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1.
Инвентарный номер: нет.
   


   
    2,3-Dichloro-1-alkylpyrazinium tetrafluoroborates: the synthesis and reactions with nucleophiles [Electronic resource] / G. L. Rusinov, P. A. Slepukhin, V. N. Charushin, O. N. Chupakhin // Mendeleev Communications. - 2001. - Vol. 11, № 2. - P78-80
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The alkylation of 2,3-dichloropyrazine with the Meerwein reagents afforded 1-alkyl-2,3-dichloropyrazinium tetrafluoroborates, which were transformed into mono.mono- or disubstitution products, while the reaction of these salts with 1,4-N,Xdinucleophiles resulted in fused heterocyclic systems

\\\\expert2\\nbo\\Mendeleev Communications\\2001, v.11, N 2. p.78.pdf
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2.
Инвентарный номер: нет.
   
   I-83


   
    ipso- and tele-Substitution in reactions of 3-chloro-1-ethyl-2-R-pyrazinium salts with C-nucleophiles [Electronic resource] / P. A. Slepukhin, G. L. Rusinov, V. N. Charushin, M. I. Kodess, O. N. Chupakhin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2003. - Vol. 52, № 3. - P689-694
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of 2,3-dichloro- and 3-chloro-1-ethyl-2-morpholinopyrazinium tetrafluoroborates with compounds containing the active methylene group were studied. The reactions with malonodinitrile and cyanoacetic ester afford products of ipso-substitution at position 2, while 1,3-dicarbonyl compounds produce products of tele-substitution of the Cl atom at the C(3) atom due to the attack of a nucleophile to position 6 of the pyrazine cycle

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2003, 52 (3), 689.pdf
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3.
Инвентарный номер: нет.
   
   M 81


   
    Mono- and diadducts and bicyclic adducts in reactions of 2,3-dicyano-1-ethylpyrazinium cation with C- and O-nucleophiles [Electronic resource] / P. A. Slepukhin, G. L. Rusinov, V. N. Charushin, V. I. Filyakova, N. S. Karpenko, D. B. Krivolapov, I. A. Litvinov // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2004. - Vol. 53, № 6. - P1272-1278
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Products of diaddition of O- and C-nucleophiles to the 2,3-dicyano-1-ethylpyrazinium cation were isolated for the first time. The tandem AN—AN reactions of 2,3-dicyano-1-ethylpyrazinium tetrafluoroborate with 1,3-diketone enolates or keto esters afforded tetrahydrofuro[2,3-b]pyrazine derivatives, whereas cyclization with ethylene glycol gave tetrahydro-1,4-dioxino[2,3-b]pyrazine. Crystallographic data on the three-dimensional structures of these compounds were reported

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2004, 53 (6), 1272.pdf
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4.
Инвентарный номер: нет.
   
   T 19


   
    Tandem reactions in the synthesis of condensed 1,4-diazines [Text] / V. N. Charushin, P. A. Slepukhin, N. N. Mochul`skaya, L. P. Sidorova, G. L. Rusinov, O. N. Chupakhin // 20-th International Congress of Heterocyclic Chemistry : abstracts. - Palermo, Italy, 2005. - P504
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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5.
Инвентарный номер: нет.
   
   N 71


   
    Nitroalkyl-substituted tetrahydropyrazines in syntheses of azapolycyclic compounds [Electronic resource] / P. A. Slepukhin, N. N. Mochul`skaya, L. P. Sidorova, G. L. Rusinov, M. A. Ezhikova, M. I. Kodess, O. N. Kazheva, A. N. Chekhlov, O. A. Dyachenko, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2005. - Vol. 54, № 9. - P2197-2203. - Библиогр. : с. 2203 (13 назв. )
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Tri-and tetracyclic compounds were synthesized by the cyclization of 6-alkoxy-2,3-dicyano-5-nitromethyl-1,4,5,6-tetrahydropyrazines with 1,2,3-triazinium and quinoxalinium cations.

