: A original method of synthesis of quasi one dimensional Ti1 – xVx(OCH2CH2O)2 (0 ≤ x ≤ 0.13) and Zn1 – xCox(HCOO)(HOCH2CH2O) (0 ≤ x ≤ 0.3) has been developed. The synthesis products were used as a basis for nanoscale extended Ti1 – xVxO2 and Zn1 – xCoxO oxides. The compounds obtained and products of their thermolysis were investigated by X ray diffraction, microscopy, IR spectroscopy, thermogravimetry, and chemical analysis; the shape and size of particles were determined by scanning electron microscopy. The good prospects of Ti1 – xVxO2 and Zn1 – xCoxO solid solutions as photocatalysts for hydroquinone oxidation are shown

\\\\Expert2\\nbo\\Bulletin of the Russian Academy of Sciences Physics\\2009, V. 73, N 8, P. 1113-1116.pdf
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8.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis, Microstructure, and Photocatalytic Characteristics of Quasi One Dimensional Zinc Oxide Doped with d Elements / O. I. Gyrdasova, V. N. Krasil'nikov, E. V. Shalaeva, L. Yu. Buldakova, M. Yu. Yanchenko, V. G. Bamburov // Doklady Chemistry. - 2010. - Vol. 434, № 1. - P. 211-213 : il. - Bibliogr. : p. 113 (9 ref.)
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Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ФОТОКАТАЛИЗ -- ОКСИД ЦИНКА -- СИНТЕЗ -- МИКРОСТРУКТУРА

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9.
Инвентарный номер: нет.
   
   N 28


   
    Nature of defects in nanocrystalline zinc oxide with particles of tubular morphology / M. A. Melkozerova, V. N. Krasil'nikov, O. I. Gyrdasova, E. V. Zabolotskaya, E. V. Shalaeva, R. F. Samigullina // Theoretical and Experimental Chemistry. - 2012. - Vol. 48, № 3. - P139-142 : il. - Bibliogr. : p. 142 (14 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ОКСИД ЦИНКА -- МАТЕРИАЛЫ НАНОРАЗМЕРНЫЕ -- СТРУКТУРА ДЕФЕКТНАЯ -- ЭПР -- ФОТОКАТАЛИЗ
Аннотация: Nanostructured ZnO powders with particles of tubular form were synthesized by a precursor method. A narrow symmetrical line with a g factor of 2.002 was detected in the ESR spectra of the materials. On the basis of analysis of the dependence of the line intensities on the heat treatment conditions it was concluded that the signal belongs to singly charged oxygen vacancies V(+)O

\\\\Expert2\\nbo\\Theoretical and Experimental Chemistry\\2012, V.48, № 3, p.139.pdf
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10.
Инвентарный номер: нет.
   
   V 86


    Volkov, V. L.
    The ion emission properties of MxV205 (M = Li, Na, K, Cs) bronzes were studied at temperatures in Sodium Aluminum Vanadium beta-Bronzes / V. L. Volkov, O. I. Gyrdasova // Inorganic Chemistry. - 2000. - Vol. 36, № 8. - P. 802-806 : il. - Bibliogr. : p. 806 (7 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ТЕРМОДИНАМИКА -- БРОНЗЫ ВАНАДИЕВЫЕ -- АЛЮМИНИЙ
Аннотация: The partial thermodynamic functions of AI in the [3-bronzes Na2-yAlyVl2030 (0 < y <= 0.7), Na2AlyVl2030 (0 < y <= 1.4), and Nal.3AlyVl2030 (0 < y <= 2.1) were determined as a function of composition in the temperature range 294-348 K. The AG (AI), AH (AI), and AY; (AI) of the bronzes were found to vary in a complex manner with AI content, passing through extrema near y = 1 as a result of the structural ordering of A13+ ions. The temperature dependences of A G (AI) show changes in slope between 303 and 318 K, attributable to redistribution of the AI 3+ ions over the possible crystallographic sites in the beta-bronze structure

