C 11 Ca3(VO4)2–LaVO4 Cation Conductors / I. A. Leonidov, O. N. Leonidova, L. L. Surat, R. F. Samigullina // Inorganic Materials. - 2003. - Vol. 39, № 6. - P. 616-620 : il. - Bibliogr. : p. 620 (20 ref.) Рубрики: ХИМИЧЕСКИЕ НАУКИ Кл.слова (ненормированные): ФАЗОВОЕ РАВНОВЕСИЕ -- ВАНАДАТ КАЛЬЦИЯ -- ВАНАДАТ ЛАНТАНА Аннотация: Experimental data are presented on the electrical conductivity, ionic transference numbers, and phase transitions of Ca3 - xLa2x/3(VO4) 2 (0<= x <= 1) vanadates, which are shown to be Ca ionic conductors. The highest Ca ion conductivity is found in Ca2La2/3(VO4)2 (palmierite structure) at low temperatures and in beta'-Ca3(VO4)2 (whitlockite-like structure) at high temperatures. The mechanisms of Ca2+ transport are discussed Полный текст |