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2005, 54 (9), 2197-2203.pdf
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6.
Инвентарный номер: нет.
   
   F 56


   
    First example of direct introduction of nucleophiles bearing a stable radical moiety into azaaromatic substrates [Electronic resource] / E. V. Verbitskiy, G. L. Rusinov, P. A. Slepukhin, A. I. Matern, Yu. N. Shvachko, V. N. Charushin, O. N. Chupakhin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2006. - Vol. 55, № 11. - P2114-2116
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Addition products of 4-hydroximino-2,2,6,6-tetramethylpiperidine-1-oxyl with 5-aryl-2,3-dicyano-1-ethylpyrazinium salts were isolated for the first time. Crystallographic data on the three-dimensional structures of ?H-adducts bearing a stable radical moiety were obtaned

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2006, 55 (11), 2114.pdf
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7.
Инвентарный номер: нет.
   
   S 98


   
    Synthesis and structure of tert - butylacetylene copper cluster [Text] / P. A. Slepukhin, E. F. Khmara, O. A. Kuznetsova, V. I. Fylyakova, A. Ye. Yermakov, M. A. Uimin, V. N. Charushin // V Conference of Clusters Chemistry and Polynuclear Compounds "Clusters-2006", Astrakhan, Russia. - Астрахань, 2006. - P97
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ

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8.
Инвентарный номер: нет.
   
   C 51


   
    Chemistry of O- and C-adducts derived from 1,4-diazinium salts: the use of tetrahydropyrazines in the synthesis of condensed systems [Electronic resource] / G. L. Rusinov, P. A. Slepukhin, V. N. Charushin, O. A. Dyachenko, O. N. Kazheva, A. N. Chekhlov, E. V. Verbitskiy, M. I. Kodess, O. N. Chupakhin // Mendeleev Communications. - 2006. - Vol. 16, № 1. - P26-29
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 1-Ethyl-2,3-dicyano-5-nitromethyl-6-methoxy-1,4,5,6-tetrahydropyrazine reacts with N-methylquinoxalinium iodide in the presence of triethylamine to form octahydro-2,4a,5,10-tetraazabenzo[b]fluorene-3,4-dicarbonitrile, while our attempts to obtain similar polycyclic products from stereoisomeric 5-(S)- and 5-(R)-(1`-nitroprop-1`-yl)-6-methoxy-1,4,5,6-tetrahydropyrazines derived from the reaction of 1-nitropropane with 2,3-dicyano-5,6-dimethoxy-1-ethyl-1,4,5,6-tetrahydropyrazine.

\\\\Expert2\\nbo\\Mendeleev Communications\\2006, v.1, p.26.pdf
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9.
Инвентарный номер: нет.
   
   N 52


   
    New podandes and crown ethers nodified with the fragments of fluorinated pyrazolines [Text] : доклад, тезисы доклада / V. I. Filyakova, E. B. Letova, N. S. Boltacheva, P. A. Slepukhin, V. N. Charushin // 15th European symposium on fluorine chemistry, Prague, Czech Republic, July 15-20, 2007 : abstr. - 2007. - P202
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
FLUORINATED PYRAZOLINES

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10.
Инвентарный номер: нет.
   
   T 82


   
    Transformations of 8-substituted tetrazolo[1,5-a]pyrazines [Electronic resource] / P. A. Slepukhin, G. L. Rusinov, S. Dedeneva, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2007. - Vol. 56, № 2. - P345-350
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The reactions of 8-chlorotetrazolo[1,5-a]pyrazine with N-, O-, and S-nucleophiles involve the ipso substitution of the chlorine atom. Heating of this compound with benzotriazole or phenyltetrazole results in elimination of the nitrogen molecule from one of the tetrazole rings to form new annelated azapentalenes

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2007, 56 (2), 345.pdf
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11.
Инвентарный номер: нет.
   