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11.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis, Physicochemical Properties, and Electrode Behavior of Ni2[Ni(OH)6W6O18] · 8H2O / E. V. Polyakov, T. A. Denisova, L. G. Maksimova, O. I. Gyrdasova, L. I. Manakova // Inorganic Materials. - 2002. - Vol. 38, № 9. - P. 956-961 : il. - Bibliogr. : p. 961 (14 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ГЕКСАВОЛЬФРАМОНИКЕЛАТ НИКЕЛЯ -- ЯДЕРНЫЙ МАГНИТНЫЙ РЕЗОНАНС -- ЯМР
Аннотация: Nickel(II) hexatungstonickelate(II) was synthesized and characterized by elemental analysis, x-ray diffraction, thermal analysis, IR spectroscopy, and 1H nuclear magnetic resonance. The results demonstrate that constitutional water is present in the form of OH groups, which can be removed by heating to 230–370 °C. The chemical formula of the compound is Ni2[Ni(OH)6W6O18] ·8H2O. Nickel(II) hexatungstonickelate(II), a poorly soluble compound, was tested as an electrode for Ni(II) determination in solution. Its electrode properties and selectivity for other ions suggest that it is a promising material for such applications. At pH 5, the ionselective electrode we fabricated has a Nernstian response to Ni(II) (10–5 to 10–1 mol/l) which is close to that predicted theoretically

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12.
Инвентарный номер: нет.
   
   T 93


   
    Tungstate-Selective Electrode / E. V. Polyakov, L. I. Manakova, L. G. Maksimova, T. A. Denisova, O. I. Gyrdasova // Journal of Analytical Chemistry. - 2002. - Vol. 57, № 5. - P452-455 : il. - Bibliogr. : p. 454-455 (26 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ВОЛЬФРАМАТСЕЛЕКТИВНЫЕ ЭЛЕКТРОДЫ -- СЕНСОРЫ
Аннотация: A chemical sensor for tungstate ions has been developed and implemented in two versions on the basis of the poorly soluble nickel(II) hexatungstonickelate(II) heteropoly compound. The electrode function is linear within the range 10–5–10–1 M tungsten for the film electrode and within the range 10–4–10–1 M tungsten for the coated wire electrode at pH 6–9. The slope of the electrode function is 28–29 mV. The time it takes to attain an equilibrium electrode potential is 1–5 min, depending on the ion concentration to be determined. The selectivity coefficients are found for the tungstate-selective electrode in the presence of chloride, sulfate, nitrate, and perchlorate

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13.
Инвентарный номер: нет.
   
   V 26


   
    Vanadyl and Titanium Glycolates as Precursors for the Preparation of Oxide Materials in the Form of Elongated Microparticles and Nanoparticles / V. N. Krasil'nikov, A. P. Shtin, O. I. Gyrdasova, I. V. Baklanova, L. A. Perelyaeva // Nanotechnologies in Russia . - 2008. - Vol. 3, № 1-2. - P106-111 : il. - Bibliogr. : p. 110-111 (14 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ГЛИКОЛЯТ ВАНАДИЛА -- ГЛИКОЛЯТ ТИТАНА -- ОКСИДЫ -- НАНОЧАСТИЦЫ
Аннотация: This paper reports on the results of investigations of the optimum conditions for the formation and properties of vanadyl and titanium glycolates of the compositions VO(OCH2CHO) and Ti(OCH2CH2O)2 with elongated crystals, as well as solid solutions of the composition Ti1–xVx(OCH2CH2O)2(0
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14.
Инвентарный номер: нет.
   
   S 54


    Shkerin, S. N.
    Electrode System Ni/NayAlxV12O30/Al3+:An Impedance Spectroscopy Study / S. N. Shkerin, O. I. Gyrdasova, V. L. Volkov // Russian Journal of Electrochemistry. - 2002. - Vol. 38, № 5. - P496-506. - Bibliogr. : p. 505-506 (17 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ЭЛЕКТРОДНЫЕ СИСТЕМЫ -- ИМПЕДАНСНАЯ СПЕКТРОСКОПИЯ
Аннотация: The impedance of electrochemical cells Ni/VOB/Al3+, Ni/VOB/Na+, and Ni/VOB/Ni (where VOB stands for vanadium oxide bronzes of the general formula NayAlxV12O30, with 0 < x £1.7) is studied both at equilibrium and a constant-current polarization. Variations in the VOB composition and aqueous electrolytic solutions in contact with the bronze as a result of the passing of the current are monitored. The results of these measurements are employed to substantiate a model that describes the occurrence of processes of current production in the Ni/VOB/Al3+ electrode system. The overvoltage is defined to a substantial degree by the aluminum diffusion. The diffusion coefficients for aluminum, its partial conductivity, and transport number are estimated

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15.
Инвентарный номер: нет.
   