   F 52


    Filyakova, V. I.
    Unusual transformation of trifluoroacetylacetone [Text] : доклад, тезисы доклада / V. I. Filyakova, P. A. Slepukhin, V. N. Charushin // 15th European symposium on fluorine chemistry, Prague, Czech Republic, July 15-20, 2007 : abstr. - 2007. - P203
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Кл.слова (ненормированные):
TRIFLUOROACETYLACETONE

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12.
Инвентарный номер: нет.
   
   S 67


    Slepukhin, P. A.
    X-ray structural investigation of the products of ring closure of 2-alkenylthiopyridines upon treatment with mercury iodide [Electronic resource] / P. A. Slepukhin, D. G. Kim, V. N. Charushin // Journal of Structural Chemistry. - 2008. - Vol. 49, № 6. - P1144-1148
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The products of the reaction of 2-alkenylthiopyridines with mercury iodide have been studied by single crystal X-ray diffraction. It has been demonstrated that the products are organomercury derivatives of salts of 2,3-dihydrothiazolo[3,2-a]pyridinium

\\\\Expert2\\nbo\\Journal of Structural Chemistry\\2008, V. 49, N 6, p.1144.pdf
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13.
Инвентарный номер: нет.
   
   S 83


   
    Stereochemical features of addition of O- and C-nucleophiles to 5-(Het)aryl-2,3-dicyano-1-ethylpyrazinium salts [Electronic resource] / E. V. Verbitskiy, G. L. Rusinov, P. A. Slepukhin, A. N. Grishakov, M. A. Ezhikova, M. I. Kodess, V. N. Charushin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2008. - Vol. 44, № 2. - P302-310
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Stable delta(H)-adducts of O- and C-nucleophiles were obtained with cations of 5-(het)aryl-2,3-dicyano-1-ethylpyrazinium, and their structure was investigated by X-ray diffraction analysis. Analytical separation was performed of 1,2-dihydropyrazines into individual enantiomers by means of HPLC on columns with chiral sorbents

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2008, 44 (2), 302.pdf
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14.
Инвентарный номер: нет.
   
   F 70


   
    Fluorine-containing heterocycles. XVII. (Tetrafluorobrnzoyl)thioureas in the synthesis of fluorine-containing azaheterocycles [Electronic resource] / G. N. Lipunova, E. V. Nosova, A. A. Laeva, T. V. Trashakhova, P. A. Slepukhin, V. N. Charushin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2008. - Vol. 44, № 5. - P741-749
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Proceeding from (tetrafluorobenzoyl)thioureas fluorine-containing derivatives were synthesized of 1-aryl-2-ethylthioquinazolin-4-one, [1,3]benzothiazin-4-one, and also of thiazolidine and 1H-1,2,4-triazole

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2008, 44 (5), 741.pdf
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15.
Инвентарный номер: нет.
   
   C 91


   
    Crystal structure of lithium beta-diketonate containing perfluorobutyl and pyridyl substituents [Electronic resource] / P. A. Slepukhin, N. S. Boltacheva, V. I. Filyakova, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2008. - Vol. 57, № 3. - P573-576
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The crystal structure of lithium 4,4,5,5,6,6,7,7,7-nonafluoro-1-(3-pyridyl)heptane-1,3-dionate hydrate was established by X-ray diffraction

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2008, 57 (3), 573.pdf
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16.
Инвентарный номер: нет.
   
   T 82


   
    Transformations of C-adducts of 1,4-diazinium salts with dicarbonyl compounds into polycyclic systems [Electronic resource] / E. V. Verbitskiy, P. A. Slepukhin, G. L. Rusinov, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2008. - Vol. 57, № 3. - P652-656
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: C-Adducts of 5-(het)aryl-2,3-dicyano-1-pyrazinium salts containing a residue of a 1,3-dicarbonyl compound at position 6 can be involved in the cyclization with hydrazine hydrate giving rise to pyrazino[2,3-c]pyridazines along with the expected pyrazole derivatives. The reactions of the same ?H-adducts with hydroxylamine unexpectedly afforded triazacyclopenta[a]indene derivatives. The crystallographic data on the three-dimensional structures of new polycyclic compounds were obtained

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2008, 57 (3), 652.pdf
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17.
Инвентарный номер: нет.
   