   E 27


   
    Effect of Ethylene Glycol on the Formation of Extended Crystals of M1/3Co2/3C2O4(M = Zn, Mn) Oxalates and Their Thermolysis Products / O. I. Gyrdasova, V. N. Krasil'nikov, I. G. Grigorov, G. V. Bazuev // Russian Journal of Inorganic Chemistry. - 2006. - Vol. 51, № 6. - P949-955 : il. - Bibliogr. : p. 954-955 (19 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ЭТИЛЕНГЛИКОЛЬ -- ОКСАЛАТЫ -- ТЕРМОЛИЗ -- ЦИНК -- МАРГАНЕЦ
Аннотация: The effect of ethylene glycol (EG) on the formation of whiskers and fibers of complex oxides with the general formula MCo2O4 upon the thermolysis of M1/3Co2/3C2O4(M = Zn, Mn) oxalates has been studied. New compounds (solvates) are formed when powdered oxalates are heated with EG. In the solvates, EG molecules substitute for water molecules according to the reaction M1/3Co2/3C2O4· 2H2O + HOCH2CH2OH =M1/3Co2/3C2O4(HOCH2CH2OH) + 2H2O. The solvates have been characterized using X-ray powder diffraction, microscopy, IR spectroscopy, thermogravimetry, and chemical analysis. The shape, structure, and particle size of the thermolysis products of EG-modified oxalates have been determined using scanning electron microscopy

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16.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and Properties of Titanium Glycolate Ti(OCH2CH2O)2 / V. N. Krasil'nikov, A. P. Shtin, O. I. Gyrdasova, E. V. Polyakov, G. P. Shveikin // Russian Journal of Inorganic Chemistry. - 2008. - Vol. 53, № 7. - P1065-1069 : il. - Bibliogr. : p. 1069 (21 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ГЛИКОЛЯТ ТИТАНА -- ДИОКСИД ТИТАНА -- НАНОТЕХНОЛОГИИ
Аннотация: A new efficient method for the synthesis of extended micro- and nano-sized crystals (whiskers, fibers) of titanium glycolate Ti(OCH2CH2O)2 has been suggested. The method implies the reaction of hydrated titanium dioxide with ethylene glycol on heating in air. Thermolysis of Ti(OCH2CH2O)2 in air gives titanium dioxide as anatase (400–500°C) and rutile (T> 700°C), the morphology of titanium glycolate crystals being inherited by the oxide. The pseudocrystals of the thermolysis product in an inert gas medium (T=500–950°C) represent aglomeration of nano-sized titanium dioxide particles and amorphous carbon. At temperatures up to 1300°C, the formation of the TiO2–xCx phase with a rutile structure is probable. In a wet air environment, titanium glycolate is partially hydrolyzed to give TiOx(OCH2CH2O)2–2x(OH)2x·xH2O(0≤x≤1) and on keeping in water at room temperature, ethylene glycol is completely displaced from the crystals. This process is also not accompanied by changes in the particle morphology

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17.
Инвентарный номер: нет.
   
   K 81


    Krasil'nikov, V. N.
    Ethylene Glycol-Modified Cobalt and Iron Oxalates As Precursors for the Synthesis of Oxides As Extended Microsized and Nanosized Objects / V. N. Krasil'nikov, O. I. Gyrdasova, G. V. Bazuev // Russian Journal of Inorganic Chemistry. - 2008. - Vol. 53, № 12. - P1854-1861 : il. - Bibliogr. : p. 1860-1861 (18 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ЭТИЛЕНГЛИКОЛЬ -- КОБАЛЬТ -- ОКСИДЫ -- ОКСАЛАТ ЖЕЛЕЗА
Аннотация: The reactions of ethylene glycol with iron and cobalt oxalates upon heating in air are reported. Heat treatment of mixtures of oxalate powders with ethylene glycol yields new compounds (solvates) via the replacement of the water molecules in the oxalate structure by ethylene glycol molecules: MC2O4·2H2O+HOCH2CH2OH=MC2O4(HOCH2CH2OH)+2H2O↑. The crystals resulting from this reaction are elongated, and their shape is inherited by their thermolysis products. Thermolysis in air yields microwhiskers and nanowhiskers of Fe2O3and Co3O4, and thermolysis in an inert atmosphere affords Fe3O4and Co whiskers. The thermolysis of FeC2O4(HOCH2CH2OH) in helium yields a new structural modification of FeC2O4 as an intermediate product. The resulting compounds and their thermolysis products were characterized by X-ray powder diffraction, microscopy, IR spectroscopy, and thermogravimetric and chemical analyses. The particle shape and size were determined by scanning electron microscopy

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18.
Инвентарный номер: нет.
   
   G 99


    Gyrdasova, O. I.
    Synthesis of Micro- and Nanosized Manganese Oxides from Hydrated Manganese Oxalates and Products of Their Chemical Modification with Ethylene Glycol / O. I. Gyrdasova, V. N. Krasil'nikov, G. V. Bazuev // Russian Journal of Inorganic Chemistry. - 2009. - Vol. 54, № 7. - P1035-1040 : il. - Bibliogr. : p. 1040 (9 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ОКСИД МАРГАНЦА -- ОКСАЛАТЫ -- ЭТИЛЕНГЛИКОЛЬ
Аннотация: The reactions of ethylene glycol with manganese oxalates MnC2O4·2H2O and MnC2O4·3H2O on heating in air were studied. At temperature below 100°C, ethylene glycol was found to displace water from oxalates to give a new solvate compound according to the reaction MnC2O4·nH2O+HOCH2CH2OH=MnC2O4(HOCH2CH2OH) +nH2O↑. The crystals of the solvates retain the morphology of the initial oxalates, which is then inherited by the products of their thermolysis. Thus, thermolysis of MnC2O4·3H2O and MnC2O4(HOCH2CH2OH) having quasi-unidimensional structure gave Mn3O4 and Mn2O3nanowhiskers in air and MnO in an inert gas environment. Heating of MnC2O4·nH2O in ethylene glycol at temperatures above 100°C results in anhydrous manganese oxalate

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19.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and Photocatalytic Activity of Ti[1 – x]VxO[2 – y]Cy Whiskers in Hydroquinone Oxidation in Aqueous Solutions / V. N. Krasil'nikov, A. P. Shtin, O. I. Gyrdasova, E. V. Polyakov, L. Yu. Buldakova, M. Yu. Yanchenko, V. M. Zainullina, V. P. Zhukov // Russian Journal of Inorganic Chemistry. - 2010. - Vol. 55, № 8. - P1184-1191 : il. - Bibliogr. : p. 1190-1191 (28 ref.)
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
ФОТОКАТАЛИТИЧЕСКАЯ АКТИВНОСТЬ -- ГИДРОХИНОН -- ВАНАДИЙ
Аннотация: Ti1–xVxO2–yCy (0 ≤ x ≤ 0.10 and x = 0.50) whiskers having the anatase structure were synthesized via thermolysis of vanadium doped titanium glycolate of composition Ti1–xVx(OCH2CH2O)2 (0 ≤ x ≤ 0.10 and x = 0.50). The starting reagents used to prepare Ti1–xVx(OCH2CH2O)2 were mixtures of coprecipitated titanium and vanadyl hydroxides, which were heated in ethylene glycol at T ≤ 200°C: (1 – x)TiO(OH)2 + xVO(OH)2 + 2HOCH2CH2OH = Ti1–xVx(OCH2CH2O)2 + 3H2O↑. Thermolysis of vanadium doped titanium glycolate in various gas media over a wide range of temperatures is useful to prepare titania samples doped with both vanadium and carbon to form a phase of the general composition Ti1 – xVxO2 – yCy whiskers prepared by thermolyzing Ti1 – xVx(OCH2CH2O)2 in air at 450°C were found to have a high photocatalytic activity in hydroquinone oxidation in aqueous solutions irradiated in the UV spectral range; the photocatalyst’s activity increases with increasing vanadium concentration. When hydroquinone was irradiated in the blue, the maximal catalytic activity was discovered in a sample of composition Ti0.50V0.50O2–yCy. Quantum chemical calculations support experimental data that the double doping of titania (Ti1–xVxO2–yCy) enhances its photocatalytic activity compared to undoped anatase or anatase doped in one sublattice: Ti1–xVxO2 and TiO2–yCy alytic activity compared to undoped anatase or anatase doped in one sublattice: Ti1–xVxO2 and TiO2–yCy.

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20.
Инвентарный номер: нет.
   
   O-66


   
    Optical and photocatalytic properties of quasi-one-dimensional ZnO activated by carbon / O. I. Gyrdasova, V. N. Krasil'nikov, E. V. Shalaeva, I. V. Baklanova, M. A. Melkozerova, L. Y. Buldakova, M. Y. Yanchenko // Mendeleev Communications. - 2014. - Vol. 24, № 3. - P143-144
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
СВОЙСТВА ОПТИЧЕСКИЕ -- УГЛЕРОД

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  БХЛ - Фонд художественной литературы

  ИИиА -Фонд исторической литературы в ЦНБ УрО РАН

  ИМЕТ -Отдел ЦНБ в Институте металлургии УрО РАН

  кх - Отдел фондов (книгохранениe)

  МБА - Межбиблиотечный абонемент

  мф - Методический фонд

  ок - Отдел научной каталогизации

  оку - Отдел комплектования и учета

  орф - Обменно-резервный фонд

  пф - Читальный зал деловой и патентной информации

  рк - Фонд редкой книги

  ч/з - Главный читальный зал

  эр - Зал электронных ресурсов

  

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