   S 59


   
    Sigma(H)-Adducts of N-alkylpyrazinium and quinoxalinium salts with nucleophiles. The 1H and 13C NMR spectra and the crystal structures of P-adducts [Electronic resource] / E. V. Verbitskiy, M. V. Berezin, P. A. Slepukhin, G. L. Rusinov, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2009. - Vol. 58, № 1. - P176-181
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The previously unknown addition products of P-nucleophiles to 5-aryl- and 5-hetaryl- 2,3-dicyano-1-ethylpyrazinium salts and to 5-aryl- and 5-hetaryl-14nethylquinoxalinium salts were synthesized. The three-dimensional structures of the P- sigma(H)-adducts of the 1,4-diazine series were established by X-ray diffraction

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2009, 58 (1), 176-181.pdf
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18.
Инвентарный номер: нет.
   
   F 70


   
    Fluorine-containing quinazolines annulated at the pyrimidine ring [Electronic resource] / E. V. Nosova, A. A. Laeva, T. V. Trashakhova, G. N. Lipunova, P. A. Slepukhin, V. N. Charushin // Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya). - 2009. - Vol. 58, № 6. - P1303-1308
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: Fluorine-containing quinazolines annulated at the sides [a] and [c] were synthesized by the reaction of 2- and 4-hydrazino-substituted quinazolines with aldehydes and subsequent oxidative cyclization. Annulation at the side [b] was performed by alkylation of 2-alkylthio-4(3H)-quinazolinones with bromoethanol and ipso-substitution of the alkylthio group

\\\\Expert2\\nbo\\Russian Chemical Bulletin\\2009, 58 (6), 1303-1308.pdf
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19.
Инвентарный номер: нет.
   
   F 70


   
    Fluorine-containing heterocycles. XVIII. Monofluoro derivatives of quinazolines and 1,3-benzothiazin-4-ones [Electronic resource] / E. V. Nosova, A. A. Laeva, T. V. Trashakhova, A. V. Golovchenko, G. N. Lipunova, P. A. Slepukhin, V. N. Charushin // Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimii). - 2009. - Vol. 45, № 6. - P904-912
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: 5- and 7-Fluoro-substituted quinazolines and 1,3-benzothiazin-4-ones were synthesized starting from 2-amino-6-fluorobenzonitrile and mono- and difluoro-substituted benzoic acid derivatives. The reactivities of di- and tetrafluoro-substituted benzoyl chlorides and benzoyl isothiocyanates in cyclocondensations leading to fluorinated quinazolines and 1,3-benzothiazines were compared

\\\\Expert2\\nbo\\Russian Journal of Organic Chemistry\\2009, 45 (6), 904.pdf
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20.
Инвентарный номер: нет.
   
   C 45


   
    Changes in the vibrational characteristics of substituted 1,2,4,5-tetrazines after complexation with 1,2,3-benzotriazole: A theoretical study [Electronic resource] / N. N. Ivshina, E. V. Bartashevich, V. A. Potemkin, M. A. Grishina, R. I. Ishmetova, G. L. Rusinov, N. I. Latosh, P. A. Slepukhin, V. N. Charushin // Journal of Structural Chemistry. - 2009. - Vol. 50, № 6. - P1053-1058
ББК 54
Рубрики: ХИМИЧЕСКИЕ НАУКИ
Аннотация: The complexation of 3,6-substituted 1,2,4,5-tetrazines with benzotriazole was studied theoretically based on the vibrational spectra. For model complexes, the energy was minimized by the geometrical parameters, and the spectral characteristics were calculated by the PM3 method. The shift of the bond vibration frequencies of the atoms involved in complexation after the formation of different various intermolecular contacts was determined. This made it possible to determine the type of intermolecular interaction and suggest the structures of the complexes

\\\\Expert2\\nbo\\Journal of Structural Chemistry\\2009, V. 50, N 6, p.1053.pdf
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